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21087-64-9,MFCD00055525
Catalog No.:AA007P17

21087-64-9 | 4-Amino-6-(tert-butyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one

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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA007P17
Chemical Name:
4-Amino-6-(tert-butyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one
CAS Number:
21087-64-9
Molecular Formula:
C8H14N4OS
Molecular Weight:
214.2880
MDL Number:
MFCD00055525
SMILES:
CSc1nnc(c(=O)n1N)C(C)(C)C
UN Number:
3077
Properties
Computed Properties
 
Complexity:
316  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
14  
Hydrogen Bond Acceptor Count:
5  
Hydrogen Bond Donor Count:
1  
Rotatable Bond Count:
2  
XLogP3:
1.7  

Literature

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Journal: Archives of environmental contamination and toxicology 20121101

Title: Spectroscopic investigation and hydrogen-bonding analysis of triazinones.

Journal: Journal of molecular modeling 20120801

Title: Rapid effects of diverse toxic water pollutants on chlorophyll a fluorescence: variable responses among freshwater microalgae.

Journal: Water research 20120515

Title: The effects of pesticide mixtures on degradation of pendimethalin in soils.

Journal: Environmental monitoring and assessment 20120501

Title: Biodegradation of soil-applied pesticides by selected strains of plant growth-promoting rhizobacteria (PGPR) and their effects on bacterial growth.

Journal: Biodegradation 20120401

Title: Absorption, translocation and metabolism of metamitron in Chenopodium album.

Journal: Pest management science 20120201

Title: Effect of fly ash on sorption behavior of metribuzin in agricultural soils.

Journal: Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes 20120101

Title: Evaluation of genotoxic and cytotoxic effects in human peripheral blood lymphocytes exposed in vitro to neonicotinoid insecticides news.

Journal: Journal of toxicology 20120101

Title: The effects of subchronic exposure to terbuthylazine on early developmental stages of common carp.

Journal: TheScientificWorldJournal 20120101

Title: The effects of subchronic exposure to metribuzin on Danio rerio.

Journal: TheScientificWorldJournal 20120101

Title: [Pesticide residues in drinking water of an agricultural community in the state of Mérida, Venezuela].

Journal: Investigacion clinica 20111201

Title: Simultaneous determination of triazine herbicides in rice by high-performance liquid chromatography coupled with high resolution and high mass accuracy hybrid linear ion trap-orbitrap mass spectrometry.

Journal: Analytica chimica acta 20111107

Title: Effects of an anionic surfactant (FFD-6) on the energy and information flow between a primary producer (Scenedesmus obliquus) and a consumer (Daphnia magna).

Journal: Ecotoxicology (London, England) 20111101

Title: Suicide and pesticide use among pesticide applicators and their spouses in the agricultural health study.

Journal: Environmental health perspectives 20111101

Title: Toxicological assessment of selective pesticides towards plant growth promoting activities of phosphate solubilizing Pseudomonas aeruginosa.

Journal: Acta microbiologica et immunologica Hungarica 20110901

Title: Quantification of triazine herbicides in soil by microwave-assisted extraction and high-performance liquid chromatography.

Journal: Environmental monitoring and assessment 20110701

Title: Ecotoxicological assessment of pesticides towards the plant growth promoting activities of Lentil (Lens esculentus)-specific Rhizobium sp. strain MRL3.

Journal: Ecotoxicology (London, England) 20110601

Title: Biochemical markers of contamination in fish toxicity tests.

Journal: Interdisciplinary toxicology 20110601

Title: Effect of pesticides on plant growth promoting traits of greengram-symbiont, Bradyrhizobium sp. strain MRM6.

Journal: Bulletin of environmental contamination and toxicology 20110401

Title: Metribuzin transport in undisturbed soil cores under controlled water potential conditions: experiments and modelling to evaluate the risk of leaching in a sandy loam soil profile.

Journal: Pest management science 20110401

Title: Reduced metribuzin pollution with phosphatidylcholine-clay formulations.

Journal: Pest management science 20110301

Title: Toxicological effects of selective herbicides on plant growth promoting activities of phosphate solubilizing Klebsiella sp. strain PS19.

Journal: Current microbiology 20110201

Title: Evaluation of buffer zone effectiveness in mitigating the risks associated with agricultural runoff in Prince Edward Island.

Journal: The Science of the total environment 20110201

Title: Metribuzin impairs the unicell-colony transformation in the green alga Scenedesmus obliquus.

Journal: Chemosphere 20110101

Title: [Analysis of metribuzin and its metabolites in livestock products and seafoods by liquid chromatography-tandem mass spectrometry].

Journal: Shokuhin eiseigaku zasshi. Journal of the Food Hygienic Society of Japan 20110101

Title: Comparative losses of glyphosate and selected residual herbicides in surface runoff from conservation-tilled watersheds planted with corn or soybean.

Journal: Journal of environmental quality 20110101

Title: Synthesis and SAR studies of 1,4-benzoxazine MenB inhibitors: novel antibacterial agents against Mycobacterium tuberculosis.

Journal: Bioorganic & medicinal chemistry letters 20101101

Title: Residue and bio-efficacy evaluation of controlled release formulations of metribuzin against weeds in wheat.

Journal: Bulletin of environmental contamination and toxicology 20100901

Title: A 75% reduction in herbicide use through integration with sorghum + sunflower extracts for weed management in wheat.

Journal: Journal of the science of food and agriculture 20100830

Title: A review of pesticide exposure and cancer incidence in the Agricultural Health Study cohort.

Journal: Environmental health perspectives 20100801

Title: Caffeine and agricultural pesticide concentrations in surface water and groundwater on the north shore of Kauai (Hawaii, USA).

Journal: Marine pollution bulletin 20100801

Title: Novel biomixtures based on local Mediterranean lignocellulosic materials: evaluation for use in biobed systems.

Journal: Chemosphere 20100801

Title: Toxicity of the herbicide atrazine: effects on lipid peroxidation and activities of antioxidant enzymes in the freshwater fish Channa punctatus (Bloch).

Journal: International journal of environmental research and public health 20100801

Title: Pesticide use and cutaneous melanoma in pesticide applicators in the agricultural heath study.

Journal: Environmental health perspectives 20100601

Title: Prevention of chloridazon and metribuzin pollution using lignin-based formulations.

Journal: Environmental pollution (Barking, Essex : 1987) 20100501

Title: Controlled release formulations of metribuzin: release kinetics in water and soil.

Journal: Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes 20100501

Title: Assessment of heavy metal and pesticide levels in soil and plant products from agricultural area of Belgrade, Serbia.

Journal: Archives of environmental contamination and toxicology 20100201

Title: Fate and effect of linuron and metribuzin on the co-composting of green waste and sewage sludge.

Journal: Waste management (New York, N.Y.) 20100101

Title: Chlorophyll fluorescence protocol for quick detection of triazinone resistant Chenopodium album L.

Journal: Communications in agricultural and applied biological sciences 20100101

Title: Chemometric study and optimization of extraction parameters in single-drop microextraction for the determination of multiclass pesticide residues in grapes and apples by gas chromatography mass spectrometry.

Journal: Journal of chromatography. A 20091106

Title: Adsorption of herbicides on coal fly ash from aqueous solutions.

Journal: Journal of hazardous materials 20090830

Title: Occupational exposure to metribuzin and the incidence of cancer in the Agricultural Health Study.

Journal: Annals of epidemiology 20090601

Title: Extractive spectrophotometric method for determination of metribuzin herbicide and application of factorial design in optimization of various factors.

Journal: Journal of hazardous materials 20090530

Title: Ability of the MACRO model to predict long-term leaching of metribuzin and diketometribuzin.

Journal: Environmental science & technology 20090501

Title: Synthesis and structure--activity relationships of substituted cinnamic acids and amide analogues: a new class of herbicides.

Journal: Journal of agricultural and food chemistry 20090422

Title: Effects of soil characteristics on metribuzin dissipation using clay-gel-based formulations.

Journal: Journal of agricultural and food chemistry 20090422

Title: Effects of acute exposure to metribuzin on some hematological, biochemical and histopathological parameters of common carp (Cyprinus carpio L.).

Journal: Bulletin of environmental contamination and toxicology 20090401

Title: Comparison between the short-term and the long-term toxicity of six triazine herbicides on photobacteria Q67.

Journal: Water research 20090401

Title: Application of the electrosorption technique to remove Metribuzin pesticide.

Journal: Journal of hazardous materials 20090130

Title: Use of semipermeable membrane devices for monitoring pesticides in indoor air.

Journal: Journal of AOAC International 20090101

Title: The watershed as a conceptual framework for the study of environmental and human health.

Journal: Environmental health insights 20090101

Title: Novel system for reducing leaching of the herbicide metribuzin using clay-gel-based formulations.

Journal: Journal of agricultural and food chemistry 20081224

Title: Variation of MCPA, metribuzine, methyltriazine-amine and glyphosate degradation, sorption, mineralization and leaching in different soil horizons.

Journal: Environmental pollution (Barking, Essex : 1987) 20081201

Title: S-ethyl-N,N-dipropylthiocarbamate exposure and cancer incidence among male pesticide applicators in the agricultural health study: a prospective cohort.

Journal: Environmental health perspectives 20081101

Title: Biocompost from sugar distillery effluent: effect on metribuzin degradation, sorption and mobility.

Journal: Pest management science 20081001

Title: Effects of subchronic metribuzin exposure on common carp (Cyprinus carpio).

Journal: Neuro endocrinology letters 20081001

Title: Influence of Asian and Western United states agricultural areas and fires on the atmospheric transport of pesticides in the Western United States.

Journal: Environmental science & technology 20080901

Title: Pesticide levels in ground and surface waters of Primavera do Leste Region, Mato Grosso, Brazil.

Journal: Journal of chromatographic science 20080801

Title: Incident diabetes and pesticide exposure among licensed pesticide applicators: Agricultural Health Study, 1993-2003.

Journal: American journal of epidemiology 20080515

Title: Aquatic risk assessment of herbicides in freshwater ecosystems of South Florida.

Journal: Archives of environmental contamination and toxicology 20080501

Title: Effects of possible endocrine disruptors on MyD88-independent TLR4 signaling.

Journal: FEMS immunology and medical microbiology 20080301

Title: Impact of glyphosate-tolerant soybean and glufosinate-tolerant corn production on herbicide losses in surface runoff.

Journal: Journal of environmental quality 20080101

Title: A rapid multi-residue determination method of herbicides in grain by GC-MS-SIM.

Journal: Journal of chromatographic science 20080101

Title: Field-scale variation in microbial activity and soil properties in relation to mineralization and sorption of pesticides in a sandy soil.

Journal: Journal of environmental quality 20080101

Title: Impact of basic soil parameters on pesticide disappearance investigated by multivariate partial least square regression and statistics.

Journal: Journal of environmental quality 20080101

Title: Resistance of Chenopodium albumto photosystem II-inhibitors.

Journal: Communications in agricultural and applied biological sciences 20080101

Title: Chlorophyll fluorescence tests for monitoring triazinone resistance in Chenopodium album L.

Journal: Communications in agricultural and applied biological sciences 20080101

Title: Interactions between population density of the Colorado potato beetle, Leptinotarsa decemlineata, and herbicide rate for suppression of solanaceous weeds.

Journal: Journal of insect science (Online) 20080101

Title: Online in situ analysis of selected semi-volatile organic compounds in water by automated microscale solid-phase extraction with large-volume injection/gas chromatography/mass spectrometry.

Journal: Journal of chromatography. A 20071228

Title: [Determination of six pesticides in milk using cloud point extraction-high performance liquid chromatography].

Journal: Se pu = Chinese journal of chromatography 20071101

Title: Modifying sorbents in controlled release formulations to prevent herbicides pollution.

Journal: Chemosphere 20071001

Title: Assessing exposure to atrazine and its metabolites using biomonitoring.

Journal: Environmental health perspectives 20071001

Title: Large volume sample stacking in capillary zone electrophoresis for the monitoring of the degradation products of metribuzin in environmental samples.

Journal: Journal of chromatography. A 20070914

Title: Metabolic activation of herbicide products by Vicia faba detected in human peripheral lymphocytes using alkaline single cell gel electrophoresis.

Journal: Toxicology in vitro : an international journal published in association with BIBRA 20070901

Title: Pesticides in surface drinking-water supplies of the northern Great Plains.

Journal: Environmental health perspectives 20070801

Title: Factors influencing degradation of pesticides in soil.

Journal: Journal of agricultural and food chemistry 20070530

Title: Effect of soil amendments on sorption and mobility of metribuzin in soils.

Journal: Chemosphere 20070101

Title: Prediction of estrogen receptor agonists and characterization of associated molecular descriptors by statistical learning methods.

Journal: Journal of molecular graphics & modelling 20061101

Title: On the way to cyanobacterial blooms: impact of the herbicide metribuzin on the competition between a green alga (Scenedesmus) and a cyanobacterium (Microcystis).

Journal: Chemosphere 20061001

Title: Effects of possible endocrine disrupting chemicals on bacterial component-induced activation of NF-kappaB.

Journal: Biological & pharmaceutical bulletin 20061001

Title: psbA mutation (Asn266 to Thr) in Senecio vulgaris L. confers resistance to several PS II-inhibiting herbicides.

Journal: Pest management science 20060901

Title: Proximity to crops and residential exposure to agricultural herbicides in iowa.

Journal: Environmental health perspectives 20060601

Title: Metribuzin mobility in soil columns as affected by urea fertiliser.

Journal: Pest management science 20060501

Title: Comparative sensitivity of green algae to herbicides using erlenmeyer flask and microplate growth-inhibition assays.

Journal: Bulletin of environmental contamination and toxicology 20060501

Title: Ecological impact in ditch mesocosms of simulated spray drift from a crop protection program for potatoes.

Journal: Integrated environmental assessment and management 20060401

Title: Ambient air concentrations of pesticides used in potato cultivation in Prince Edward Island, Canada.

Journal: Pest management science 20060201

Title: Triazine adsorption by saponite and beidellite clay minerals.

Journal: Environmental toxicology and chemistry 20060201

Title: Determination of the herbicide metribuzin and its major conversion products in soil by micellar electrokinetic chromatography.

Journal: Journal of chromatography. A 20060113

Title: Reduced downward mobility of metolachlor and metribuzin from surfactant-modified clays.

Journal: Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes 20060101

Title: Degradation of metribuzin in two soil types of Lebanon.

Journal: Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes 20060101

Title: Stability of pesticides on solid-phase extraction disks after incubation at various temperatures and for various time intervals: interlaboratory study.

Journal: Journal of AOAC International 20060101

Title: Tillage system, application rate, and extreme event effects on herbicide losses in surface runoff.

Journal: Journal of environmental quality 20060101

Title: Novel formulation for enhancing efficiency of metribuzin.

Journal: Communications in agricultural and applied biological sciences 20060101

Title: Metamitron-resistant Chenopodium album from sugar beet: cross-resistance profile.

Journal: Communications in agricultural and applied biological sciences 20060101

Title: Possibilities of chemical weed control in Lupinus albus and Lupinus luteus-screening of herbicides.

Journal: Communications in agricultural and applied biological sciences 20060101

Title: Effect of pre-emergence herbicides on growth parameters of green pea.

Journal: Communications in agricultural and applied biological sciences 20060101

Title: Impact of rainfall intensity on the transport of two herbicides in undisturbed grassed filter strip soil cores.

Journal: Journal of contaminant hydrology 20051201

Title: A psbA mutation in Kochia scoparia (L) Schrad from railroad rights-of-way with resistance to diuron, tebuthiuron and metribuzin.

Journal: Pest management science 20051101

Title: Agricultural pesticide use and risk of glioma in Nebraska, United States.

Journal: Occupational and environmental medicine 20051101

Title: Leaching of metribuzin metabolites and the associated contamination of a sandy Danish aquifer.

Journal: Environmental science & technology 20051101

Title: Characterizing exposures to nonpersistent pesticides during pregnancy and early childhood in the National Children's Study: a review of monitoring and measurement methodologies.

Journal: Environmental health perspectives 20050801

Title: Accelerators increase permeability of cuticles for the lipophilic solutes metribuzin and iprovalicarb but not for hydrophilic methyl glucose.

Journal: Journal of agricultural and food chemistry 20050406

Title: Promutagen activation of triazine herbicides metribuzin and ametryn through Vicia faba metabolism inducing sister chromatid exchanges in human lymphocytes in vitro and in V. faba root tip meristems.

Journal: Toxicology in vitro : an international journal published in association with BIBRA 20050301

Title: Population dynamics of Digitaria spp submitted to selection pressure by herbicides in sugarcane crop.

Journal: Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes 20050101

Title: Pesticide retention in the watershed and in a small constructed wetland treating diffuse pollution.

Journal: Water science and technology : a journal of the International Association on Water Pollution Research 20050101

Title: Influence of frozen storage on herbicide degradation capacity in surface and subsurface sandy soils.

Journal: Environmental science & technology 20041215

Title: [Sensitivity of Chlorella vulgaris to metribuzin, puma and alachlor].

Journal: Ying yong sheng tai xue bao = The journal of applied ecology 20040901

Title: Studies on removal of metribuzin, bromacil, 2,4-D and atrazine from water by adsorption on high area carbon cloth.

Journal: Journal of hazardous materials 20040809

Title: Comparing aquatic risk assessment methods for the photosynthesis-inhibiting herbicides metribuzin and metamitron.

Journal: Environmental pollution (Barking, Essex : 1987) 20040801

Title: The binary treatment of aqueous metribuzin using anodic fenton treatment and biodegradation.

Journal: Archives of environmental contamination and toxicology 20040801

Title: Comparison of two screening bioassays, based on the frog sciatic nerve and yeast cells, for the assessment of herbicide toxicity.

Journal: Environmental toxicology and chemistry 20040501

Title: Modeling hydrology, metribuzin degradation and metribuzin transport in macroporous tilled and no-till silt loam soil using RZWQM.

Journal: Pest management science 20040301

Title: Studies on biodegradation of 2,4-D and metribuzin in soil under controlled conditions.

Journal: Bulletin of environmental contamination and toxicology 20040301

Title: Metribuzin degradation by membrane anodic Fenton treatment and its interaction with ferric ion.

Journal: Environmental science & technology 20040215

Title: Degradation and sorption of metribuzin and primary metabolites in a sandy soil.

Journal: Journal of environmental quality 20040101

Title: Residual and contact herbicide transport through field lysimeters via preferential flow.

Journal: Journal of environmental quality 20040101

Title: [Effect of zenkor on the amount of glucose and activity of gluconeogenesis enzymes in carp's (Cyprinus carpio L.) tissues at different temperatures].

Journal: Ukrains'kyi biokhimichnyi zhurnal (1999 ) 20040101

Title: Watershed vulnerability to herbicide transport in northern Missouri and southern Iowa streams.

Journal: Environmental science & technology 20031215

Title: Triazine resistance in Amaranthus tuberculatus (Moq) Sauer that is not site-of-action mediated.

Journal: Pest management science 20031001

Title: Effects of exposure duration of herbicides on natural stream periphyton communities and recovery.

Journal: Archives of environmental contamination and toxicology 20030701

Title: The F684/F735 chlorophyll fluorescence ratio: a potential tool for rapid detection and determination of herbicide phytotoxicity in algae.

Journal: Water research 20030501

Title: Exposure of leopard frogs to a pesticide mixture affects life history characteristics of the lungworm Rhabdias ranae.

Journal: Oecologia 20030501

Title: Effects of agricultural pesticides on the immune system of Rana pipiens and on its resistance to parasitic infection.

Journal: Environmental toxicology and chemistry 20030501

Title: Solid-phase extraction and sample stacking-micellar electrokinetic capillary chromatography for the determination of multiresidues of herbicides and metabolites.

Journal: Journal of chromatography. A 20030321

Title: Retention and runoff losses of atrazine and metribuzin in soil.

Journal: Journal of environmental quality 20030101

Title: Effect of airborne bromoxynil-octanoate and metribuzin on non-target plants.

Journal: Environmental pollution (Barking, Essex : 1987) 20030101

Title: Herbicide retention in soil as affected by sugarcane mulch residue.

Journal: Journal of environmental quality 20030101

Title: Screening the retention of thirteen pesticides in a small constructed wetland.

Journal: Water science and technology : a journal of the International Association on Water Pollution Research 20030101

Title: Evaluating non-equilibrum herbicides transport in undisturbed grassed buffer strips soil columns.

Journal: Communications in agricultural and applied biological sciences 20030101

Title: Investigation of the effect of soil herbicides on the growth and nutrient uptake of potato.

Journal: Communications in agricultural and applied biological sciences 20030101

Title: Atrazine and metribuzin sorption in soils of the Argentinean humid pampas.

Journal: Environmental toxicology and chemistry 20021201

Title: Photocatalytic degradation of pesticides and bio-molecules in water.

Journal: Pest management science 20021101

Title: Activity of mesotrione on resistant weeds in maize.

Journal: Pest management science 20020901

Title: Leaching of trifluralin, metolachlor, and metribuzin in a clay loam soil of Louisiana.

Journal: Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes 20020901

Title: Runoff of trifluralin, metolachlor, and metribuzin from a clay loam soil of Louisiana.

Journal: Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes 20020901

Title: Fate and effects of the triazinone herbicide metribuzin in experimental pond mesocosms.

Journal: Archives of environmental contamination and toxicology 20020801

Title: Determination of metribuzin and major conversion products in soils by microwave-assisted water extraction followed by liquid chromatographic analysis of extracts.

Journal: Journal of chromatography. A 20020712

Title: Effects of common-use pesticides on developmental and reproductive processes in Daphnia.

Journal: Toxicology and industrial health 20020601

Title: Analysis of Metribuzin and transformation products in soil by pressurized liquid extraction and liquid chromatographic-tandem mass spectrometry.

Journal: Journal of chromatography. A 20020524

Title: Redox effects on resin extraction of herbicides from soil.

Journal: Talanta 20020516

Title: Runoff and drainage losses of atrazine, metribuzin, and metolachlor in three water management systems.

Journal: Journal of environmental quality 20020101

Title: Effects of soil variability and weather conditions on pesticide leaching--a farm-level evaluation.

Journal: Journal of environmental quality 20020101

Title: Pesticides in surface water, sediment, and rainfall of the northeastern Pantanal basin, Brazil.

Journal: Journal of environmental quality 20020101

Title: Action of an algicide from a cyanobacterium, Oscillatoria laetevirens, on photosystem II.

Journal: Indian journal of experimental biology 20011201

Title: Testing a multimedia compartmental model with monitoring data.

Journal: Environmental toxicology and chemistry 20010901

Title: Electrochemical behavior and voltammetric determination of the herbicide metribuzin at mercury electrodes.

Journal: Fresenius' journal of analytical chemistry 20010801

Title: Residual fate of metribuzin on carrot (Daucus carota) crop.

Journal: Bulletin of environmental contamination and toxicology 20010501

Title: Removal of herbicides from liquid media by fungi isolated from a contaminated soil.

Journal: Journal of environmental quality 20010101

Title: Tillage, intercrop, and controlled drainage-subirrigation influence atrazine, metribuzin, and metolachlor loss.

Journal: Journal of environmental quality 20010101

Title: [Specific density of leaf as a characteristic of the photosynthetic apparatus].

Journal: Prikladnaia biokhimiia i mikrobiologiia 20010101

Title: Fatty acid alteration of plastidic and extra-plastidic membrane lipids in metribuzin-resistant photoautotrophic Chenopodium rubrum cells as compared to wild-type cells.

Journal: Zeitschrift fur Naturforschung. C, Journal of biosciences 20010101

Title: Carbohydrate, protein and glycoprotein metabolism by the guinea-pig liver in chronic metribuzin poisoning.

Journal: Acta biologica Hungarica 19850101

Title: Whitney Pilcher, et al. Genome-wide Microarray Analysis Leads to Identification of Genes in Response to Herbicide, Metribuzin in Wheat Leaves. PLoS One. 2017 Dec 11;12(12):e0189639.

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SDS
Tags:21087-64-9 Molecular Formula|21087-64-9 MDL|21087-64-9 SMILES|21087-64-9 4-Amino-6-(tert-butyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one