+1 858-523-8231
Login | Register
AA Blocks, Building Blocks, Catalysts, Inhibitors
Login | Register
Home Other Building Blocks 117968-51-1
117968-51-1,MFCD06658479
Catalog No.:AA000I5L

117968-51-1 | 4-(tert-Butyl-dimethyl-silanyloxy)-but-2-ynoic acid methyl ester

Pack Size
Purity
Availability
Price(USD)
Quantity
  
250mg
95%
in stock  
$384.00   $269.00
- +
1g
95%
in stock  
$916.00   $641.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA000I5L
Chemical Name:
4-(tert-Butyl-dimethyl-silanyloxy)-but-2-ynoic acid methyl ester
CAS Number:
117968-51-1
Molecular Formula:
C11H20O3Si
Molecular Weight:
228.3602
MDL Number:
MFCD06658479
SMILES:
COC(=O)C#CCO[Si](C(C)(C)C)(C)C
Properties
Computed Properties
 
Complexity:
288  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
15  
Hydrogen Bond Acceptor Count:
3  
Rotatable Bond Count:
4  

Downstream Synthesis Route
931-49-7    117968-51-1   
(Z)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-5-cyclohex-1-enyl-pent-2-en-4-ynoicacidmethylester 

[1]Trost,BarryM.;Hachiya,Iwao;McIntosh,MatthiasC.[TetrahedronLetters,1998,vol.39,#36,p.6445-6448]

2777-66-4    117968-51-1   
(Z)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-tetradec-2-en-4-ynedioicaciddimethylester 

[1]Trost,BarryM.;Hachiya,Iwao;McIntosh,MatthiasC.[TetrahedronLetters,1998,vol.39,#36,p.6445-6448]

[1]Koppisch,AndrewT.;Blagg,BrianS.J.;Poulter,C.Dale[OrganicLetters,2000,vol.2,#2,p.215-217]

[1]Abe,Hideki;Itaya,Satoko;Sasaki,Kei;Kobayashi,Toyoharu;Ito,Hisanaka[ChemicalCommunications,2015,vol.51,#17,p.3586-3589]

[2]Abe,Hideki;Tango,Haruhito;Kobayashi,Toyoharu;Ito,Hisanaka[TetrahedronLetters,2017,vol.58,#45,p.4296-4298]

[3]Koppisch,AndrewT.;Blagg,BrianS.J.;Poulter,C.Dale[OrganicLetters,2000,vol.2,#2,p.215-217]

[4]Yamamoto,Yoshihiko;Shibano,Shinya;Kurohara,Takashi;Shibuya,Masatoshi[JournalofOrganicChemistry,2014,vol.79,#10,p.4503-4511]

[5]Linstadt,RoscoeT.H.;Peterson,CarlA.;Lippincott,DanielJ.;Jette,CarinaI.;Lipshutz,BruceH.[AngewandteChemie-InternationalEdition,2014,vol.53,#16,p.4159-4163][Angew.Chem.,2014,vol.126,#16,p.4243-4247,5]

117968-51-1    304457-04-3   
4-(<i>tert</i>-butyl-dimethyl-silanyloxymethyl)-2-(2,5,5-trimethyl-1,3dioxan-2-ylmethyl)-furan-3-carboxylicacidmethylester 
 
4-(<i>tert</i>-butyl-dimethyl-silanyloxymethyl)-5-(2,5,5-trimethyl-1,3dioxan-2-ylmethyl)-furan-3-carboxylicacidmethylester 

[1]Efremov,Ivan;Paquette,LeoA.[Heterocycles,2002,vol.56,#1-2,p.35-38]

[2]Efremov,Ivan;Paquette,LeoA.[JournaloftheAmericanChemicalSociety,2000,vol.122,#38,p.9324-9325]

[3]Paquette;Efremov[JournaloftheAmericanChemicalSociety,2001,vol.123,#19,p.4492-4501]

Literature
Quotation Request
Company Name:
*
Contact Person:
*
Email:
*
Quantity Required:
*
Country:
Additional Info:
SDS
Related Products of 117968-51-1
141-78-6

141-78-6

 3424-59-7

3424-59-7

 90691-33-1

90691-33-1

 2258-42-6

2258-42-6
Building Blocks
More >
Tags:117968-51-1 Molecular Formula|117968-51-1 MDL|117968-51-1 SMILES|117968-51-1 4-(tert-Butyl-dimethyl-silanyloxy)-but-2-ynoic acid methyl ester