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1436-34-6,MFCD00005154
Catalog No.:AA003DCD

1436-34-6 | 1,2-EPOXYHEXANE

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Purity
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Price(USD)
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1g
96%
in stock  
$29.00   $20.00
- +
5g
96%
in stock  
$62.00   $44.00
- +
25g
96%
in stock  
$170.00   $119.00
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100g
96%
in stock  
$544.00   $381.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003DCD
Chemical Name:
1,2-EPOXYHEXANE
CAS Number:
1436-34-6
Molecular Formula:
C6H12O
Molecular Weight:
100.1589
MDL Number:
MFCD00005154
SMILES:
CCCCC1CO1
Properties
Properties
 
BP:
118-120 °C(lit.)  
Form:
Liquid  
MP:
94°C  
Refractive Index:
n20/D 1.406  
Solubility:
Difficult to mix.  
Storage:
2-8℃;  

Computed Properties
 
Complexity:
52.1  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
1  
Rotatable Bond Count:
3  
Undefined Atom Stereocenter Count:
1  
XLogP3:
1.9  

Downstream Synthesis Route

[1]HelveticaChimicaActa,1991,vol.74,p.1500-1510

1436-34-6    64318-28-1   
{2-4-(2-hydroxy-hexyloxy)-phenyl-ethyl}-carbamicacid<i>tert</i>-butylester 

[1]JournaloftheAmericanChemicalSociety,1999,vol.121,p.6086-6087

1436-34-6    2916-68-9   
(S)-1-(2-trimethylsilylethoxy)-2-hexanol 

[1]Ready,JosephM.;Jacobsen,EricN.[AngewandteChemie-InternationalEdition,2002,vol.41,#8,p.1374-1377]

[2]Ready;Jacobsen[JournaloftheAmericanChemicalSociety,2001,vol.123,#11,p.2687-2688]

1436-34-6    18982-54-2   
(S)-1-(2-bromobenzyloxy)-2-hexanol 

[1]Ready;Jacobsen[JournaloftheAmericanChemicalSociety,2001,vol.123,#11,p.2687-2688]

[2]Locationinpatent:schemeortableZhu,Xunjin;Venkatasubbaiah,Krishnan;Weck,Marcus;Jones,ChristopherW.[JournalofMolecularCatalysisA:Chemical,2010,vol.329,#1-2,p.1-6]

[1]Schneider,Christoph;Brauner,Jörg[EuropeanJournalofOrganicChemistry,2001,#23,p.4445-4450]

Literature

Title: Development of a whole-cell biocatalyst co-expressing P450 monooxygenase and glucose dehydrogenase for synthesis of epoxyhexane.

Journal: Applied microbiology and biotechnology 20120701

Title: Cloning and characterization of an epoxide hydrolase from Cupriavidus metallidurans-CH34.

Journal: Protein expression and purification 20110901

Title: Aluminum nanoparticles capped by polymerization of alkyl-substituted epoxides: ratio-dependent stability and particle size.

Journal: Inorganic chemistry 20110606

Title: Olefin metathesis as a tool for multinuclear Co(III)salen catalyst construction: access to cooperative catalysts.

Journal: Dalton transactions (Cambridge, England : 2003) 20100114

Title: Capping and passivation of aluminum nanoparticles using alkyl-substituted epoxides.

Journal: Langmuir : the ACS journal of surfaces and colloids 20090818

Title: Amphiphilic polymers based on higher alkylene oxides Synthesis and characterization by different chromatographic techniques.

Journal: Journal of chromatography. A 20090213

Title: An exploration of the coupling reactions of epoxides and carbon dioxide catalyzed by tetramethyltetraazaannulene chromium(III) derivatives: formation of copolymers versus cyclic carbonates.

Journal: Inorganic chemistry 20081215

Title: New method for determination of epichlorohydrin in epoxy-coated cans by oxolane derivatization and gas chromatography-mass spectrometry.

Journal: Journal of chromatography. A 20080801

Title: A cold-adapted epoxide hydrolase from a strict marine bacterium, Sphingophyxis alaskensis.

Journal: Journal of microbiology and biotechnology 20080801

Title: Improved catalytic activity of homochiral dimeric cobalt-salen complex in hydrolytic kinetic resolution of terminal racemic epoxides.

Journal: Chirality 20051101

Title: Active site engineering of the epoxide hydrolase from Agrobacterium radiobacter AD1 to enhance aerobic mineralization of cis-1,2-dichloroethylene in cells expressing an evolved toluene ortho-monooxygenase.

Journal: The Journal of biological chemistry 20041105

Title: Directed evolution of epoxide hydrolase from A. radiobacter toward higher enantioselectivity by error-prone PCR and DNA shuffling.

Journal: Chemistry & biology 20040701

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Tags:1436-34-6 Molecular Formula|1436-34-6 MDL|1436-34-6 SMILES|1436-34-6 1,2-EPOXYHEXANE