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Home Amines 213843-90-4
213843-90-4,MFCD04117685
Catalog No.:AA003BO3

213843-90-4 | (3Ar,8ar)-(-)-(2,2-dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

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Price(USD)
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100mg
98%
in stock  
$31.00   $22.00
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250mg
98%
in stock  
$75.00   $53.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
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  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003BO3
Chemical Name:
(3Ar,8ar)-(-)-(2,2-dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine
CAS Number:
213843-90-4
Molecular Formula:
C33H34NO4P
Molecular Weight:
539.6011
MDL Number:
MFCD04117685
SMILES:
CN(P1OC(c2ccccc2)(c2ccccc2)[C@H]2[C@H](C(O1)(c1ccccc1)c1ccccc1)OC(O2)(C)C)C
Properties
Properties
 
BP:
569.804°C at 760 mmHg  
Form:
Solid  
MP:
218-221°C  
Stability:
moisture sensitive  
Storage:
Inert atmosphere;2-8℃;  


Downstream Synthesis Route

[1]Alexakis,Alexandre;Burton,Jonathan;Vastra,Johann;Benhaim,Cyril;Fournioux,Xavier;VanDenHeuvel,Alexandra;Leveque,Jean-Marc;Maze,Frederique;Rosset,Stephane[EuropeanJournalofOrganicChemistry,2000,#24,p.4011-4027]

[1]Pfretzschner,Tatjana;Kleemann,Lutz;Janza,Birgit;Harms,Klaus;Schrader,Thomas[Chemistry-AEuropeanJournal,2004,vol.10,#23,p.6048-6057]

[2]Lee,ErnestE.;Rovis,Tomislav[OrganicLetters,2008,vol.10,#6,p.1231-1234]

93379-48-7   
CASUnavailable 
  213843-90-4 

[1]Burks,HeatherE.;Liu,Shubin;Morken,JamesP.[JournaloftheAmericanChemicalSociety,2007,vol.129,#28,p.8766-8773]

CASUnavailable 
  93379-48-7    213843-90-4 

[1]Locationinpatent:experimentalpartPichota,Arkadius;Gramlich,Volker;Bichsel,Hans-Ulrich;Styner,Thomas;Knoepfel,Thomas;Wuensch,Ralf;Hintermann,Tobias;Schweizer,W.Bernd;Beck,AlbertK.;Seebach,Dieter[HelveticaChimicaActa,2012,vol.95,#8,p.1273-1302]

29892-37-3    213843-90-4   
CASUnavailable 

[1]García-Morales,Cristina;Ranieri,Beatrice;Escofet,Imma;López-Suarez,Laura;Obradors,Carla;Konovalov,AndreyI.;Echavarren,AntonioM.[JournaloftheAmericanChemicalSociety,2017,vol.139,#39,p.13628-13631]

Literature
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SDS
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Tags:213843-90-4 Molecular Formula|213843-90-4 MDL|213843-90-4 SMILES|213843-90-4 (3Ar,8ar)-(-)-(2,2-dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine