Home Other Building Blocks 3634-89-7
3634-89-7,MFCD00188412
Catalog No.:AA00CH5U

3634-89-7 | N-Tosylaziridine

Pack Size
Purity
Availability
Price(USD)
Quantity
  
250mg
98%
in stock  
$14.00   $10.00
- +
1g
98%
in stock  
$42.00   $30.00
- +
5g
98%
in stock  
$138.00   $97.00
- +
10g
98%
in stock  
$245.00   $171.00
- +
25g
98%
in stock  
$477.00   $334.00
- +
100g
98%
in stock  
$1,407.00   $985.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA00CH5U
Chemical Name:
N-Tosylaziridine
CAS Number:
3634-89-7
Molecular Formula:
C9H11NO2S
Molecular Weight:
197.2541
MDL Number:
MFCD00188412
SMILES:
Cc1ccc(cc1)S(=O)(=O)N1CC1
Properties
Properties
 
Form:
Solid  
MP:
52-56℃  
Storage:
Keep in dry area;-20 ℃;  

Computed Properties
 
Complexity:
269  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
13  
Hydrogen Bond Acceptor Count:
3  
Rotatable Bond Count:
2  
XLogP3:
1.2  

Downstream Synthesis Route

[1]CurrentPatentAssignee:UNIVERSITYOFCALIFORNIA-WO2008/63721,2008,A2Locationinpatent:Page/Pagecolumn77

[2]CurrentPatentAssignee:MASSGENERALBRIGHAMINC-US2022/25254,2022,A1Locationinpatent:Paragraph0041-0042;0053;0606-0607;0738;0740

[3]Bird,R.etal.[JournaloftheChemicalSociety.PerkintransactionsII,1973,p.1215-1220]

[1]JournaloftheChemicalSociety.PerkintransactionsII,1992,p.1059-1065

[1]Payne,N.Connor;Kalyakina,AlenaS.;Singh,Kritika;Tye,MarkA.;Mazitschek,Ralph[NatureChemicalBiology,2021,vol.17,#11,p.1168-1177]

[2]CurrentPatentAssignee:MASSGENERALBRIGHAMINC-US2022/25254,2022,A1Locationinpatent:Paragraph0041-0042;0053;0608-0609;0738;0741

[3]CurrentPatentAssignee:UNIVERSITYOFCALIFORNIA-WO2008/63721,2008,A2Locationinpatent:Page/Pagecolumn77

[4]Voronkov,M.G.;Knutov,V.I.;Butin,M.K.[ChemistryofHeterocyclicCompounds,1989,vol.25,#7,p.839-840][KhimiyaGeterotsiklicheskikhSoedinenii,1989,vol.25,#7,p.1000]

[5]Garcia-Espana,Enrique;Micheloni,Mauro;Paoletti,Piero;Bianchi,Antonio[GazzettaChimicaItaliana,1985,vol.115,#8,p.399-400]

[1]JournalofOrganicChemistryUSSR(EnglishTranslation),1990,vol.26,p.1537-1544    ZhurnalOrganicheskoiKhimii,1990,vol.26,p.1776-1784

[2]JournaloftheChemicalSociety.PerkintransactionsI,1988,p.3141-3148

[3]Synthesis,1988,p.335-336

[1]Wu,Jie;Hou,Xue-Long;Dai,Li-Xin[JournalofOrganicChemistry,2000,vol.65,#5,p.1344-1348]

[2]Das,Biswanath;Krishnaiah,Maddeboina;Laxminarayana,Keetha[JournalofChemicalResearch,2007,#2,p.82-83]

[3]Stamm,Helmut;Onistschenko,Andreas;Buchholz,Berthold;Mall,Thomas[JournalofOrganicChemistry,1989,vol.54,#1,p.193-199]

Literature

Title: Mn2+ complexes with 12-membered pyridine based macrocycles bearing carboxylate or phosphonate pendant arm: crystallographic, thermodynamic, kinetic, redox, and 1H/17O relaxation studies.

Journal: Inorganic chemistry 20111219

Title: Ag(I)-catalyzed regioselective ring-opening of N-tosylaziridine and N-tosylazetidine with S-, O-, and N-nucleophiles and tethered dinucleophiles.

Journal: The Journal of organic chemistry 20110304

Title: Birch reductive alkylation of biaryls: scope and limitations.

Journal: The Journal of organic chemistry 20090904

Title: A stereodivergent strategy to both product enantiomers from the same enantiomer of a stereoinducing catalyst: agelastatin A.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20090713

Title: Studies on the reaction of aziridines with nitriles and carbonyls: synthesis of imidazolines and oxazolidines.

Journal: The Journal of organic chemistry 20070316

Title: New class of nucleophiles for palladium-catalyzed asymmetric allylic alkylation. Total synthesis of agelastatin A.

Journal: Journal of the American Chemical Society 20060510

Title: Preparation of hexaaza and heptaaza macrocycles functionalized with a single aminoalkyl pendant arm.

Journal: Organic & biomolecular chemistry 20030307

Title: Metalloporphyrin-mediated asymmetric nitrogen-atom transfer to hydrocarbons: aziridination of alkenes and amidation of saturated C-H bonds catalyzed by chiral ruthenium and manganese porphyrins.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20020402

Title: New diamide-diamine ligands and their zirconium and hafnium dichloride and bis(dimethylamide) complexes.

Journal: Inorganic chemistry 20020311

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