+1 858-523-8231
Login | Register
menu
AA Blocks, Building Blocks, Catalysts, Inhibitors
Login | Register
129946-88-9,MFCD00236132
Catalog No.:AA000TQB

129946-88-9 | S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate

Pack Size
Purity
Availability
Price(USD)
Quantity
  
250mg
97%
in stock  
$26.00   $19.00
- +
1g
97%
in stock  
$72.00   $50.00
- +
5g
97%
in stock  
$285.00   $200.00
- +
25g
97%
in stock  
$1,235.00   $865.00
- +
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Application
  • Request for Quotation
  • Download SDS
Technical Information
Catalog Number:
AA000TQB
Chemical Name:
S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate
CAS Number:
129946-88-9
Molecular Formula:
C14H8F6O3S2
Molecular Weight:
402.3319
MDL Number:
MFCD00236132
SMILES:
[O-]S(=O)(=O)C(F)(F)F.FC([S+]1c2ccccc2c2c1cccc2)(F)F
Properties
Properties
 
Form:
Solid  
MP:
155 °C  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
412  
Covalently-Bonded Unit Count:
2  
Defined Atom Stereocenter Count:
0  
Defined Bond Stereocenter Count:
0  
Formal Charge:
0  
Heavy Atom Count:
25  
Hydrogen Bond Acceptor Count:
9  
Hydrogen Bond Donor Count:
0  
Isotope Atom Count:
0  
Rotatable Bond Count:
0  
Undefined Atom Stereocenter Count:
0  
Undefined Bond Stereocenter Count:
0  

Upstream Synthesis Route

[1]Patent:CN108239021,2018,A,.Locationinpatent:Paragraph0060-0062

[1]ChemicalCommunications,2011,vol.47,#14,p.4300-4302

[1]ChemicalCommunications,2011,vol.47,#14,p.4300-4302

[1]JournaloftheAmericanChemicalSociety,1993,vol.115,#6,p.2156-2164

[1]JournalofFluorineChemistry,1999,vol.98,#1,p.75-81

[2]JournalofFluorineChemistry,1998,vol.92,#2,p.181-187

[3]JournaloftheAmericanChemicalSociety,1993,vol.115,#6,p.2156-2164

[4]JournaloftheAmericanChemicalSociety,1993,vol.115,#6,p.2156-2164

[5]TetrahedronLetters,1990,vol.31,#25,p.3579-3582

Downstream Synthesis Route

[1]TetrahedronLetters,1990,vol.31,p.3579-3582

[1]JournaloftheAmericanChemicalSociety,1993,vol.115,p.2156-2164

[1]Umemoto,Teruo;Adachi,Kenji[JournalofOrganicChemistry,1994,vol.59,#19,p.5692-5699]

[1]Locationinpatent:schemeortableXu,Jun;Luo,Dong-Fen;Xiao,Bin;Liu,Zhao-Jing;Gong,Tian-Jun;Fu,Yao;Liu,Lei[ChemicalCommunications,2011,vol.47,#14,p.4300-4302]

[1]Locationinpatent:schemeortableXu,Jun;Luo,Dong-Fen;Xiao,Bin;Liu,Zhao-Jing;Gong,Tian-Jun;Fu,Yao;Liu,Lei[ChemicalCommunications,2011,vol.47,#14,p.4300-4302]

Literature
Application
5-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate is a compound instrumental in Pd(II)-catalyzed trifluoromethylation reactions. It facilitates electrophilic trifluoromethylation processes in ionic liquids. Additionally, it is utilized in the stereoselective preparation of trifluoromethylalkynes, achieved through trifluoromethylation of terminal alkynes using Umemoto′s reagent and a copper catalyst. This compound's role lies in enabling efficient and selective trifluoromethylation transformations, contributing to advancements in synthetic methodologies and the synthesis of fluorinated organic molecules.
Quotation Request
Company Name:
*
Contact Person:
*
Email:
*
Quantity Required:
*
Country:
Additional Info:
Submit
SDS
Related Products of 129946-88-9
129946-88-9

129946-88-9
Building Blocks
More >
Historical Records
1148027-30-8

1148027-30-8

 922076-28-6

922076-28-6

 618441-62-6

618441-62-6

 2034592-86-2

2034592-86-2
Tags:129946-88-9 Molecular Formula|129946-88-9 MDL|129946-88-9 SMILES|129946-88-9 S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate
Catalog No.: AA000TQB
129946-88-9,MFCD00236132
129946-88-9 | S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate
Pack Size： 250mg
Purity： 97%
in stock
$26.00 $19.00
Pack Size： 1g
Purity： 97%
in stock
$72.00 $50.00
Pack Size： 5g
Purity： 97%
in stock
$285.00 $200.00
Pack Size： 25g
Purity： 97%
in stock
$1,235.00 $865.00
Quantity
- +
Add to Card
Order Now
bulk Quotation Request
Technical Information
Catalog Number: AA000TQB
Chemical Name: S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate
CAS Number: 129946-88-9
Molecular Formula: C14H8F6O3S2
Molecular Weight: 402.3319
MDL Number: MFCD00236132
SMILES: [O-]S(=O)(=O)C(F)(F)F.FC([S+]1c2ccccc2c2c1cccc2)(F)F
Properties
Form: Solid  
MP: 155 °C  
Storage: Keep in dry area;Room Temperature;  
Complexity: 412  
Covalently-Bonded Unit Count: 2  
Defined Atom Stereocenter Count: 0  
Defined Bond Stereocenter Count: 0  
Formal Charge: 0  
Heavy Atom Count: 25  
Hydrogen Bond Acceptor Count: 9  
Hydrogen Bond Donor Count: 0  
Isotope Atom Count: 0  
Rotatable Bond Count: 0  
Undefined Atom Stereocenter Count: 0  
Undefined Bond Stereocenter Count: 0  
Upstream Synthesis Route
109-04-6    129946-88-9    368-48-9 

[1]Patent:CN108239021,2018,A,.Locationinpatent:Paragraph0060-0062

89466-08-0    129946-88-9    444-30-4 

[1]ChemicalCommunications,2011,vol.47,#14,p.4300-4302

129946-88-9    1801-10-1 

[1]ChemicalCommunications,2011,vol.47,#14,p.4300-4302

1493-13-6    129922-51-6    129946-88-9 

[1]JournaloftheAmericanChemicalSociety,1993,vol.115,#6,p.2156-2164

129922-51-6    129946-88-9 

[1]JournalofFluorineChemistry,1999,vol.98,#1,p.75-81

[2]JournalofFluorineChemistry,1998,vol.92,#2,p.181-187

[3]JournaloftheAmericanChemicalSociety,1993,vol.115,#6,p.2156-2164

[4]JournaloftheAmericanChemicalSociety,1993,vol.115,#6,p.2156-2164

[5]TetrahedronLetters,1990,vol.31,#25,p.3579-3582

Downstream Synthesis Route
129946-88-9    26960-77-0    2757-37-1    129922-44-7 

[1]TetrahedronLetters,1990,vol.31,p.3579-3582

129946-88-9    112-55-0    2757-37-1    129922-44-7 

[1]JournaloftheAmericanChemicalSociety,1993,vol.115,p.2156-2164

129946-88-9    93-55-0    128271-44-3 

[1]Umemoto,Teruo;Adachi,Kenji[JournalofOrganicChemistry,1994,vol.59,#19,p.5692-5699]

5122-94-1    142-71-2    129946-88-9    92-52-4    148-86-7    135-70-6    398-36-7 

[1]Locationinpatent:schemeortableXu,Jun;Luo,Dong-Fen;Xiao,Bin;Liu,Zhao-Jing;Gong,Tian-Jun;Fu,Yao;Liu,Lei[ChemicalCommunications,2011,vol.47,#14,p.4300-4302]

5122-94-1    142-71-2    129946-88-9    148-86-7    135-70-6    398-36-7 

[1]Locationinpatent:schemeortableXu,Jun;Luo,Dong-Fen;Xiao,Bin;Liu,Zhao-Jing;Gong,Tian-Jun;Fu,Yao;Liu,Lei[ChemicalCommunications,2011,vol.47,#14,p.4300-4302]

Application fold 
5-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate is a compound instrumental in Pd(II)-catalyzed trifluoromethylation reactions. It facilitates electrophilic trifluoromethylation processes in ionic liquids. Additionally, it is utilized in the stereoselective preparation of trifluoromethylalkynes, achieved through trifluoromethylation of terminal alkynes using Umemoto′s reagent and a copper catalyst. This compound's role lies in enabling efficient and selective trifluoromethylation transformations, contributing to advancements in synthetic methodologies and the synthesis of fluorinated organic molecules.
Related Products of of 129946-88-9
129946-88-9
129946-88-9
Building Blocks More >
130205-11-7
130205-11-7
3-(1-Naphthylmethoxy)benzaldehyde
AA000U2J | MFCD04227160
13042-33-6
13042-33-6
Glycine, N-[(3α,5β,6α)-3,6-dihydroxy-24-oxocholan-24-yl]-
AA000UCK | MFCD00200631
130673-36-8
130673-36-8
4-Hydrazino-4-oxobutanamide
AA000UP2 | MFCD00984930
128013-69-4
128013-69-4
Hexanoic acid, 3-(aminomethyl)-5-methyl-
AA000V0O | MFCD00906155
1310383-98-2
1310383-98-2
1,5-Dimethyl-1h-indazole-6-boronic acid
AA000VBA | MFCD12028659
131172-64-0
131172-64-0
4,5,6,7-Tetrahydro-1h-indole-2-carboxylic acid
AA000VKT | MFCD01101168
1313738-64-5
1313738-64-5
1-Methylindazole-7-boronic acid pinacol ester
AA000VYE | MFCD15071446
1314985-57-3
1314985-57-3
1-BOC-3-Ethoxyazetidine
AA000W9D | MFCD06246886
1271-51-8
1271-51-8
Vinylferrocene
AA000WLE | MFCD30580682
127348-02-1
127348-02-1
H-D-Cys(mbzl)-oh
AA000WV9 | MFCD00236945
Historical Records
1148027-30-8
1148027-30-8
922076-28-6
922076-28-6
618441-62-6
618441-62-6
2034592-86-2
2034592-86-2
Submit
© 2017 AA BLOCKS, INC. All rights reserved.