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14024-58-9,MFCD00000022
Catalog No.:AA003RD5

14024-58-9 | Manganese(II) bis(acetylacetonate)

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5g
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003RD5
Chemical Name:
Manganese(II) bis(acetylacetonate)
CAS Number:
14024-58-9
Molecular Formula:
C10H14MnO4
Molecular Weight:
253.1538
MDL Number:
MFCD00000022
SMILES:
[O-]/C(=C\C(=O)C)/C.[O-]/C(=C\C(=O)C)/C.[Mn+2]
Properties
Properties
 
BP:
187.6°C at 760 mmHg  
Form:
Solid  
MP:
248-250 °C (dec.)(lit.)  
Solubility:
11.5g/l  
Stability:
Hygroscopic  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
90.4  
Covalently-Bonded Unit Count:
3  
Defined Bond Stereocenter Count:
2  
Heavy Atom Count:
15  
Hydrogen Bond Acceptor Count:
4  
Rotatable Bond Count:
2  

Downstream Synthesis Route
14024-18-1    14024-58-9   
zincbis(2,4-pentanedionate)monohydrate 
 
Mn(1-x)Zn(x)Fe2O4x:0-1; 

[1]Itoh,Hideaki;Yamaguchi,Hirofumi;Naka,Shigeharu[NipponKagakuKaishi/JournaloftheChemicalSocietyofJapan][NipponKagakuKaishi,1987,vol.62,p.2004-2005]

[1]Takeichi,Tsutomu;Sakurada,Yoshihiro;Hieda,Yoshihiro;Takayama,Yuzi[ChemistryLetters,1987,p.1301-1302]

[1]Takeichi,Tsutomu;Sakurada,Yoshihiro;Hieda,Yoshihiro;Takayama,Yuzi[ChemistryLetters,1987,p.1301-1302]

Literature

Title: Acid induced acetylacetonato replacement in biscyclometalated iridium(III) complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20120407

Title: Radioactive holmium acetylacetonate microspheres for interstitial microbrachytherapy: an in vitro and in vivo stability study.

Journal: Pharmaceutical research 20120301

Title: Ligand field-tuned single-molecule magnet behaviour of 2p-4f complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20120114

Title: Spectroscopic studies on Solvatochromism of mixed-chelate copper(II) complexes using MLR technique.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120101

Title: Voltammetric sensing of phosphoproteins using a gallium(III) acetylacetonate-modified carbon paste electrode.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20120101

Title: VO(acac)(2)/H(2)O(2)/NaI: a mild and efficient combination for the cleavage of dithioacetal derivatives of sugars.

Journal: Carbohydrate research 20111129

Title: NbO lattice MOFs based on octahedral M(II) and ditopic pyridyl substituted diketonate ligands: structure, encapsulation and guest-driven luminescent property.

Journal: Chemical communications (Cambridge, England) 20111014

Title: The direct writing of plasmonic gold nanostructures by electron-beam-induced deposition.

Journal: Advanced materials (Deerfield Beach, Fla.) 20110617

Title: Vanadyl bisacetylacetonate protects β cells from palmitate-induced cell death through the unfolded protein response pathway.

Journal: Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20110601

Title: Evaluation of electrogenerated chemiluminescence from a neutral Ir(III) complex for quantitative analysis in flowing streams.

Journal: The Analyst 20110521

Title: Solvent effect on the optical property of uranyl acetylacetonate monohydrate.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20110101

Title: Synthesis, DNA binding, photo-induced DNA cleavage and cytotoxicity studies of europium(III) complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20101128

Title: Cyclometalated red iridium(III) complexes containing carbazolyl-acetylacetonate ligands: efficiency enhancement in polymer LED devices.

Journal: Dalton transactions (Cambridge, England : 2003) 20101007

Title: Improved high-brightness efficiency of phosphorescent organic LEDs comprising emitter molecules with small permanent dipole moments.

Journal: Advanced materials (Deerfield Beach, Fla.) 20100803

Title: Fully and partially coherent pathways in multiply enhanced odd-order wave-mixing spectroscopy.

Journal: The journal of physical chemistry. A 20100121

Title: Application of Δ- and λ-isomerism of octahedral metal complexes for inducing chiral nematic phases.

Journal: International journal of molecular sciences 20091001

Title: Structure and vibrational assignment of beryllium acetylacetonate.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20090715

Title: A general approach to silicate nanoshells: gadolinium silicate and gadolinium silicate:europium nanoshells for dual-modality optical and MR imaging.

Journal: Chemical communications (Cambridge, England) 20090621

Title: Microspheres with ultrahigh holmium content for radioablation of malignancies.

Journal: Pharmaceutical research 20090601

Title: Lanthanide(III)-doped magnetite nanoparticles.

Journal: Journal of the American Chemical Society 20090513

Title: DNA cleavage activity of V IV O(acac)2 and derivatives.

Journal: Journal of inorganic biochemistry 20090401

Title: Antitumor activity of Ru(III) complexes carrying beta-diketonato ligands in vitro and in vivo.

Journal: Journal of B.U.ON. : official journal of the Balkan Union of Oncology 20090101

Title: Organometallic red-emitting chromophores: a computational and experimental study on cyclometallated Nile Red complexes of palladium(II) and platinum(II) acetylacetonates and hexafluoroacetylacetonates.

Journal: Dalton transactions (Cambridge, England : 2003) 20081214

Title: IR spectroscopic investigation of cis-(CH(3))(2)Au(O,O'-acac) and cis-(CD(3))(2)Au(O,O'-acac).

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20081201

Title: Acetylacetonate anchors for robust functionalization of TiO2 nanoparticles with Mn(II)-terpyridine complexes.

Journal: Journal of the American Chemical Society 20081029

Title: Spectroscopy and electrochemical properties of a homologous series of acetylacetonato and hexafluoroacetylacetonato cyclopalladated and cycloplatinated complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20080828

Title: Vanadyl bisacetylacetonate induced G1/S cell cycle arrest via high-intensity ERK phosphorylation in HepG2 cells.

Journal: Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20080801

Title: Synthesis of homogeneous FePt nanoparticles using a nitrile ligand.

Journal: Small (Weinheim an der Bergstrasse, Germany) 20080801

Title: Holmium-loaded PLLA nanoparticles for intratumoral radiotherapy via the TMT technique: preparation, characterization, and stability evaluation after neutron irradiation.

Journal: Drug development and industrial pharmacy 20080801

Title: The influence of pore size on colonization of poly(L-lactide-glycolide) scaffolds with human osteoblast-like MG 63 cells in vitro.

Journal: Journal of materials science. Materials in medicine 20080101

Title: Copper acetylacetonate anchored onto amine-functionalised clays.

Journal: Journal of colloid and interface science 20071215

Title: Cobalt-catalyzed cross-coupling of alkynyl Grignard reagents with alkenyl triflates.

Journal: Chemical communications (Cambridge, England) 20071121

Title: New platinum(II) complexes containing both an O,O'-chelated acetylacetonate ligand and a sulfur ligand in the platinum coordination sphere induce apoptosis in HeLa cervical carcinoma cells.

Journal: Biochemical pharmacology 20070630

Title: Effects on the bones of vanadyl acetylacetonate by oral administration: a comparison study in diabetic rats.

Journal: Journal of bone and mineral metabolism 20070101

Title: Iron-oxide-modified nanosized diamond: preparation, characterization, and catalytic properties in methanol decomposition.

Journal: Journal of colloid and interface science 20061015

Title: Organized and highly dispersed growth of MnO2 nano-rods by sonochemical hydrolysis of Mn3acetate.

Journal: Ultrasonics sonochemistry 20060901

Title: Studies of interaction between Rh(I) and human serum albumin in a 'nanostructured biocatalyst' active in the hydroformylation reaction.

Journal: Journal of inorganic biochemistry 20060901

Title: Controlled synthesis of highly dispersed platinum nanoparticles in ordered mesoporous carbons.

Journal: Chemical communications (Cambridge, England) 20060828

Title: Facile light-triggered one-step synthesis of small and stable platinum nanoparticles in an aqueous medium from a beta-cyclodextrin host-guest inclusion complex.

Journal: Inorganic chemistry 20060123

Title: Photoacoustic phase study on the frequency dependence of phase angle and triplet state lifetime of Nd(III)-acetylacetonate.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20060101

Title: Structure and relaxation dynamics of poly(amide urethane)s with bioactive transition metal acetyl acetonates in hard blocks.

Journal: The European physical journal. E, Soft matter 20051201

Title: Pharmacodynamics and pharmacokinetics of the insulin-mimetic agent vanadyl acetylacetonate in non-diabetic and diabetic rats.

Journal: Journal of inorganic biochemistry 20050501

Title: Layer-by-layer assembly of ordinary and composite coordination multilayers.

Journal: Langmuir : the ACS journal of surfaces and colloids 20041123

Title: Synthesis, characterization, and detailed electrochemistry of binuclear ruthenium(III) complexes bridged by bisacetylacetonate. Crystal and molecular structures of [[Ru(acac)2]2(tae)] (acac = 2,4-pentanedionate ion, tae = 1,1,2,2-tetraacetylethanate dianion).

Journal: Inorganic chemistry 20041004

Title: Spectroscopic studies on charge-transfer complexes formed in the reaction of ferric(III) acetylacetonate with sigma- and pi-acceptors.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20040601

Title: The permeability and cytotoxicity of insulin-mimetic vanadium compounds.

Journal: Pharmaceutical research 20040601

Title: Influence of neutron irradiation on holmium acetylacetonate loaded poly(L-lactic acid) microspheres.

Journal: Biomaterials 20020401

Title: Preparation of the addition products of alpha-tocopherol with cholesteryl linoleate-peroxyl radicals.

Journal: Bioscience, biotechnology, and biochemistry 20020301

Title: Iron-catalyzed reaction products of alpha-tocopherol with 1-palmitoyl-2-linoleoyl-3-sn-phosphatidylcholine (13S)-hydroperoxide.

Journal: Chemistry and physics of lipids 20020201

Title: Characterization of poly(L-lactic acid) microspheres loaded with holmium acetylacetonate.

Journal: Biomaterials 20011101

Title: Density functional theory study of the fourier transform infrared and Raman spectra of dichloro-bis(2,4-pentanedionate)tin(IV).

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20010501

Title: X-ray structure, solution properties, and biological activity profile of vanadocene(IV) acetylacetonate complex,

Journal: Journal of inorganic biochemistry 20010401

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