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2622-14-2,MFCD00003853
Catalog No.:AA002S8U

2622-14-2 | Tricyclohexylphosphine

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5g
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10g
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25g
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  • Technical Information
  • Properties
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Technical Information
Catalog Number:
AA002S8U
Chemical Name:
Tricyclohexylphosphine
CAS Number:
2622-14-2
Molecular Formula:
C18H33P
Molecular Weight:
280.4284
MDL Number:
MFCD00003853
SMILES:
C1CCC(CC1)P(C1CCCCC1)C1CCCCC1
NSC Number:
158657
Properties
Computed Properties
 
Complexity:
202  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
19  
Rotatable Bond Count:
3  
XLogP3:
5.4  

Literature

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Journal: Accounts of chemical research 20121016

Title: Direct, redox-neutral prenylation and geranylation of secondary carbinol C-H bonds: C4-regioselectivity in ruthenium-catalyzed C-C couplings of dienes to α-hydroxy esters.

Journal: Journal of the American Chemical Society 20120926

Title: Pyridazine based scorpionate ligand in a copper boratrane compound.

Journal: Inorganic chemistry 20111219

Title: Synthesis, antimicrobial and antiproliferative activity of novel silver(I) tris(pyrazolyl)methanesulfonate and 1,3,5-triaza-7-phosphadamantane complexes.

Journal: Inorganic chemistry 20111107

Title: Synthesis, characterization and anticancer studies of mixed ligand dithiocarbamate palladium(II) complexes.

Journal: European journal of medicinal chemistry 20110901

Title: Cytotoxic gold(I)-bearing dendrimers from alkyne precursors.

Journal: Dalton transactions (Cambridge, England : 2003) 20110828

Title: Deducing chemical structure from crystallographically determined atomic coordinates.

Journal: Acta crystallographica. Section B, Structural science 20110801

Title: Syntheses of α-pyrones using gold-catalyzed coupling reactions.

Journal: Organic letters 20110603

Title: Substantiating the influence of pore surface functionalities on the stability of Grubbs catalyst in mesoporous SBA-15 silica.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20110404

Title: 8-Azatetracyclines: synthesis and evaluation of a novel class of tetracycline antibacterial agents.

Journal: Journal of medicinal chemistry 20110310

Title: Rauhut-Currier type homo- and heterocouplings involving nitroalkenes and nitrodienes.

Journal: Organic & biomolecular chemistry 20101107

Title: One-pot synthesis of 2,3,4-triarylquinolines via suzuki-miyaura cross-coupling of 2-aryl-4-chloro-3-iodoquinolines with arylboronic acids.

Journal: Molecules (Basel, Switzerland) 20101022

Title: Reactivity of [1],[1]disilamolybdenocenophane toward zerovalent platinum complexes.

Journal: Journal of the American Chemical Society 20100818

Title: Phosphonium ionic liquids based on bulky phosphines: synthesis, structure and properties.

Journal: Dalton transactions (Cambridge, England : 2003) 20100621

Title: Amide synthesis from alcohols and amines catalyzed by ruthenium N-heterocyclic carbene complexes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20100618

Title: Creating an antibacterial with in vivo efficacy: synthesis and characterization of potent inhibitors of the bacterial cell division protein FtsZ with improved pharmaceutical properties.

Journal: Journal of medicinal chemistry 20100527

Title: Bis(dicyclo-hexyl-phenyl-phosphine)silver(I) nitrate.

Journal: Acta crystallographica. Section E, Structure reports online 20100501

Title: [6-(4-Bromo-phen-yl)-2,2'-bipyridine-κN,N'](tricyclo-hexyl-phosphine-κP)copper(I) tetra-fluoridoborate.

Journal: Acta crystallographica. Section E, Structure reports online 20100201

Title: The catalytic performance of Ru-NHC alkylidene complexes: PCy₃versus pyridine as the dissociating ligand.

Journal: Beilstein journal of organic chemistry 20100101

Title: [μ-Bis(diphenyl-arsino)methane-1:2κAs:As']nona-carbonyl-1κC,2κC,3κC-tricyclo-hexyl-phosphine-3κP-triangulo-triruthenium(0).

Journal: Acta crystallographica. Section E, Structure reports online 20091201

Title: Phosphine- and carbene-ligated silver acetate: easily-accessed synthons for reactions with silylated nucleophiles.

Journal: Inorganic chemistry 20091005

Title: Bis(η-cyclo-hepta-trien-yl)tri-μ-hydrido-dimolybdenum(0,I).

Journal: Acta crystallographica. Section E, Structure reports online 20090101

Title: Iridium-mediated isomerization-cyclization of bicyclic Pauson-Khand derived allylic alcohols.

Journal: The Journal of organic chemistry 20081107

Title: Reduction of an eta2-iminoacyl ligand to eta2-iminium enabled by adjacent carbon monoxide ligand replacement with a variable electron donor alkyne ligand in a cationic Tungsten(II) bis(acetylacetonate) complex.

Journal: Inorganic chemistry 20081006

Title: Nickel-catalysed reactions with trialkylboranes and silacyclobutanes.

Journal: Chemical communications (Cambridge, England) 20080728

Title: Reactivity of a phosphinito-bridged PtI-PtI complex with nucleophiles: substitution versus addition.

Journal: Inorganic chemistry 20080602

Title: Pd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions.

Journal: Dalton transactions (Cambridge, England : 2003) 20080207

Title: Bis[μ-1,2-bis-(diphenyl-phosphino)methane-κP:P']bis-[(η-ethene)nickel(0)] toluene disolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20080201

Title: An electronic rationale for observed initiation rates in ruthenium-mediated olefin metathesis: charge donation in phosphine and N-heterocyclic carbene ligands.

Journal: Journal of the American Chemical Society 20071226

Title: A convenient and general iron-catalyzed hydrosilylation of aldehydes.

Journal: Organic letters 20071220

Title: Pd(OAc)2/P(cC6H11)3-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation.

Journal: Journal of the American Chemical Society 20070411

Title: N-heterocyclic carbene and phosphine ruthenium indenylidene precatalysts: a comparative study in olefin metathesis.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

Title: Direct measurements of rate constants and activation volumes for the binding of H2, D2, N2, C2H4, and CH3CN to W(CO)3(PCy3)2: theoretical and experimental studies with time-resolved step-scan FTIR and UV-vis spectroscopy.

Journal: Journal of the American Chemical Society 20061213

Title: Ligand controlled dioxygen oxidation of rhenium nitrosyl complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20061014

Title: Preparation and properties of a monomeric Mn(IV)-oxo complex.

Journal: Journal of the American Chemical Society 20060712

Title: Phosphine-ligated induced formation of thallium(I) full Pt3TlPt3 sandwich versus 'open-face' TlPt3 sandwich with triangular Pt3(mu2-CO)3(PR3)3 units: synthesis and structural/spectroscopic analysis of triphenylphosphine [(mu3-Tl)Pt3(mu2-CO)3(PPh3)3]+ and its (mu3-AuPPh3)Pt3 analogue.

Journal: Dalton transactions (Cambridge, England : 2003) 20060227

Title: Synthesis, neutron structure, and reactivity of the bis(dihydrogen) complex RuH2(eta(2)-H2)2(PCyp3)2 stabilized by two tricyclopentylphosphines.

Journal: Journal of the American Chemical Society 20051221

Title: Effective, selective coupling of propylene oxide and carbon dioxide to poly(propylene carbonate) using (salen)CrN3 catalysts.

Journal: Inorganic chemistry 20050627

Title: Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides.

Journal: Dalton transactions (Cambridge, England : 2003) 20041121

Title: 14-electron disilene palladium complex having strong pi-complex character.

Journal: Journal of the American Chemical Society 20041013

Title: Phosphine coordination complexes of the diphenylphosphenium cation: a versatile synthetic methodology for P-P bond formation.

Journal: Journal of the American Chemical Society 20031126

Title: Simple tricyclohexylphosphine-palladium complexes as efficient catalysts for the Stille coupling of deactivated aryl chlorides.

Journal: Chemical communications (Cambridge, England) 20021121

Title: Metal-metal interactions in dinuclear d(8) metal cyanide complexes supported by phosphine ligands. Spectroscopic properties and ab initio calculations of [M(2)(mu-diphosphine)(2)(CN)(4)] and trans-[M(phosphine)(2)(CN)(2)] (M = Pt, Ni).

Journal: Inorganic chemistry 20020729

Title: Ruthenium alkylidenes: modulation of a new class of catalysts for controlled radical polymerization of vinyl monomers.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20020702

Title: New Pd-catalyzed selective reduction of carboxylic acids to aldehydes.

Journal: Chemical communications (Cambridge, England) 20020421

Title: A new practical ketone synthesis directly from carboxylic acids: first application of coupling reagents in palladium catalysis.

Journal: Chemical communications (Cambridge, England) 20011021

Title: Highly active catalysts for the Suzuki coupling of aryl chlorides.

Journal: Chemical communications (Cambridge, England) 20010907

Title: Stereoselective synthesis of styrene oxides via a Mitsunobu cyclodehydration.

Journal: Organic letters 20010809

Title: Tricyclohexylphosphine derivatives of bis(2,6-difluorophenoxide)cadmium: a solution and solid-state NMR study.

Journal: Inorganic chemistry 20010702

Title: trans-Chloro(methyl)bis(tricyclohexylphosphine)platinum(II).

Journal: Acta crystallographica. Section C, Crystal structure communications 20010701

Title: Synthesis, characterization, and ligand exchange studies of W(6)S(8)L(6) cluster compounds.

Journal: Inorganic chemistry 20010604

Title: Luminescent mu-ethynediyl and mu-butadiynediyl binuclear gold(I) complexes: observation of (3)(pi pi*) emissions from bridging C(n)(2-) units.

Journal: Journal of the American Chemical Society 20010530

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