Home Other Building Blocks 4559-70-0
4559-70-0,MFCD00002079
Catalog No.:AA003PN6

4559-70-0 | Diphenylphosphine oxide

Pack Size
Purity
Availability
Price(USD)
Quantity
  
5g
97%
in stock  
$6.00   $4.00
- +
100g
>98%
in stock  
$100.00   $70.00
- +
  • Technical Information
  • Properties
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA003PN6
Chemical Name:
Diphenylphosphine oxide
CAS Number:
4559-70-0
Molecular Formula:
C12H11OP
Molecular Weight:
202.1889
MDL Number:
MFCD00002079
SMILES:
O=P(c1ccccc1)c1ccccc1
NSC Number:
77604
Properties
Properties
 
BP:
329.2±25.0°C at 760 mmHg  
Form:
Solid  
MP:
56-57 °C(lit.)  
Refractive Index:
1.608-1.61  
Stability:
Moisture Sensitive  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
171  
Covalently-Bonded Unit Count:
1  
Formal Charge:
1  
Heavy Atom Count:
14  
Hydrogen Bond Acceptor Count:
1  
Rotatable Bond Count:
2  
XLogP3:
2.5  

Literature

Title: Ligand Activity of Group 15 Compounds Possessing Triphenyl Substituent for the RXR and PPARγ Nuclear Receptors.

Journal: Biological & pharmaceutical bulletin 20160101

Title: [NiCl2(dppp)]-catalyzed cross-coupling of aryl halides with dialkyl phosphite, diphenylphosphine oxide, and diphenylphosphine.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120727

Title: Oxidation products of calcium and strontium bis(diphenylphosphanide).

Journal: Inorganic chemistry 20120716

Title: Synthesis of water-soluble phosphine oxides by Pd/C-catalyzed P-C coupling in water.

Journal: Organic letters 20120420

Title: Solubilization of triphenylamine, triphenylphosphine, triphenylphosphineoxide and triphenylmethanol in single and binary surfactant systems.

Journal: Journal of colloid and interface science 20111201

Title: (Z)-(1,2-Dichloro-vin-yl)diphenyl-phosphine oxide.

Journal: Acta crystallographica. Section E, Structure reports online 20110901

Title: A new phosphine oxide host based on ortho-disubstituted dibenzofuran for efficient electrophosphorescence: towards high triplet state excited levels and excellent thermal, morphological and efficiency stability.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20110801

Title: Manganese(III)-mediated phosphinoyl radical reactions for stereoselective synthesis of phosphinoylated tetrahydronaphthalenes.

Journal: Chemical communications (Cambridge, England) 20110721

Title: Ni(II)/Zn catalyzed reductive coupling of aryl halides with diphenylphosphine oxide in water.

Journal: Organic letters 20110701

Title: Sequential catalytic role of bifunctional bicyclic guanidine in asymmetric phospha-Michael reaction.

Journal: Organic & biomolecular chemistry 20110621

Title: Towards the limit of atropochiral stability: H-MIOP, an N-heterocyclic carbene precursor and cationic analogue of the H-MOP ligand.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20110426

Title: Chiral magnesium BINOL phosphate-catalyzed phosphination of imines: access to enantioenriched α-amino phosphine oxides.

Journal: Organic letters 20110415

Title: In vitro cytotoxic evaluation of a novel phosphinyl derivative of boldine.

Journal: Molecules (Basel, Switzerland) 20110307

Title: Triphenylphosphine oxide is a potent and selective inhibitor of the transient receptor potential melastatin-5 ion channel.

Journal: Assay and drug development technologies 20101201

Title: Synthesis and SAR studies of 1,4-benzoxazine MenB inhibitors: novel antibacterial agents against Mycobacterium tuberculosis.

Journal: Bioorganic & medicinal chemistry letters 20101101

Title: (Diphenyl-phosphor-yl)(2-nitro-phen-yl)methanol.

Journal: Acta crystallographica. Section E, Structure reports online 20100901

Title: Calcium-centred phosphine oxide reactivity: P-C metathesis, reduction and P-P coupling.

Journal: Chemical communications (Cambridge, England) 20100414

Title: (2,4-Dichloro-phen-yl)(diphenyl-phosphor-yl)methanol.

Journal: Acta crystallographica. Section E, Structure reports online 20100201

Title: Bipolar host molecules for efficient blue electrophosphorescence: a quantum chemical design.

Journal: The journal of physical chemistry. A 20100121

Title: Time-resolved electron spin resonance spectroscopy of radicals formed during free radical polymerizations of alkyl acrylates.

Journal: Macromolecular rapid communications 20091201

Title: Synthesis, structures and reactivity of 2-phosphorylmethyl-1H-pyrrolato complexes of titanium, yttrium and zinc.

Journal: Dalton transactions (Cambridge, England : 2003) 20091021

Title: Methyl (S(p))-2-(diphenyl-phosphino)ferrocene-1-carboxyl-ate.

Journal: Acta crystallographica. Section E, Structure reports online 20091001

Title: 2-(2H-Benzotriazol-2-yl)-4-methyl-phenyl diphenyl-phosphinate.

Journal: Acta crystallographica. Section E, Structure reports online 20090801

Title: High-throughput analysis of drug binding interactions for the human cardiac channel, Kv1.5.

Journal: Biochemical pharmacology 20090115

Title: Neighboring group participation of phosphine oxide functionality in the highly regio- and stereoselective iodohydroxylation of 1,2-allenylic diphenyl phosphine oxides.

Journal: The Journal of organic chemistry 20081017

Title: Lewis base-catalyzed conjugate reduction and reductive aldol reaction of alpha,beta-unsaturated ketones using trichlorosilane.

Journal: Chemical communications (Cambridge, England) 20080928

Title: Comparison of the electrochemical and luminescence properties of two carbazole-based phosphine oxide Eu(III) complexes: effect of different bipolar ligand structures.

Journal: Chemphyschem : a European journal of chemical physics and physical chemistry 20080825

Title: (2S,4'R,5'R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmeth-yl)-5-phenyl-pent-4-enoate.

Journal: Acta crystallographica. Section E, Structure reports online 20080201

Title: (2-Chloro-phen-yl)(diphenyl-phosphor-yl)methanol.

Journal: Acta crystallographica. Section E, Structure reports online 20080101

Title: A novel tetrakis(pyrazolyl)borate ligand bearing triphenylphosphine oxide substituents.

Journal: Dalton transactions (Cambridge, England : 2003) 20071114

Title: Determination of NMR interaction parameters from double rotation NMR.

Journal: Journal of magnetic resonance (San Diego, Calif. : 1997) 20071001

Title: Multiporphyrin coordination arrays based on complexation of magnesium(II) porphyrins with porphyrinylphosphine oxides.

Journal: Dalton transactions (Cambridge, England : 2003) 20070607

Title: Lewis acid catalyzed ring-opening reactions of methylenecyclopropanes with diphenylphosphine oxide in the presence of sulfur or selenium.

Journal: Organic & biomolecular chemistry 20070207

Title: Synthesis, structures, and properties of meso-phosphorylporphyrins: self-organization through P-oxo-zinc coordination.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

Title: The enantiospecific synthesis of (+)-monomorine I using a 5-endo-trig cyclisation strategy.

Journal: Beilstein journal of organic chemistry 20070101

Title: Determination of triphenylphosphine oxide in active pharmaceutical ingredients by hollow-fiber liquid-phase microextraction followed by reversed-phase liquid chromatography.

Journal: Journal of chromatography. A 20060915

Title: A dibenzofuran-based host material for blue electrophosphorescence.

Journal: Organic letters 20060914

Title: EPR and DFT studies of the structure of phosphinyl radicals complexed by a pentacarbonyl transition metal.

Journal: The journal of physical chemistry. A 20060810

Title: Meso-porphyrinylphosphine oxides: mono- and bidentate ligands for supramolecular chemistry and the crystal structures of monomeric {[10,20-diphenylporphyrinatonickel(II)-5,15-diyl]-bis-[P(O)Ph(2)] and polymeric self-coordinated {[10,20-diphenylporphyrinatozinc(II)-5,15-diyl]-bis-[P(O)Ph(2)]}.

Journal: Inorganic chemistry 20060807

Title: Novel, potent inhibitors of human Kv1.5 K+ channels and ultrarapidly activating delayed rectifier potassium current.

Journal: The Journal of pharmacology and experimental therapeutics 20060601

Title: A direct catalytic asymmetric Mannich-type reaction via a dinuclear zinc catalyst: synthesis of either anti- or syn-alpha-hydroxy-beta-amino ketones.

Journal: Journal of the American Chemical Society 20060308

Title: Characterization of spectroscopic of Pr(DBM)3(TPPO)2 containing poly(methyl methacrylate).

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20060201

Title: Ruthenium-catalyzed formation of aryl(diphenyl)phosphine oxides by reactions of propargylic alcohols with diphenylphosphine oxide.

Journal: Organic letters 20050901

Title: Nickel-catalyzed addition of P(O)-H bonds to propargyl alcohols: one-pot generation of phosphinoyl 1,3-butadienes.

Journal: Organic letters 20050707

Title: Extent of sonochemical degradation and change of toxicity of a pharmaceutical precursor (triphenylphosphine oxide) in water as a function of treatment conditions.

Journal: Environment international 20050201

Title: A convenient method to remove ruthenium byproducts from olefin metathesis reactions using polymer-bound triphenylphosphine oxide (TPPO).

Journal: Molecular diversity 20050101

Title: A simple, general and efficient ketone synthesis via alkylation and dephosphinoylation of beta-keto-diphenylphosphine oxides.

Journal: Chemical communications (Cambridge, England) 20041121

Title: Double phosphinylation of propargylic alcohols: a novel synthetic route to 1,2-bis(diphenylphosphino)ethane derivatives.

Journal: Organic letters 20041028

Title: Synthesis of pyrroles from 1-dialkylamino-3-phosphoryl(or phosphanyl)allenes through 1,5-cyclization of conjugated azomethine ylide intermediates.

Journal: The Journal of organic chemistry 20040723

Title: Separation-friendly Mitsunobu reactions: a microcosm of recent developments in separation strategies.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20040705

Title: Microwave-assisted synthesis of allylic amines: considerable rate acceleration in the hydrozirconation-transmetalation-aldimine addition sequence.

Journal: Organic & biomolecular chemistry 20040221

Title: Evaluation of chiral oxazolines for the highly enantioselective diethylzinc addition to N-(diphenylphosphinoyl) imines.

Journal: The Journal of organic chemistry 20030530

Title: Preparation of enantiomerically pure 2'-substituted 2-diphenylphosphino-1,1'-binaphthyls by reductive cleavage of the carbon-phosphorus bond in a borane complex of 2-diphenylphosphino-2'-diphenylphosphinyl-1,1'-binaphthyl.

Journal: The Journal of organic chemistry 20011228

Title: Rhodium-catalyzed regio- and stereoselective addition of diphenylphosphine oxide to alkynes.

Journal: The Journal of organic chemistry 20010824

Title: Efficient scavenging of Ph3P and Ph3P=O with high-loading merrifield resin.

Journal: Organic letters 20010614

Title: A convenient method for the efficient removal of ruthenium byproducts generated during olefin metathesis reactions.

Journal: Organic letters 20010503

Title: Fragmentation of carbohydrate anomeric alkoxy radicals. synthesis of polyhydroxy piperidines and pyrrolidines related to carbohydrates.

Journal: The Journal of organic chemistry 20010309

Quotation Request
Company Name:
*
Contact Person:
*
Email:
*
Quantity Required:
*
Country:
Additional Info:
SDS
Tags:4559-70-0 Molecular Formula|4559-70-0 MDL|4559-70-0 SMILES|4559-70-0 Diphenylphosphine oxide