31762-50-2,MFCD00009184
Catalog No.:AA01X3O2

31762-50-2 | 2-Propynoic acid, ethyl ester, homopolymer

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  • Technical Information
  • Properties
  • Literature
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Technical Information
Catalog Number:
AA01X3O2
Chemical Name:
2-Propynoic acid, ethyl ester, homopolymer
CAS Number:
31762-50-2
Molecular Formula:
C5H6O2
Molecular Weight:
98.0999
MDL Number:
MFCD00009184
SMILES:
CCOC(=O)C#C
NSC Number:
60551
Properties
Computed Properties
 
Complexity:
107  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0  
Defined Bond Stereocenter Count:
0  
Formal Charge:
0  
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
0  
Isotope Atom Count:
0  
Rotatable Bond Count:
2  
Undefined Atom Stereocenter Count:
0  
Undefined Bond Stereocenter Count:
0  
XLogP3:
1  

Literature

Title: Regioselective synthesis of 2-(2-hydroxyaryl)pyridines from the reactions of benzynes with pyridine N-oxides.

Journal: Organic & biomolecular chemistry 20120914

Title: Hydrotris(3-mesitylpyrazolyl)borato-copper(I) alkyne complexes: synthesis, structural characterization and rationalization of their activities as alkyne cyclopropenation catalysts.

Journal: Dalton transactions (Cambridge, England : 2003) 20120507

Title: Organocatalysis in synthesis: L-proline as an enantioselective catalyst in the synthesis of pyrans and thiopyrans.

Journal: Molecules (Basel, Switzerland) 20120410

Title: Automated determination of total captopril in urine by liquid chromatography with post-column derivatization coupled to on-line solid phase extraction in a sequential injection manifold.

Journal: Talanta 20120115

Title: Ethyl propiolate as a post-column derivatization reagent for thiols: development of a green liquid chromatographic method for the determination of glutathione in vegetables.

Journal: Analytica chimica acta 20110325

Title: Functionalized tetrahydrofurans from alkenols and olefins/alkynes via aerobic oxidation-radical addition cascades.

Journal: Journal of the American Chemical Society 20110323

Title: Ethyl 1-(2,6-difluoro-benz-yl)-1H-1,2,3-triazole-4-carboxyl-ate.

Journal: Acta crystallographica. Section E, Structure reports online 20110101

Title: Ethyl 1,3,10,12-tetra-phenyl-19,20-dioxa-hexa-cyclo-[10.6.1.1.0.0.0]icosa-4(9),5,7,13(18),14,16-hexa-ene-2-carboxyl-ate.

Journal: Acta crystallographica. Section E, Structure reports online 20101201

Title: Synthesis and properties of macrolones characterized by two ether bonds in the linker.

Journal: Bioorganic & medicinal chemistry 20100901

Title: Thieno[2,3-d]pyrimidines in the synthesis of antitumor and antioxidant agents.

Journal: Archiv der Pharmazie 20100501

Title: Orthogonal synthesis of densely functionalized pyrroles and thiophenes from the reactions of imidazo[1,5-a]pyridine carbene-derived zwitterions with electron-deficient alkynes.

Journal: The Journal of organic chemistry 20100402

Title: Reactions of ruthenium Cp phosphine complex with 4,4-disubstituted-1,6-enynes: effect of methyl substituents in the olefinic fraction.

Journal: Journal of the American Chemical Society 20091230

Title: Generation of allenic/propargylic zirconium complexes and subsequent cross-coupling reactions: a facile synthesis of multisubstituted allenes.

Journal: The Journal of organic chemistry 20091218

Title: Ethyl-propiolate as a novel and promising analytical reagent for the derivatization of thiols: study of the reaction under flow conditions.

Journal: Journal of pharmaceutical and biomedical analysis 20091015

Title: Synthesis of macrocyclic precursors of phomactins using [2,3]-Wittig rearrangements.

Journal: Organic & biomolecular chemistry 20090621

Title: Drastic effect of bidentate phosphine ligands on Pd-catalyzed hydroarylation of ethyl propiolate: a simple route to arylbutadienes.

Journal: Chemical communications (Cambridge, England) 20081028

Title: Hydrolytic reactivity trends among potential prodrugs of the O2-glycosylated diazeniumdiolate family. Targeting nitric oxide to macrophages for antileishmanial activity.

Journal: Journal of medicinal chemistry 20080710

Title: Low-calcemic, highly antiproliferative, 23-oxa ether analogs of the natural hormone 1 alpha,25-dihydroxyvitamin D3: design, synthesis, and preliminary biological evaluation.

Journal: Journal of medicinal chemistry 20071115

Title: Domino reaction of 3-(2-formylphenoxy)propenoates and amines: a novel synthesis of 1,4-dihydropyridines from salicaldehydes, ethyl propiolate, and amines.

Journal: The Journal of organic chemistry 20070928

Title: Gold-catalyzed synthesis of oxygen- and nitrogen-containing heterocycles from alkynyl ethers: application to the total synthesis of andrachcinidine.

Journal: The Journal of organic chemistry 20070914

Title: Substrate-controlled and site-selective [3+2] cycloadditions of N-heterocyclic carbene derived ambident dipoles.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

Title: Cu(I)-catalyzed conjugate addition of ethyl propiolate.

Journal: Angewandte Chemie (International ed. in English) 20070101

Title: Strategy for the enantioselective synthesis of trans-2,4-disubstituted piperidines: application to the CCR3 antagonist IS811.

Journal: The Journal of organic chemistry 20061110

Title: Synthesis of N-methoxy-N-methyl-beta-enaminoketoesters: new synthetic precursors for the regioselective synthesis of heterocyclic compounds.

Journal: Organic letters 20060720

Title: Ruthenium complexes of thiocinnamaldehydes: synthesis, structure, and [4+2]-cycloaddition reactions.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060614

Title: A N-heterocyclic carbene derived highly regioselective ambident C-C-S and C-C-N 1,3-dipolar system.

Journal: Chemical communications (Cambridge, England) 20060321

Title: Acetylenic TACE inhibitors. Part 3: Thiomorpholine sulfonamide hydroxamates.

Journal: Bioorganic & medicinal chemistry letters 20060315

Title: Cp*RuCl-catalyzed [2 + 2 + 2] cycloadditions of alpha,omega-diynes with electron-deficient carbon-heteroatom multiple bonds leading to heterocycles.

Journal: Journal of the American Chemical Society 20050119

Title: [Bisbenzothieno[3,2-b: 2',3'-e]pyridines].

Journal: Die Pharmazie 20040901

Title: Phosphine-mediated reductive condensation of gamma-acyloxy butynoates: a diversity oriented strategy for the construction of substituted furans.

Journal: Journal of the American Chemical Society 20040407

Title: Tethered 2 + 2 + 2 cycloaddition reactions of cobalt-cycloheptyne complexes.

Journal: Chemical communications (Cambridge, England) 20031207

Title: Radical carbonylation/reductive cyclization for the construction of tetrahydrofuran-3-ones and pyrrolidin-3-ones.

Journal: The Journal of organic chemistry 20031031

Title: Reaction of acetylenic esters and N-functionalized phosphazenes. 1,2-versus 1,4-addition of N-vinylic phosphazenes.

Journal: Organic & biomolecular chemistry 20030407

Title: 3-carboxy-4-phosphonocyclopentane amino acids: new metabotropic glutamate receptor ligands.

Journal: Amino acids 20030401

Title: Photochemical, thermal, and base-induced access to hydroazulene derivatives via two-carbon ring-enlargement reactions of condensed electrophilic cyclobutenes.

Journal: The Journal of organic chemistry 20030124

Title: Construction of tetrahydrofuran-3-ones from readily available organochalcogen precursors via radical carbonylation/reductive cyclization.

Journal: Organic letters 20020110

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SDS
Tags:31762-50-2 Molecular Formula|31762-50-2 MDL|31762-50-2 SMILES|31762-50-2 2-Propynoic acid, ethyl ester, homopolymer
Catalog No.: AA01X3O2
31762-50-2,MFCD00009184
31762-50-2 | 2-Propynoic acid, ethyl ester, homopolymer
This product is typically in stock,please click "Inquire" below or contact us at [email protected]for pricing and availability information.
Inquire
Technical Information
Catalog Number: AA01X3O2
Chemical Name: 2-Propynoic acid, ethyl ester, homopolymer
CAS Number: 31762-50-2
Molecular Formula: C5H6O2
Molecular Weight: 98.0999
MDL Number: MFCD00009184
SMILES: CCOC(=O)C#C
NSC Number: 60551
Properties
Complexity: 107  
Covalently-Bonded Unit Count: 1  
Defined Atom Stereocenter Count: 0  
Defined Bond Stereocenter Count: 0  
Formal Charge: 0  
Heavy Atom Count: 7  
Hydrogen Bond Acceptor Count: 2  
Hydrogen Bond Donor Count: 0  
Isotope Atom Count: 0  
Rotatable Bond Count: 2  
Undefined Atom Stereocenter Count: 0  
Undefined Bond Stereocenter Count: 0  
XLogP3: 1  
Literature fold

Title: Regioselective synthesis of 2-(2-hydroxyaryl)pyridines from the reactions of benzynes with pyridine N-oxides.

Journal: Organic & biomolecular chemistry20120914

Title: Hydrotris(3-mesitylpyrazolyl)borato-copper(I) alkyne complexes: synthesis, structural characterization and rationalization of their activities as alkyne cyclopropenation catalysts.

Journal: Dalton transactions (Cambridge, England : 2003)20120507

Title: Organocatalysis in synthesis: L-proline as an enantioselective catalyst in the synthesis of pyrans and thiopyrans.

Journal: Molecules (Basel, Switzerland)20120410

Title: Automated determination of total captopril in urine by liquid chromatography with post-column derivatization coupled to on-line solid phase extraction in a sequential injection manifold.

Journal: Talanta20120115

Title: Ethyl propiolate as a post-column derivatization reagent for thiols: development of a green liquid chromatographic method for the determination of glutathione in vegetables.

Journal: Analytica chimica acta20110325

Title: Functionalized tetrahydrofurans from alkenols and olefins/alkynes via aerobic oxidation-radical addition cascades.

Journal: Journal of the American Chemical Society20110323

Title: Ethyl 1-(2,6-difluoro-benz-yl)-1H-1,2,3-triazole-4-carboxyl-ate.

Journal: Acta crystallographica. Section E, Structure reports online20110101

Title: Ethyl 1,3,10,12-tetra-phenyl-19,20-dioxa-hexa-cyclo-[10.6.1.1.0.0.0]icosa-4(9),5,7,13(18),14,16-hexa-ene-2-carboxyl-ate.

Journal: Acta crystallographica. Section E, Structure reports online20101201

Title: Synthesis and properties of macrolones characterized by two ether bonds in the linker.

Journal: Bioorganic & medicinal chemistry20100901

Title: Thieno[2,3-d]pyrimidines in the synthesis of antitumor and antioxidant agents.

Journal: Archiv der Pharmazie20100501

Title: Orthogonal synthesis of densely functionalized pyrroles and thiophenes from the reactions of imidazo[1,5-a]pyridine carbene-derived zwitterions with electron-deficient alkynes.

Journal: The Journal of organic chemistry20100402

Title: Reactions of ruthenium Cp phosphine complex with 4,4-disubstituted-1,6-enynes: effect of methyl substituents in the olefinic fraction.

Journal: Journal of the American Chemical Society20091230

Title: Generation of allenic/propargylic zirconium complexes and subsequent cross-coupling reactions: a facile synthesis of multisubstituted allenes.

Journal: The Journal of organic chemistry20091218

Title: Ethyl-propiolate as a novel and promising analytical reagent for the derivatization of thiols: study of the reaction under flow conditions.

Journal: Journal of pharmaceutical and biomedical analysis20091015

Title: Synthesis of macrocyclic precursors of phomactins using [2,3]-Wittig rearrangements.

Journal: Organic & biomolecular chemistry20090621

Title: Drastic effect of bidentate phosphine ligands on Pd-catalyzed hydroarylation of ethyl propiolate: a simple route to arylbutadienes.

Journal: Chemical communications (Cambridge, England)20081028

Title: Hydrolytic reactivity trends among potential prodrugs of the O2-glycosylated diazeniumdiolate family. Targeting nitric oxide to macrophages for antileishmanial activity.

Journal: Journal of medicinal chemistry20080710

Title: Low-calcemic, highly antiproliferative, 23-oxa ether analogs of the natural hormone 1 alpha,25-dihydroxyvitamin D3: design, synthesis, and preliminary biological evaluation.

Journal: Journal of medicinal chemistry20071115

Title: Domino reaction of 3-(2-formylphenoxy)propenoates and amines: a novel synthesis of 1,4-dihydropyridines from salicaldehydes, ethyl propiolate, and amines.

Journal: The Journal of organic chemistry20070928

Title: Gold-catalyzed synthesis of oxygen- and nitrogen-containing heterocycles from alkynyl ethers: application to the total synthesis of andrachcinidine.

Journal: The Journal of organic chemistry20070914

Title: Substrate-controlled and site-selective [3+2] cycloadditions of N-heterocyclic carbene derived ambident dipoles.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20070101

Title: Cu(I)-catalyzed conjugate addition of ethyl propiolate.

Journal: Angewandte Chemie (International ed. in English)20070101

Title: Strategy for the enantioselective synthesis of trans-2,4-disubstituted piperidines: application to the CCR3 antagonist IS811.

Journal: The Journal of organic chemistry20061110

Title: Synthesis of N-methoxy-N-methyl-beta-enaminoketoesters: new synthetic precursors for the regioselective synthesis of heterocyclic compounds.

Journal: Organic letters20060720

Title: Ruthenium complexes of thiocinnamaldehydes: synthesis, structure, and [4+2]-cycloaddition reactions.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20060614

Title: A N-heterocyclic carbene derived highly regioselective ambident C-C-S and C-C-N 1,3-dipolar system.

Journal: Chemical communications (Cambridge, England)20060321

Title: Acetylenic TACE inhibitors. Part 3: Thiomorpholine sulfonamide hydroxamates.

Journal: Bioorganic & medicinal chemistry letters20060315

Title: Cp*RuCl-catalyzed [2 + 2 + 2] cycloadditions of alpha,omega-diynes with electron-deficient carbon-heteroatom multiple bonds leading to heterocycles.

Journal: Journal of the American Chemical Society20050119

Title: [Bisbenzothieno[3,2-b: 2',3'-e]pyridines].

Journal: Die Pharmazie20040901

Title: Phosphine-mediated reductive condensation of gamma-acyloxy butynoates: a diversity oriented strategy for the construction of substituted furans.

Journal: Journal of the American Chemical Society20040407

Title: Tethered 2 + 2 + 2 cycloaddition reactions of cobalt-cycloheptyne complexes.

Journal: Chemical communications (Cambridge, England)20031207

Title: Radical carbonylation/reductive cyclization for the construction of tetrahydrofuran-3-ones and pyrrolidin-3-ones.

Journal: The Journal of organic chemistry20031031

Title: Reaction of acetylenic esters and N-functionalized phosphazenes. 1,2-versus 1,4-addition of N-vinylic phosphazenes.

Journal: Organic & biomolecular chemistry20030407

Title: 3-carboxy-4-phosphonocyclopentane amino acids: new metabotropic glutamate receptor ligands.

Journal: Amino acids20030401

Title: Photochemical, thermal, and base-induced access to hydroazulene derivatives via two-carbon ring-enlargement reactions of condensed electrophilic cyclobutenes.

Journal: The Journal of organic chemistry20030124

Title: Construction of tetrahydrofuran-3-ones from readily available organochalcogen precursors via radical carbonylation/reductive cyclization.

Journal: Organic letters20020110

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