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1439-36-7,MFCD00008774
Catalog No.:AA00324M

1439-36-7 | (Acetylmethylene)triphenylphosphorane

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Purity
Availability
Price(USD)
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5g
98%
in stock  
$6.00   $4.00
- +
10g
98%
in stock  
$7.00   $5.00
- +
25g
98%
in stock  
$16.00   $11.00
- +
100g
98%
in stock  
$25.00   $18.00
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500g
98%
in stock  
$90.00   $63.00
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA00324M
Chemical Name:
(Acetylmethylene)triphenylphosphorane
CAS Number:
1439-36-7
Molecular Formula:
C21H19OP
Molecular Weight:
318.3487
MDL Number:
MFCD00008774
SMILES:
CC(=O)C=P(c1ccccc1)(c1ccccc1)c1ccccc1
NSC Number:
407394
Properties
Properties
 
BP:
478.5°C at 760 mmHg  
Form:
Solid  
MP:
204-209°C  
Solubility:
Soluble in chloroform. Slightly soluble in methanol.  
Stability:
Air Sensitive  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
383  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
23  
Hydrogen Bond Acceptor Count:
1  
Rotatable Bond Count:
4  
XLogP3:
3.6  

Upstream Synthesis Route

[1]J.Gen.Chem.USSR(Engl.Transl.),1975,vol.45,p.2571-2574

[2]ZhurnalObshcheiKhimii,1975,vol.45,p.2609-2614

[1]Molecules,2018,vol.23,#9,

[2]Phosphorus,SulfurandSiliconandRelatedElements,1998,vol.143,p.33-44

[3]LiebigsAnnalenderChemie,1983,#12,p.2135-2140

Downstream Synthesis Route

[1]JournalofgeneralchemistryoftheUSSR,1970,vol.40,p.45-53    ZhurnalObshcheiKhimii,1970,vol.40,p.48-57

[2]TetrahedronLetters,2001,vol.42,p.6827-6829

[3]AngewandteChemie-InternationalEdition,2008,vol.47,p.8703-8706

[4]AngewandteChemie-InternationalEdition,2010,vol.49,p.4976-4980

[5]OrganicLetters,2015,vol.17,p.5974-5977

[6]Patent:WO2008/44127,2008,A1.Locationinpatent:Page/Pagecolumn83

[1]JournalofgeneralchemistryoftheUSSR,1975,vol.45,p.2571-2574    ZhurnalObshcheiKhimii,1975,vol.45,p.2609-2614

[1]CarbohydrateResearch,1966,vol.3,p.69-75

[2]JournalofgeneralchemistryoftheUSSR,1965,vol.35,p.183-185    ZhurnalObshcheiKhimii,1965,vol.35,p.181-183

[1]Patent:WO2003/103661,2003,A1.Locationinpatent:Page108-109

[2]JournalofChemicalResearch,Miniprint,1984,p.2801-2821

[1]ArchivderPharmazie,1983,vol.316,p.530-536

Literature

Title: Highly substituted tetrahydropyrones from hetero-Diels-Alder reactions of 2-alkenals with stereochemical induction from chiral dienes.

Journal: The Journal of organic chemistry 20050401

Title: Towards organo-click chemistry: development of organocatalytic multicomponent reactions through combinations of aldol, Wittig, Knoevenagel, Michael, Diels-Alder and Huisgen cycloaddition reactions.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20041025

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SDS
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