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333-27-7,MFCD00000409
Catalog No.:AA00356H

333-27-7 | Methyl trifluoromethanesulfonate

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  • Technical Information
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Technical Information
Catalog Number:
AA00356H
Chemical Name:
Methyl trifluoromethanesulfonate
CAS Number:
333-27-7
Molecular Formula:
C2H3F3O3S
Molecular Weight:
164.1036
MDL Number:
MFCD00000409
SMILES:
COS(=O)(=O)C(F)(F)F
NSC Number:
270679
UN Number:
2924
Properties
Properties
 
BP:
96.5°C at 760 mmHg  
Form:
Liquid  
Refractive Index:
n20/D 1.326(lit.)  
Stability:
Air Sensitive  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
172  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
9  
Hydrogen Bond Acceptor Count:
6  
Rotatable Bond Count:
1  
XLogP3:
0.9  

Literature

Title: Noncovalent interactions in peri-substituted chalconium acenaphthene and naphthalene salts: a combined experimental, crystallographic, computational, and solid-state NMR study.

Journal: Inorganic chemistry 20121015

Title: 9-(3-Fluoro-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate monohydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20120301

Title: Reactivity of divalent germanium alkoxide complexes is in sharp contrast to the heavier tin and lead analogues.

Journal: Inorganic chemistry 20120206

Title: Dissociative electron attachment to triflates.

Journal: The Journal of chemical physics 20111207

Title: 9-(2,5-Dimethyl-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20111201

Title: Fully automated and reproducible radiosynthesis of high specific activity [¹¹C]raclopride and [¹¹C]Pittsburgh compound-B using the combination of two commercial synthesizers.

Journal: Nuclear medicine communications 20111101

Title: (Isopropyl-amino)(meth-yl)diphenyl-phospho-nium iodide.

Journal: Acta crystallographica. Section E, Structure reports online 20110701

Title: Activation of carbon dioxide by divalent tin alkoxides complexes.

Journal: Inorganic chemistry 20110307

Title: 1,2-diphosphaacenaphthene 1,2-dications: synthetic, stereochemical and computational study of the stabilising role of naphthalene-1,8-diyl backbone.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20110225

Title: Lithium salts of [1,12-dialkyl-CB11Me10]- anions.

Journal: Inorganic chemistry 20101115

Title: 9-(4-Fluoro-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20101101

Title: 9-(4-Chloro-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20101101

Title: 10-Methyl-9-[2-(propan-2-yl)phenoxy-carbonyl]-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20101101

Title: 9-Phenyl-10H-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20101101

Title: 9-(2,6-Dimethyl-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20101101

Title: Room temperature palladium-catalyzed cross coupling of aryltrimethylammonium triflates with aryl Grignard reagents.

Journal: Organic letters 20101001

Title: Synthesis, structure, and reactivity of a stabilized phosphiranylium salt.

Journal: Angewandte Chemie (International ed. in English) 20100726

Title: Identification and evaluation of [11C]GSK931145 as a novel ligand for imaging the type 1 glycine transporter with positron emission tomography.

Journal: Synapse (New York, N.Y.) 20100701

Title: 9-Benzyl-10-methyl-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20100701

Title: Effects of frozen conditions on stereoselectivity and velocity of O-glycosylation reactions.

Journal: Bioorganic & medicinal chemistry 20100601

Title: 9-(4-Methyl-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20100601

Title: 9-(4-Bromo-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20100601

Title: Microstructured poly(2-oxazoline) bottle-brush brushes on nanocrystalline diamond.

Journal: Physical chemistry chemical physics : PCCP 20100507

Title: First principles insight into the alpha-glucan structures of starch: their synthesis, conformation, and hydration.

Journal: Chemical reviews 20100414

Title: [Three cases of occupational methyl trifluoromethanesulfonate poisoning].

Journal: Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases 20100401

Title: 9-(2-Ethyl-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20100401

Title: 10-Methyl-9-phenoxy-carbonyl-acridinium trifluoro-methane-sulfonate monohydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20100401

Title: Catalytic (asymmetric) methylene transfer to aldehydes.

Journal: Organic letters 20100205

Title: H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.

Journal: Accounts of chemical research 20100119

Title: Bis(4'-dibutylaminostyryl)benzene: spectroscopic behavior upon protonation or methylation.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20091207

Title: Carbonyl-chlorido(1-methyl-sulfanylpenta-1,3-dien-1-yl-5-yl-idene)bis-(triphenyl-phosphane)osmium(II).

Journal: Acta crystallographica. Section E, Structure reports online 20091101

Title: Addition of methyl triflate to a hafnocene dinitrogen complex: stepwise n(2) methylation and conversion to a hafnocene hydrazonato compound.

Journal: Journal of the American Chemical Society 20091021

Title: Synthesis and reactivity of a Ru(I) dimer devoid of pi-acid ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20090814

Title: Cationic heterocycles as ligands: synthesis and reactivity with anionic nucleophiles of cationic triruthenium clusters containing C-metalated N-methylquinoxalinium or N-methylpyrazinium ligands.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20090727

Title: 9-Chloro-2,4-dimethoxy-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20090401

Title: 9-(Methyl-sulfan-yl)acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20090301

Title: Synthesis and reactivity of metal carbene complexes with heterobiaryl spacer substituents.

Journal: Dalton transactions (Cambridge, England : 2003) 20090128

Title: Synthesis of phenol and quinone metabolites of benzo[a]pyrene, a carcinogenic component of tobacco smoke implicated in lung cancer.

Journal: The Journal of organic chemistry 20090116

Title: 9-Ethyl-10-methyl-acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20090101

Title: Lewis-acid-assisted methyl exchange reactions in silylated aminodichloroarsanes.

Journal: Inorganic chemistry 20081215

Title: The preparation of stable aziridinium ions and their ring-openings.

Journal: Chemical communications (Cambridge, England) 20080928

Title: Divergent and regioselective synthesis of 1,2,4- and 1,2,5-trisubstituted imidazoles.

Journal: The Journal of organic chemistry 20080905

Title: C-H activation on a diphosphine and hydrido-bridged diiridium complex: generation and detection of an active IrII-IrII species [(Cp*Ir)2(micro-dmpm)(micro-H)]+.

Journal: Dalton transactions (Cambridge, England : 2003) 20080721

Title: (Carbonyl-1κC)bis-[2,3(η)-cyclo-penta-dien-yl][μ(3)-(S-methyl trithio-carbonato)methylidyne-1:2:3κC,S'':C:C](triphenyl-phosphine-1κP)(μ(3)-sulfido-1:2:3κS)dicobalt(II)iron(II) trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20080501

Title: Pyridine ring opening at room temperature at a rhenium tricarbonyl bipyridine complex.

Journal: Journal of the American Chemical Society 20080430

Title: Carboxylation of an ansa-zirconocene dinitrogen complex: regiospecific hydrazine synthesis from N2 and CO2.

Journal: Journal of the American Chemical Society 20080402

Title: 10-Methyl-9-(2-nitro-phenoxy-carbon-yl)acridinium trifluoro-methane-sulfonate.

Journal: Acta crystallographica. Section E, Structure reports online 20080201

Title: Reactivity and stability of platinum(II) formyl complexes based on PCP-type ligands. The significance of sterics.

Journal: Dalton transactions (Cambridge, England : 2003) 20071228

Title: Synthesis and properties of 1-methylthiopropargylammonium salts and their use as key precursors to sulfur-containing enediynes.

Journal: Organic letters 20071206

Title: Phase-transfer-catalyzed asymmetric acylimidazole alkylation.

Journal: Organic letters 20071108

Title: Alkylation and acylation of cyclotriphosphazenes.

Journal: Inorganic chemistry 20070820

Title: Bifunctional building blocks for glyco-architectures by TiCl4 -promoted ring opening of cyclodextrin derivatives.

Journal: Biomacromolecules 20070701

Title: Cyclotetraphosphinophosphonium ions: synthesis, structures, and pseudorotation.

Journal: Journal of the American Chemical Society 20070613

Title: Monocyclic di- and triphosphinophosphonium cations: new foundational frameworks for catena-phosphorus chemistry.

Journal: Inorganic chemistry 20070514

Title: Synthesis of para-methoxybenzyl (PMB) ethers under neutral conditions.

Journal: Chemical communications (Cambridge, England) 20070414

Title: Carbon-11 labeling chemistry based upon [11C]methyl iodide.

Journal: Ernst Schering Research Foundation workshop 20070101

Title: Diphosphiranium (P2C) or diphosphetanium (P2C2) cyclic cations: different fates for the electrophile-initiated cyclodimerization of a phosphaalkene.

Journal: Journal of the American Chemical Society 20061220

Title: Synthesis of extended polyphosphacumulenes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20061115

Title: Boryllithium: isolation, characterization, and reactivity as a boryl anion.

Journal: Science (New York, N.Y.) 20061006

Title: Synthesis and characterization of osmium(II) trispyrazolylborate complexes.

Journal: Inorganic chemistry 20060626

Title: Improved synthesis of the peripheral benzodiazepine receptor ligand [11C]DPA-713 using [11C]methyl triflate.

Journal: Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine 20060501

Title: Method for the determination of inorganic polysulfide distribution in aquatic systems.

Journal: Analytical chemistry 20060415

Title: Changes in coordination of sterically demanding hybrid imidazolylphosphine ligands on Pd(0) and Pd(II).

Journal: Journal of the American Chemical Society 20060118

Title: Study of thioglycosylation in ionic liquids.

Journal: Beilstein journal of organic chemistry 20060101

Title: Synthesis and properties of Ph2S(=N-(Ph2)S[triple bond]N)2.

Journal: Inorganic chemistry 20051128

Title: The amide group in N-acetylglucosamine glycosyl acceptors affects glycosylation outcome.

Journal: The Journal of organic chemistry 20050805

Title: Synthesis of cimiracemate B, a phenylpropanoid found in Cimicifuga racemosa.

Journal: Natural product research 20050401

Title: Spectroscopic studies on the cation-anion, cation-solvent and anion-solvent interactions in the LiCF3SO3/acetamide complex system.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20050114

Title: Ring expansion-annulation strategy for the synthesis of substituted azulenes and oligoazulenes. 2. Synthesis of azulenyl halides, sulfonates, and azulenylmetal compounds and their application in transition-metal-mediated coupling reactions.

Journal: The Journal of organic chemistry 20041210

Title: Synthesis of tertiary propargylamines by sequential reactions of in situ generated thioiminium salts with organolithium and -magnesium reagents.

Journal: Journal of the American Chemical Society 20040519

Title: Improved synthesis of [11C]SA4503, [11C]MPDX and [11C]TMSX by use of [11C]methyl triflate.

Journal: Annals of nuclear medicine 20040401

Title: A formal total synthesis of (+/-)-halichlorine and (+/-)-pinnaic acid.

Journal: Organic letters 20040318

Title: Asymmetric dearomatization of the furan ring promoted by conjugate organolithium addition to (menthyloxy)(3-furyl)carbene complexes of chromium.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20031205

Title: Substitution pattern of 3-deoxy-D-manno-oct-2-ulosonic acid in bacterial lipopolysaccharides investigated by methylation analysis of whole LPS.

Journal: Carbohydrate research 20031114

Title: Synthesis of fluorescence-labelled disaccharide substrates of glucosidase II.

Journal: Carbohydrate research 20030910

Title: Protonation reactions of dinuclear pyrazolato iridium(I) complexes.

Journal: Inorganic chemistry 20030728

Title: Acyclic selenoiminium salts: isolation, first structural characterization, and reactions.

Journal: Organic letters 20030417

Title: Preparation of unsymmetrical sulfonylureas from N,N'-sulfuryldiimidazoles.

Journal: The Journal of organic chemistry 20030110

Title: [Synthesis of aminoethyl glycosides of the carbohydrate chains of glycolipids Gb3, Gb4 i Gb5].

Journal: Bioorganicheskaia khimiia 20030101

Title: Steric and electronic effects on the reactivity of rh and ir complexes containing P-S, P-P, and P-O ligands. Implications for the effects of chelate ligands in catalysis.

Journal: Journal of the American Chemical Society 20021113

Title: An improved method for the preparation of [11C]verapamil.

Journal: Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine 20021001

Title: Reversible intramolecular hydride transfer between tantalum and an aromatic ring: an eta(5)-cyclohexadienyl complex as a masked hydride.

Journal: Journal of the American Chemical Society 20020724

Title: Optimizing the least nucleophilic anion. A new, strong methyl(+) reagent.

Journal: Journal of the American Chemical Society 20020220

Title: Synthesis, structure, and reactivity of closo-2,3,4,5,6,7,8,9,10,11-decahydroxy-1,12-bis(sulfonic acid)-1,12-dicarbadodecaborane(12).

Journal: Journal of the American Chemical Society 20011226

Title: A simple loop method for the automated preparation of (11C)raclopride from (11C)methyl triflate.

Journal: Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine 20010701

Title: MeOTf-mediated alkynylation of selenoamides leading to beta-methylselenenyl alpha,beta-unsaturated ketones and their characterization.

Journal: Organic letters 20010628

Title: Synthesis of propyl and 2-aminoethyl glycosides of alpha-D-galactosyl-(1-->3')-beta-lactoside.

Journal: Carbohydrate research 20010615

Title: Protonation and deprotonation of TpOs(NHPh)Cl(2): an unusually inert amido ligand.

Journal: Inorganic chemistry 20010409

Title: Stereoselective synthesis of 2-S-phenyl-2-deoxy-beta-glycosides using phenyl 2,3-O-thionocarbonyl-1-thioglycoside donors via 1,2-Migration and concurrent glycosidation.

Journal: Organic letters 20010208

Title: Stereospecific reduction of phosphine oxides to phosphines by the use of a methylation reagent and lithium aluminum hydride.

Journal: Organic letters 20010111

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Tags:333-27-7 Molecular Formula|333-27-7 MDL|333-27-7 SMILES|333-27-7 Methyl trifluoromethanesulfonate