Home Fluorides 1259-35-4
1259-35-4,MFCD00079654
Catalog No.:AA000OVC

1259-35-4 | Tris(pentafluorophenyl)phosphine

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1g
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$13.00   $9.00
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5g
98%
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$43.00   $30.00
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25g
98%
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$211.00   $148.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA000OVC
Chemical Name:
Tris(pentafluorophenyl)phosphine
CAS Number:
1259-35-4
Molecular Formula:
C18F15P
Molecular Weight:
532.1424
MDL Number:
MFCD00079654
SMILES:
Fc1c(P(c2c(F)c(F)c(c(c2F)F)F)c2c(F)c(F)c(c(c2F)F)F)c(F)c(c(c1F)F)F
Properties
Properties
 
BP:
343.4°C at 760 mmHg  
Form:
Solid  
MP:
108-110 °C(lit.)  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
566  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
34  
Hydrogen Bond Acceptor Count:
15  
Rotatable Bond Count:
3  
XLogP3:
6.1  

Downstream Synthesis Route

[1]Caputo,ChristopherB.;Hounjet,LindsayJ.;Dobrovetsky,Roman;Stephan,DouglasW.[Science,2013,vol.341,#6152,p.1374-1377]

[2]Solyntjes,Sven;Neumann,Beate;Stammler,Hans-Georg;Ignat'ev,Nikolai;Hoge,Berthold[EuropeanJournalofInorganicChemistry,2016,vol.2016,#25,p.3999-4010]

[3]Frohn,H.J.;Maurer,H.[JournalofFluorineChemistry,1986,vol.34,p.73-82]

[4][GmelinHandbuchderAnorganischenChemie,GmelinHandbook:F:PerFHalOrg.3,1.10,page123-137]

[5][GmelinHandbuchderAnorganischenChemie,GmelinHandbook:F:PerFHalOrg.3,1.10,page123-137]

[6]Koppe,Karsten;Haner,Jamie;Mercier,HlneP.A.;Frohn,Hermann-J.;Schrobilgen,GaryJ.[InorganicChemistry,2014,vol.53,#21,p.11640-11661]

[1]Fild,M.[Diss.Goettingen1966]

[2]Walletal.[JournaloftheAmericanChemicalSociety,1960,vol.82,p.4846]

[3][GmelinHandbuchderAnorganischenChemie,GmelinHandbook:F:PerFHalOrg.3,1.4,page31-40]

[4][GmelinHandbuchderAnorganischenChemie,GmelinHandbook:F:PerFHalOrg.3,1.4,page31-40]

[5]Abu-Omar;Espenson[JournaloftheAmericanChemicalSociety,1995,vol.117,#1,p.272-280]

[6]Furin,G.G.;Krupoder,S.A.;Rezvukhin,A.I.;Kilina,T.M.;Yakobson,G.G.[JournalofFluorineChemistry,1983,vol.22,p.345-376]

[7]Oliver,KatherineW.;Rettig,StevenJ.;Thompson,RobertC.;Trotter,James;Xia,Shihua[JournalofFluorineChemistry,1997,vol.83,#1,p.47-50]

[8]Andreevskaya,O.I.;Krupoder,S.A.;Furin,G.G.;Yakobson,G.G.[1980,p.97-104][C.A.,1981,vol.94,p.191477]

[9][GmelinHandbuchderAnorganischenChemie,GmelinHandbook:F:PerFHalOrg.3,1.10,page123-137]

[10][GmelinHandbuchderAnorganischenChemie,GmelinHandbook:F:PerFHalOrg.3,1.10,page123-137]

[11][GmelinHandbuchderAnorganischenChemie,GmelinHandbook:F:PerFHalOrg.3,1.10,page123-137]

[12][GmelinHandbuchderAnorganischenChemie,GmelinHandbook:F:PerFHalOrg.SVol.1,5.2.3,page87-96]

[1]Schaefer,Andre;Reissmann,Matti;Schaefer,Annemarie;Saak,Wolfgang;Haase,Detlev;Mueller,Thomas[AngewandteChemie-InternationalEdition,2011,vol.50,#52,p.12636-12638]

[2]Reissmann,Matti;Schaefer,Andre;Jung,Sebastian;Mueller,Thomas[Organometallics,2013,vol.32,#22,p.6736-6744]

[3]Oliver,KatherineW.;Rettig,StevenJ.;Thompson,RobertC.;Trotter,James;Xia,Shihua[JournalofFluorineChemistry,1997,vol.83,#1,p.47-50]

[1]Pérez,Manuel;Qu,Zheng-Wang;Caputo,ChristopherB.;Podgorny,Vitali;Hounjet,LindsayJ.;Hansen,Andreas;Dobrovetsky,Roman;Grimme,Stefan;Stephan,DouglasW.[Chemistry-AEuropeanJournal,2015,vol.21,#17,p.6491-6500]

[2]Godfrey,StephenM.;McAuliffe,CharlesA.;Pritchard,RobinG.;Sheffield,JoanneM.;Thompson,GraemeM.[JournaloftheChemicalSociety,DaltonTransactions,1997,#24,p.4823-4827]

[1]Pérez,Manuel;Qu,Zheng-Wang;Caputo,ChristopherB.;Podgorny,Vitali;Hounjet,LindsayJ.;Hansen,Andreas;Dobrovetsky,Roman;Grimme,Stefan;Stephan,DouglasW.[Chemistry-AEuropeanJournal,2015,vol.21,#17,p.6491-6500]

[2]Godfrey,StephenM.;McAuliffe,CharlesA.;Mushtaq,Imran;Pritchard,RobinG.;Sheffield,JoanneM.[JournaloftheChemicalSociety,DaltonTransactions,1998,#22,p.3815-3818]

Literature

Title: Probing bare high-valent transition oxo-metal complexes: an electrospray ionization Fourier transform ion cyclotron resonance study of reactive intermediates.

Journal: European journal of mass spectrometry (Chichester, England) 20100101

Title: Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo species.

Journal: Journal of the American Chemical Society 20050511

Title: Axial chirality in 1,4-disubstituted (ZZ)-1,3-dienes. Surprisingly low energies of activation for the enantiomerization in synthetically useful fluxional molecules.

Journal: Journal of the American Chemical Society 20031217

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Tags:1259-35-4 Molecular Formula|1259-35-4 MDL|1259-35-4 SMILES|1259-35-4 Tris(pentafluorophenyl)phosphine