Home Bromides 4175-77-3
4175-77-3,MFCD01318994
Catalog No.:AA0032W2

4175-77-3 | 2,4-Dibromothiazole

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Purity
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1g
98%
in stock  
$6.00   $4.00
- +
5g
98%
in stock  
$7.00   $5.00
- +
10g
98%
in stock  
$9.00   $6.00
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25g
98%
in stock  
$17.00   $12.00
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100g
98%
in stock  
$59.00   $41.00
- +
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA0032W2
Chemical Name:
2,4-Dibromothiazole
CAS Number:
4175-77-3
Molecular Formula:
C3HBr2NS
Molecular Weight:
242.9197
MDL Number:
MFCD01318994
SMILES:
Brc1scc(n1)Br
Properties
Properties
 
BP:
242.8°C at 760 mmHg  
Form:
Solid  
MP:
80-84 °C  
Storage:
Room Temperature;Keep in dry area;  

Computed Properties
 
Complexity:
70  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
2  
XLogP3:
3  

Upstream Synthesis Route

[1]Patent:US2008/261996,2008,A1,.Locationinpatent:Page/Pagecolumn44

[2]JournalofMaterialsChemistryC,2017,vol.5,#45,p.11927-11936

[3]JournalofOrganicChemistry,2006,vol.71,#10,p.3754-3761

[4]TetrahedronLetters,1995,vol.36,#51,p.9293-9296

[5]Patent:US4990520,1991,A,

[6]Patent:WO2008/94737,2008,A2,.Locationinpatent:Page/Pagecolumn41-42

[7]JournalofOrganicChemistry,2017,vol.82,#11,p.5947-5951

[1]JournaloftheChemicalSociety,PerkinTransactions1:OrganicandBio-OrganicChemistry(1972-1999),1992,#2,p.215-219

[2]JournaloftheChemicalSociety,PerkinTransactions1:OrganicandBio-OrganicChemistry(1972-1999),1992,#2,p.215-219

[1]JournalofOrganicChemistry,2006,vol.71,#10,p.3754-3761

[2]Synthesis,2012,vol.44,#7,p.1026-1029

[3]JournalofMaterialsChemistryC,2017,vol.5,#45,p.11927-11936

[4]Patent:US2007/4786,2007,A1,.Locationinpatent:Page/Pagecolumn21

[5]Tetrahedron,2006,vol.62,#38,p.9017-9037

[6]Patent:US2004/254236,2004,A1,

[7]Patent:US2008/234267,2008,A1,.Locationinpatent:Page/Pagecolumn17

[8]BioorganicandMedicinalChemistryLetters,2011,vol.21,#19,p.5849-5853

[9]Patent:US9138427,2015,B2,.Locationinpatent:Page/Pagecolumn298-299

[10]JournalofChemicalCrystallography,2015,vol.45,#10-12,p.461-465

[11]JournalofOrganicChemistry,2017,vol.82,#11,p.5947-5951

[12]JournalofOrganicChemistry,2018,vol.83,#2,p.664-671

[1]Patent:WO2007/138072,2007,A2,.Locationinpatent:Page/Pagecolumn80

[1]Patent:US4990520,1991,A,

Downstream Synthesis Route

[1]Dondoni,A.;Mastellari,A.R.;Medici,A.;Negrini,E.;Pedrini,P.[Synthesis,1986,#9,p.757-760]

[2]Dondoni,Alessandro;Fantin,Giancarlo;Fogagnolo,Marco;Medici,Alessandro;Pedrini,Paola[JournalofOrganicChemistry,1988,vol.53,#8,p.1748-1761]

[1]JournaloftheChemicalSociety.PerkintransactionsI,1992,p.215-219

[1]Patent:US2014/179663,2014,A1.Locationinpatent:Paragraph0174

[2]JournalofFluorineChemistry,1991,vol.55,p.173-178

[3]Patent:WO2008/57336,2008,A2.Locationinpatent:Page/Pagecolumn36

[4]Patent:US2015/175597,2015,A1.Locationinpatent:Paragraph0179;0180

[1]Patent:WO2013/178362,2013,A1.Locationinpatent:Page/Pagecolumn156

[2]JournaloftheChemicalSociety.PerkintransactionsI,1992,p.215-219

[1]JournaloftheChemicalSociety.PerkintransactionsI,1992,p.215-219

[2]JournaloftheChemicalSociety.PerkintransactionsI,1992,p.215-219

Literature

Title: Total synthesis of lodopyridone.

Journal: Organic letters 20120907

Title: Synthesis and configurational assignment of the amino alcohol in the eastern fragment of the GE2270 antibiotics by regio- and stereoselective addition of 2-metalated 4-bromothiazoles to alpha-chiral electrophiles.

Journal: The Journal of organic chemistry 20060609

Title: Total synthesis of (+/-)-mycothiazole and formal enantioselective approach.

Journal: Organic letters 20050120

Title: Synthesis of 2'-substituted 4-bromo-2,4'-bithiazoles by regioselective cross-coupling reactions.

Journal: The Journal of organic chemistry 20020809

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