Home Other Building Blocks 484-11-7
484-11-7,MFCD00004973
Catalog No.:AA00I8PE

484-11-7 | 2,9-dimethyl-1,10-phenanthroline

Pack Size
Purity
Availability
Price(USD)
Quantity
  
1g
98%
in stock  
$12.00   $8.00
- +
5g
98%
in stock  
$22.00   $15.00
- +
10g
98%
in stock  
$26.00   $18.00
- +
25g
98%
in stock  
$64.00   $45.00
- +
100g
98%
in stock  
$239.00   $167.00
- +
  • Technical Information
  • Properties
  • Literature
  • Application
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA00I8PE
Chemical Name:
2,9-dimethyl-1,10-phenanthroline
CAS Number:
484-11-7
Molecular Formula:
C14H12N2
Molecular Weight:
208.2585
MDL Number:
MFCD00004973
SMILES:
Cc1ccc2c(n1)c1nc(C)ccc1cc2
NSC Number:
4280
Properties
Computed Properties
 
Complexity:
227  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
16  
Hydrogen Bond Acceptor Count:
2  
XLogP3:
3.3  

Literature

Title: Copper-redox cycling by coumarin-di(2-picolyl)amine hybrid molecule leads to ROS-mediated DNA damage and apoptosis: A mechanism for cancer chemoprevention.

Journal: Chemico-biological interactions 20180625

Title: Perturbation of copper homeostasis is instrumental in early developmental arrest of intraerythrocytic Plasmodium falciparum.

Journal: BMC microbiology 20140101

Title: Copper(I) (pseudo)halide complexes with neocuproine and aminomethylphosphines derived from morpholine and thiomorpholine - in vitro cytotoxic and antimicrobial activity and the interactions with DNA and serum albumins.

Journal: Chemical biology & drug design 20131101

Title: Production of LPS-induced inflammatory mediators in murine peritoneal macrophages: neocuproine as a broad inhibitor and ATP7A as a selective regulator.

Journal: Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine 20130601

Title: Catalyst-controlled regioselectivity in the synthesis of branched conjugated dienes via aerobic oxidative Heck reactions.

Journal: Journal of the American Chemical Society 20121010

Title: Aerobic oxidation of primary alcohols catalyzed by copper complexes of 1,10-phenanthroline-derived ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20121007

Title: Reactions of the cationic zinc thiolate model complex [Zn(Tab)4](PF6)2 with N-donor ligands and cobalt dichloride.

Journal: Inorganic chemistry 20121001

Title: Modulation in selectivity and allosteric properties of small-molecule ligands for CC-chemokine receptors.

Journal: Journal of medicinal chemistry 20120927

Title: Field-induced slow magnetic relaxation in a six-coordinate mononuclear cobalt(II) complex with a positive anisotropy.

Journal: Journal of the American Chemical Society 20120926

Title: Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(III) species by molecular oxygen.

Journal: Dalton transactions (Cambridge, England : 2003) 20120714

Title: 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetra-chloridoferrate(III) methanol monosolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20120701

Title: Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')zinc.

Journal: Acta crystallographica. Section E, Structure reports online 20120601

Title: Exceptionally long-lived luminescence from [Cu(I)(isocyanide)2(phen)]+ complexes in nanoporous crystals enables remarkable oxygen gas sensing.

Journal: Journal of the American Chemical Society 20120530

Title: New family of thiocyanate-bridged Re(IV)-SCN-M(II) (M = Ni, Co, Fe, and Mn) heterobimetallic compounds: synthesis, crystal structure, and magnetic properties.

Journal: Inorganic chemistry 20120521

Title: Restricted photochemistry in the molecular solid state: structural changes on photoexcitation of Cu(I) phenanthroline metal-to-ligand charge transfer (MLCT) complexes by time-resolved diffraction.

Journal: The journal of physical chemistry. A 20120405

Title: Differences in responsivity of original cupric reducing antioxidant capacity and cupric-bathocuproine sulfonate assays to antioxidant compounds.

Journal: Analytical biochemistry 20120401

Title: (2,9-Dimethyl-1,10-phenanthroline-κ(2)N,N')bis-(2-meth-oxy-benzoato-κ(2)O(1),O(1'))cadmium.

Journal: Acta crystallographica. Section E, Structure reports online 20120401

Title: Theoretical insights into the ferromagnetic coupling in oxalato-bridged chromium(III)-cobalt(II) and chromium(III)-manganese(II) dinuclear complexes with aromatic diimine ligands.

Journal: Inorganic chemistry 20120305

Title: 2-Amino-pyridinium bis-(pyridine-2,6-dicarboxyl-ato)ferrate(III).

Journal: Acta crystallographica. Section E, Structure reports online 20120201

Title: Reactions of cadmium(II) nitrate with 4-(trimethylammonio)benzenethiolate in the presence of N-donor ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20120114

Title: 2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb-oxy-4-hy-droxy-pyridine-2-carboxyl-ato-κO,N,O)(4-hy-droxy-pyridine-2,6-dicarboxyl-ato-κO,N,O)zincate(II) 2.35-hydrate: a proton-transfer compound.

Journal: Acta crystallographica. Section E, Structure reports online 20120101

Title: (3-{[N-(5-Chloro-2-hy-droxy-phen-yl)oxamo-yl]amino}-prop-yl)dimethyl-aza-nium perchlorate.

Journal: Acta crystallographica. Section E, Structure reports online 20120101

Title: Synthesis, characterization, cellular uptake, apoptosis, cytotoxicity, dna-binding, and antioxidant activity studies of ruthenium(II) complexes.

Journal: Nucleosides, nucleotides & nucleic acids 20120101

Title: Effect of substituent of terpyridines on the DNA-interaction of polypyridyl ruthenium(II) complexes.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20111215

Title: (2,9-Dimethyl-1,10-phenanthroline-κN,N')diiodidocadmium.

Journal: Acta crystallographica. Section E, Structure reports online 20111201

Title: Dibromido(2,9-dimethyl-1,10-phenanthroline-κN,N')cadmium.

Journal: Acta crystallographica. Section E, Structure reports online 20111201

Title: Synthesis of functionalized cinnamaldehyde derivatives by an oxidative Heck reaction and their use as starting materials for preparation of Mycobacterium tuberculosis 1-deoxy-D-xylulose-5-phosphate reductoisomerase inhibitors.

Journal: The Journal of organic chemistry 20111104

Title: Spectral and electrochemical studies of bis(diimine)copper(II) complexes in anionic, cationic and nonionic micelles.

Journal: Journal of colloid and interface science 20111015

Title: Aqua-(dicyanamido-κN)(2,9-dimethyl-1,10-phenanthroline-κN,N')(nitrato-κO,O')cobalt(II)-2,9-dimethyl-1,10-phenanthroline-water (2/1/2).

Journal: Acta crystallographica. Section E, Structure reports online 20111001

Title: Neocuproine-KOtBu promoted intramolecular cross coupling to approach fused rings.

Journal: Chemical communications (Cambridge, England) 20110921

Title: Aqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')diformato-κO,O';κO-nickel(II) monohydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20110901

Title: Synthesis, structural characterization and luminescent properties of a series of Cu(I) complexes based on polyphosphine ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20110807

Title: Biological activity and structure dependent properties of cuprous iodide complexes with phenanthrolines and water soluble tris (aminomethyl) phosphanes.

Journal: Journal of inorganic biochemistry 20110801

Title: Carnosine and neocuproine as neutralizing agents for copper overload-induced damages in cultured human cells.

Journal: Chemico-biological interactions 20110715

Title: Synthesis, crystal structures, and magnetic properties of a new family of heterometallic cyanide-bridged Fe(III)2M(II)2 (M=Mn, Ni, and Co) square complexes.

Journal: Inorganic chemistry 20110704

Title: DNA interaction studies of cobalt (II) mixed-ligand complexes containing dimethyl-1, 10-phenanthroline and dipyrido[3,2-a:2',3'-c]phenazine: the role of methyl substitutions on the mode of binding.

Journal: DNA and cell biology 20110701

Title: Coherent nuclear dynamics in ultrafast photoinduced structural change of bis(diimine)copper(I) complex.

Journal: Journal of the American Chemical Society 20110525

Title: Amino-anthraquinone chromophores functionalised with 3-picolyl units: structures, luminescence, DFT and their coordination chemistry with cationic Re(I) di-imine complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20110414

Title: Structures, electronic properties and solid state luminescence of Cu(I) iodide complexes with 2,9-dimethyl-1,10-phenanthroline and aliphatic aminomethylphosphines or triphenylphosphine.

Journal: Dalton transactions (Cambridge, England : 2003) 20110321

Title: Solid-state dinuclear-to-trinuclear conversion in an oxalato-bridged chromium(III)-cobalt(II) complex as a new route toward single-molecule magnets.

Journal: Inorganic chemistry 20110321

Title: DNA binding and gel electrophoresis studies of a new silver(I) complex containing 2,9-dimethyl-1,10-phenanthroline ligands.

Journal: DNA and cell biology 20110301

Title: Highly diastereoselective C(sp3)-C(sp) cross-coupling reactions between 1,3- and 1,4-substituted cyclohexylzinc reagents and bromoalkynes through remote stereocontrol.

Journal: Angewandte Chemie (International ed. in English) 20110225

Title: Zebrafish sod1 and sp1 expression are modulated by the copper ATPase gene atp7a in response to intracellular copper status.

Journal: Chemico-biological interactions 20110201

Title: Aqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')(formato-κO,O')(formato-κO)cobalt(II) monohydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20110101

Title: Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nona-hydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20110101

Title: Magneto-structural studies on heterobimetallic malonate-bridged M(II)Re(IV) complexes (M = Mn, Co, Ni and Cu).

Journal: Dalton transactions (Cambridge, England : 2003) 20101221

Title: An efficient organocatalytic method for constructing biaryls through aromatic C-H activation.

Journal: Nature chemistry 20101201

Title: Oxygen gas sensing by luminescence quenching in crystals of Cu(xantphos)(phen)+ complexes.

Journal: Journal of the American Chemical Society 20101013

Title: Synthesis of aryl ketones by palladium(II)-catalyzed decarboxylative addition of benzoic acids to nitriles.

Journal: Angewandte Chemie (International ed. in English) 20101011

Title: Dichlorido(2,9-dimethyl-1,10-phenanthroline-κN,N')cobalt(II).

Journal: Acta crystallographica. Section E, Structure reports online 20101001

Title: catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κN,N')cobalt(II)]-μ-malonato-κO,O:O,O].

Journal: Acta crystallographica. Section E, Structure reports online 20101001

Title: 2,2'-(Disulfanedi-yl)dibenzoic acid-2,9-dimethyl-phenanthroline-tetra-hydro-furan (1/2/1).

Journal: Acta crystallographica. Section E, Structure reports online 20101001

Title: 2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb-oxy-4-hy-droxy-pyridine-2-carboxyl-ato-κO,N,O)(4-hy-droxy-pyridine-2,6-dicarboxyl-ato-κO,N,O)nickelate(II) 2.35-hydrate: a proton-transfer compound.

Journal: Acta crystallographica. Section E, Structure reports online 20100901

Title: Determination of peroxide-based explosives with copper(II)-neocuproine assay combined with a molecular spectroscopic sensor.

Journal: The Analyst 20100801

Title: Benzoic acid-2,9-dimethyl-phenanthroline (1/1).

Journal: Acta crystallographica. Section E, Structure reports online 20100801

Title: Determination of antioxidants by a novel on-line HPLC-cupric reducing antioxidant capacity (CUPRAC) assay with post-column detection.

Journal: Analytica chimica acta 20100726

Title: DNA binding, cytotoxicity, and apoptotic-inducing activity of ruthenium(II) polypyridyl complex.

Journal: Acta biochimica et biophysica Sinica 20100701

Title: Bis(2,9-dimethyl-1,10-phenanthroline-κN,N')bis-(nitrato-κO,O')lead(II).

Journal: Acta crystallographica. Section E, Structure reports online 20100701

Title: DNA binding and gel electrophoresis studies of a copper (II) complex containing mixed aliphatic and aromatic dinitrogen ligands.

Journal: DNA and cell biology 20100601

Title: Tritopic phenanthroline and pyridine tail-tied aza-scorpiands.

Journal: Organic & biomolecular chemistry 20100521

Title: Stability of disubstituted copper complexes in the gas phase analyzed by electrospray ionization mass spectrometry.

Journal: Rapid communications in mass spectrometry : RCM 20100515

Title: Development of a low-cost optical sensor for cupric reducing antioxidant capacity measurement of food extracts.

Journal: Analytical chemistry 20100515

Title: Bis[bis-(4,4'-dimethyl-2,2'-bipyridine)(10,11,12,13-tetra-hydro-dipyrido[3,2-a:2',3'-c]phenazine)ruthenium(II)] tetra-kis(perchlorate) acetonitrile disolvate monohydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20100501

Title: Dithiocarbamates are teratogenic to developing zebrafish through inhibition of lysyl oxidase activity.

Journal: Toxicology and applied pharmacology 20100415

Title: Bis(2,2'-bipyridyl-κN,N')bis-(2-hydroxy-benzoato)-κO;κO,O-cadmium(II) methanol solvate.

Journal: Acta crystallographica. Section E, Structure reports online 20100201

Title: Bis(2,9-dimethyl-1,10-phenanthroline-κN,N')(10,11,12,13-tetra-hydro-dipyrido[3,2-a:2',3'-c]phenazine-κN,N)ruthenium(II) bis-(perchlorate) dihydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20100201

Title: 2,9-Bis(trichloro-meth-yl)-1,10-phenanthroline.

Journal: Acta crystallographica. Section E, Structure reports online 20100201

Title: Syntheses, structures and spectroscopy of uni- and bi-dentate nitrogen base complexes of silver(I) trifluoromethanesulfonate.

Journal: Dalton transactions (Cambridge, England : 2003) 20100121

Title: Synthesis, characterization, interaction with DNA and cytotoxicity in vitro of the complexes [M(dmphen)(CO3)].H2O [M=Pt(II), Pd(II)].

Journal: European journal of medicinal chemistry 20100101

Title: Dichlorido(2,9-dimethyl-1,10-phenanthroline)manganese(II) hemihydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20091201

Title: Dibromido(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Journal: Acta crystallographica. Section E, Structure reports online 20091101

Title: (6,6'-Dimethyl-2,2'-bipyridine-κN,N')diiodidozinc(II).

Journal: Acta crystallographica. Section E, Structure reports online 20091101

Title: Dichlorido(2,9-dimethyl-1,10-phenanthroline-κN,N')copper(II).

Journal: Acta crystallographica. Section E, Structure reports online 20091001

Title: Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Journal: Acta crystallographica. Section E, Structure reports online 20091001

Title: Plumbagin induces cell death through a copper-redox cycle mechanism in human cancer cells.

Journal: Mutagenesis 20090901

Title: A chemical screening approach reveals that indole fluorescence is quenched by pre-fibrillar but not fibrillar amyloid-beta.

Journal: Bioorganic & medicinal chemistry letters 20090901

Title: Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κN,N')mercury(II) acetonitrile hemisolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20090801

Title: Aqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')bis-(3-hydroxy-benzoato-κO)manganese(II)-2,9-dimethyl-1,10-phenanthroline-water (1/1/1).

Journal: Acta crystallographica. Section E, Structure reports online 20090801

Title: Dichloridobis(phenanthridine-κN)zinc(II).

Journal: Acta crystallographica. Section E, Structure reports online 20090701

Title: (2,9-Dimethyl-1,10-phenanthroline)(4-hydroxy-pyridine-2,6-dicarboxyl-ato)copper(II) trihydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20090701

Title: Equilibrium and ab initio computational studies on the adduct formation of 1,3-diketonato-lithium(I), -sodium(I) and -potassium(I) with 1,10-phenanthroline and its 2,9-dimethyl derivatives.

Journal: Talanta 20090615

Title: Capturing and analyzing the excited-state structure of a Cu(I) phenanthroline complex by time-resolved diffraction and theoretical calculations.

Journal: Journal of the American Chemical Society 20090513

Title: Synthesis, crystal structure, cytotoxic activities and DNA-binding properties of new binuclear copper(II) complexes bridged by N,N'-bis(N-hydroxyethylaminoethyl)oxamide.

Journal: Journal of inorganic biochemistry 20090501

Title: Dibromido(2,9-dimethyl-1,10-phenanthroline-κN,N')mercury(II).

Journal: Acta crystallographica. Section E, Structure reports online 20090501

Title: Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20090501

Title: Differential effect of neocuproine, a copper(I) chelator, on contractile activity in isolated ovariectomized non-pregnant rat, pregnant rat and pregnant human uterus.

Journal: European journal of pharmacology 20090301

Title: Aqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')bis-(2-hydroxy-benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20090201

Title: Bis(phenanthridinium) hexa-chloridoplatinate(IV) dimethyl sulfoxide disolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20090201

Title: Development of a Novel, Ultra-rapid Biosensor for the Qualitative Detection of Hepatitis B Virus-associated Antigens and Anti-HBV, Based on 'Membrane-engineered' Fibroblast Cells with Virus-Specific Antibodies and Antigens.

Journal: Sensors (Basel, Switzerland) 20090101

Title: (2,9-Dimethyl-1,10-phenanthroline-κN,N')bis-(2-hydroxy-benzoato-κO)copper(II).

Journal: Acta crystallographica. Section E, Structure reports online 20081201

Title: Diaqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')(4-hydroxy-benzoato-κO,O')cobalt(II) nitrate dihydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20081201

Title: (2,9-Dimethyl-1,10-phenanthroline-κN,N')(4-hydroxy-benzoato-κO,O')(nitrato-κO)copper(II).

Journal: Acta crystallographica. Section E, Structure reports online 20081101

Title: New chemistry of olefin complexes of platinum(II) unravelled by basic conditions: synthesis and properties of elusive cationic species.

Journal: Dalton transactions (Cambridge, England : 2003) 20081021

Title: A new approach for the detection of ethylene using silica-supported palladium complexes.

Journal: Inorganic chemistry 20081006

Title: (4,4'-Dimethyl-2,2'-bipyridine-κN,N')diiodidomercury(II).

Journal: Acta crystallographica. Section E, Structure reports online 20081001

Title: Dichlorido(6-methyl-2,2'-bipyridine-κN,N')zinc(II).

Journal: Acta crystallographica. Section E, Structure reports online 20081001

Title: Bis(2,4,6-trimethyl-pyridinium) hexa-chloridoplatinate(IV).

Journal: Acta crystallographica. Section E, Structure reports online 20081001

Title: (4,7-Diphenyl-1,10-phenanthroline-κN,N')diiodidomercury(II).

Journal: Acta crystallographica. Section E, Structure reports online 20081001

Title: Theoretical characterization of a typical hole/exciton-blocking material bathocuproine and its analogues.

Journal: The journal of physical chemistry. A 20080925

Title: A selective resonance scattering assay for immunoglobulin G using Cu(II)-ascorbic acid-immunonanogold reaction.

Journal: Analytical biochemistry 20080915

Title: A strategy for direct identification of protein S-nitrosylation sites by quadrupole time-of-flight mass spectrometry.

Journal: Journal of the American Society for Mass Spectrometry 20080901

Title: An unusual two-dimensional hydrogen-bonding network in bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) peroxodisulfate dihydrate.

Journal: Acta crystallographica. Section C, Crystal structure communications 20080901

Title: Bis(2,6-dimethyl-pyridinium) hexa-chlorido-platinate(IV).

Journal: Acta crystallographica. Section E, Structure reports online 20080901

Title: Plant polyphenols mobilize nuclear copper in human peripheral lymphocytes leading to oxidatively generated DNA breakage: implications for an anticancer mechanism.

Journal: Free radical research 20080801

Title: A second polymorph of aqua-(2,9-di-methyl-1,10-phenanthroline-κN,N')bis-(formato-κO)copper(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080801

Title: The anthocyanidin delphinidin mobilizes endogenous copper ions from human lymphocytes leading to oxidative degradation of cellular DNA.

Journal: Toxicology 20080710

Title: Three-dimensional local structure of photoexcited Cu diimine complex refined by quantitative XANES analysis.

Journal: The journal of physical chemistry. A 20080619

Title: Hydroxyl radical scavenging assay of phenolics and flavonoids with a modified cupric reducing antioxidant capacity (CUPRAC) method using catalase for hydrogen peroxide degradation.

Journal: Analytica chimica acta 20080602

Title: (2,9-Dimethyl-1,10-phenanthroline-κN,N')bis-(2-hydroxy-benzoato)-κO;κO,O'-cobalt(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080501

Title: Apoptosis of cultured astrocytes induced by the copper and neocuproine complex through oxidative stress and JNK activation.

Journal: Toxicological sciences : an official journal of the Society of Toxicology 20080301

Title: Bis(benzoato-κO,O')(2,9-dimethyl-1,10-phenanthroline-κN,N')cobalt(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080201

Title: DNA strand-scission by phloroglucinols and lignans from heartwood of Garcinia subelliptica Merr. and Justicia plants.

Journal: Phytochemistry 20080101

Title: Activation of epidermal growth factor receptor by metal-ligand complexes decreases levels of extracellular amyloid beta peptide.

Journal: The international journal of biochemistry & cell biology 20080101

Title: BLT-1, a specific inhibitor of the HDL receptor SR-BI, induces a copper-dependent phenotype during zebrafish development.

Journal: Toxicology letters 20071210

Title: Synchronized fluxional motion and cyclometalation of ligands in platinum(II) complexes.

Journal: Inorganic chemistry 20071210

Title: Synthesis, crystal structure and magnetic properties of novel heterobimetallic malonate-bridged MIIReIV complexes (M = Mn, Fe, Co and Ni).

Journal: Dalton transactions (Cambridge, England : 2003) 20071207

Title: Differential modulation of Alzheimer's disease amyloid beta-peptide accumulation by diverse classes of metal ligands.

Journal: The Biochemical journal 20071101

Title: Vitamin B12b increases the cytotoxicity of short-time exposure to ascorbic acid, inducing oxidative burst and iron-dependent DNA damage.

Journal: European journal of pharmacology 20070702

Title: Effect of copper on the cytotoxicity of phenanthrene and 9,10-phenanthrenequinone to the human placental cell line, JEG-3.

Journal: Reproductive toxicology (Elmsford, N.Y.) 20070601

Title: Simultaneous kinetic determination of levodopa and carbidopa by H-point standard addition method.

Journal: Journal of pharmaceutical and biomedical analysis 20070509

Title: Real-time observation of the photoinduced structural change of bis(2,9-dimethyl-1,10-phenanthroline)copper(I) by femtosecond fluorescence spectroscopy: a realistic potential curve of the Jahn-Teller distortion.

Journal: Journal of the American Chemical Society 20070425

Title: Spectrophotometric determination of ascorbic acid by the modified CUPRAC method with extractive separation of flavonoids-La(III) complexes.

Journal: Analytica chimica acta 20070404

Title: Ultrafast structural rearrangements in the MLCT excited state for copper(I) bis-phenanthrolines in solution.

Journal: Journal of the American Chemical Society 20070221

Title: First investigation at elevated pressures to confirm the exact nature of the gated electron-transfer systems: volume profiles of the gated reduction reaction and nongated reverse oxidation reaction involving a [Cu(dmp)2(solvent)]2+/[Cu(dmp)2]+ couple (dmp = 2,9-dimethyl-1,10-phenanthroline).

Journal: Inorganic chemistry 20070219

Title: Prooxidant DNA breakage induced by caffeic acid in human peripheral lymphocytes: involvement of endogenous copper and a putative mechanism for anticancer properties.

Journal: Toxicology and applied pharmacology 20070201

Title: Magnetic properties and molecular structures of binuclear (2-pyrazinecarboxylate)-bridged complexes containing Re(IV) and M(II) (M = Co, Ni).

Journal: Dalton transactions (Cambridge, England : 2003) 20070121

Title: Nucleic acid biosensor for detection of hepatitis B virus using 2,9-dimethyl-1,10-phenanthroline copper complex as electrochemical indicator.

Journal: Analytica chimica acta 20070116

Title: RNA cleavage by 2,9-diamino-1,10-phenanthroline PNA conjugates.

Journal: Nucleosides, nucleotides & nucleic acids 20070101

Title: Effect of the environment on molecular properties: synthesis, structure, and photoluminescence of Cu(I) bis(2,9-dimethyl-1,10-phenanthroline) nanoclusters in eight different supramolecular frameworks.

Journal: Inorganic chemistry 20061113

Title: Sterically hindered complexes of platinum(II) with planar heterocyclic nitrogen donors. A novel complex with 1-methyl-cytosine has a spectrum of activity different from cisplatin and is able of overcoming acquired cisplatin resistance.

Journal: Journal of inorganic biochemistry 20061101

Title: A series of luminescent Cu(I) mixed-ligand complexes containing 2,9-dimethyl-1,10-phenanthroline and simple diphosphine ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20061007

Title: Dithiocarbamates have a common toxic effect on zebrafish body axis formation.

Journal: Toxicology and applied pharmacology 20061001

Title: Microsphere-based protease assays and screening application for lethal factor and factor Xa.

Journal: Cytometry. Part A : the journal of the International Society for Analytical Cytology 20060501

Title: Ruthenium-cluster-mediated activation of all bonds of a methyl group of 6,6'-dimethyl-2,2'-bipyridine and 2,9-dimethyl-1,10-phenanthroline: transformation of the latter into a 2-alkenyl-9-methyl-1,10-phenanthroline ligand.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060201

Title: Plant polyphenols mobilize endogenous copper in human peripheral lymphocytes leading to oxidative DNA breakage: a putative mechanism for anticancer properties.

Journal: FEBS letters 20060123

Title: Coordination chemistry of phosphanyl amino acids: solid state and solution structures of neutral and cationic rhodium complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20060107

Title: Ascorbic acid mobilizes endogenous copper in human peripheral lymphocytes leading to oxidative DNA breakage: a putative mechanism for anticancer properties.

Journal: The international journal of biochemistry & cell biology 20060101

Title: The cupric ion reducing antioxidant capacity and polyphenolic content of some herbal teas.

Journal: International journal of food sciences and nutrition 20060101

Title: Platinum-based antitumor drugs containing enantiomerically pure alpha-trifluoromethyl alanine as ligand.

Journal: Journal of medicinal chemistry 20051201

Title: Regioselective alkene carbon-carbon bond cleavage to aldehydes and chemoselective alcohol oxidation of allylic alcohols with hydrogen peroxide catalyzed by [cis-Ru(II)(dmp)2(H2O)2]2+ (dmp = 2,9-dimethylphenanthroline).

Journal: Organic letters 20051027

Title: Neocuproine, a copper (I) chelator, potentiates purinergic component of vas deferens contractions elicited by electrical field stimulation.

Journal: Pharmacology 20051001

Title: Total antioxidant capacity assay of human serum using copper(II)-neocuproine as chromogenic oxidant: the CUPRAC method.

Journal: Free radical research 20050901

Title: Synthesis, characterization, crystal structure, and electrochemical, photophysical, and protein-binding properties of luminescent rhenium(I) diimine indole complexes.

Journal: Inorganic chemistry 20050822

Title: Two novel bis(2,9-dimethyl-1,10-phenanthroline)copper(I) complexes: [Cu(dmp)2]2(PF6)2.0.5(bpmh).CH3CN and [Cu(dmp)2][N(CN)2].

Journal: Acta crystallographica. Section C, Crystal structure communications 20050701

Title: Further evidence supporting an inner sphere mechanism in the NO reduction of the copper(II) complex Cu(dmp)2(2+) (dmp=2,9-dimethyl-1,10-phenanthroline).

Journal: Nitric oxide : biology and chemistry 20050601

Title: Bis(2,9-dimethyl-1,10-phenanthroline-kappa(2)N,N')copper(I) hydrogen squarate hemihydrate.

Journal: Acta crystallographica. Section C, Crystal structure communications 20050601

Title: Platinum(II) complexes with antitumoral/antiviral aromatic heterocycles: effect of glutathione upon in vitro cell growth inhibition.

Journal: Journal of medicinal chemistry 20050505

Title: A spectroscopic and computational study on the effects of methyl and phenyl substituted phenanthroline ligands on the electronic structure of Re(I) tricarbonyl complexes containing 2,6-dimethylphenylisocyanide.

Journal: Dalton transactions (Cambridge, England : 2003) 20050321

Title: Syntheses, structural analyses and redox kinetics of four-coordinate [CuL2]2+ and five-coordinate [CuL2(solvent)]2+ complexes (L = 6,6'-dimethyl-2,2'-bipyridine or 2,9-dimethyl-1,10-phenanthroline): completely gated reduction reaction of [Cu(dmp)2]2+ in nitromethane.

Journal: Dalton transactions (Cambridge, England : 2003) 20050321

Title: Structural properties and dissociative fluxional motion of 2,9-dimethyl-1,10-phenanthroline in platinum(II) complexes.

Journal: Inorganic chemistry 20050307

Title: Effect of neocuproine, a copper(i) chelator, on rat bladder function.

Journal: The Journal of pharmacology and experimental therapeutics 20050301

Title: Studies in oligonucleotide-based artificial nuclease systems. intramolecular copper (II) complex formation in an oligonucleotide bis-phenanthroline conjugate.

Journal: Nucleosides, nucleotides & nucleic acids 20050101

Title: Novel total antioxidant capacity index for dietary polyphenols and vitamins C and E, using their cupric ion reducing capability in the presence of neocuproine: CUPRAC method.

Journal: Journal of agricultural and food chemistry 20041229

Title: Cu(I)(2,9-bis(trifluoromethyl)-1,10-phenanthroline)2+ complexes: correlation between solid-state structure and photoluminescent properties.

Journal: Inorganic chemistry 20041227

Title: Photochemical expulsion of the neutral monodentate ligand L in Ru(terpy*)(diimine)(L)2+: a dramatic effect of the steric properties of the spectator diimine ligand.

Journal: Inorganic chemistry 20041227

Title: Synthesis, crystal structures, and anti-convulsant activities of ternary [Zn(II)(3,5-diisopropylsalicylate)(2)], [Zn(II)(salicylate)(2)] and [Zn(II)(aspirinate)(2)] complexes.

Journal: Journal of inorganic biochemistry 20041101

Title: Zn2+-catalyzed methanolysis of phosphate triesters: a process for catalytic degradation of the organophosphorus pesticides paraoxon and fenitrothion.

Journal: Inorganic chemistry 20041018

Title: Aldehydic DNA lesions in calf thymus DNA and HeLa S3 cells produced by bacterial quinone metabolites of fluoranthene and pyrene.

Journal: Carcinogenesis 20040901

Title: Role of OGG1 and NTG2 in the repair of oxidative DNA damage and mutagenesis induced by hydrogen peroxide in Saccharomyces cerevisiae: relationships with transition metals iron and copper.

Journal: Yeast (Chichester, England) 20040901

Title: Nitric oxide and BCNU chemoresistance in C6 glioma cells: role of S-nitrosoglutathione.

Journal: Free radical biology & medicine 20040515

Title: General method for the synthesis of 8-arylsulfanyl adenine derivatives.

Journal: The Journal of organic chemistry 20040430

Title: Evidence that NiNi acetyl-CoA synthase is active and that the CuNi enzyme is not.

Journal: Biochemistry 20040406

Title: Sensitive indirect spectrophotometric determination of isoniazid.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20040301

Title: Neocuproine inhibits the decomposition of endogenous S-nitrosothiol by ultraviolet irradiation in the mouse gastric fundus.

Journal: European journal of pharmacology 20040206

Title: Metal-assisted light-induced DNA cleavage activity of 2-(methylthio)phenylsalicylaldimine Schiff base copper(II) complexes having planar heterocyclic bases.

Journal: Journal of inorganic biochemistry 20040201

Title: Speciation of ternary cobalt(II) phenanthroline-silica surface complexes as a function of pH and ligand steric bulk.

Journal: Inorganic chemistry 20031117

Title: Ternary copper complexes for photocleavage of DNA by red light: direct evidence for sulfur-to-copper charge transfer and d-d band involvement.

Journal: Journal of the American Chemical Society 20031008

Title: Structure-dependent photophysical properties of singlet and triplet metal-to-ligand charge transfer states in copper(I) bis(diimine) compounds.

Journal: Inorganic chemistry 20031006

Title: Modulation of mitochondrial membrane potential and reactive oxygen species production by copper in astrocytes.

Journal: Journal of neurochemistry 20031001

Title: Utilization of activating and masking effects by ligands for highly selective catalytic spectrophotometric determination of copper and iron in natural waters.

Journal: Talanta 20030829

Title: 'Chiral-at-Metal' octahedral ruthenium(II) complexes with achiral ligands: a new type of enantioselective catalyst.

Journal: Inorganic chemistry 20030811

Title: MLCT state structure and dynamics of a copper(I) diimine complex characterized by pump-probe X-ray and laser spectroscopies and DFT calculations.

Journal: Journal of the American Chemical Society 20030611

Title: Intracellular metal ion chelators inhibit TNFalpha-induced SP-1 activation and adhesion molecule expression in human aortic endothelial cells.

Journal: Free radical biology & medicine 20030315

Title: Heterobimetallic oxalato-bridged M(II)Re(IV) complexes (M = Mn, Fe, Co, Ni): synthesis, crystal structure, and magnetic properties.

Journal: Inorganic chemistry 20030224

Title: Inner-sphere complexation of cobalt(II) 2,9-dimethyl-1,10-phenanthroline ([Co(neo)]2+) with commercial and sol-gel derived silica gel surfaces.

Journal: Inorganic chemistry 20030127

Title: Excited state molecular structure determination in disordered media using laser pump/X-ray probe time-domain X-ray absorption spectroscopy.

Journal: Faraday discussions 20030101

Title: Anti- and pro-oxidant effects of urate in copper-induced low-density lipoprotein oxidation.

Journal: European journal of biochemistry 20021101

Title: Rapid excited-state structural reorganization captured by pulsed X-rays.

Journal: Journal of the American Chemical Society 20020911

Title: The oxidative effect of bacterial lipopolysaccharide on native and cross-linked human hemoglobin as a function of the structure of the lipopolysaccharide.

Journal: European journal of biochemistry 20020901

Title: Bis(1,10-phenanthroline)(thiosulfato)manganese(II) methanol solvate and catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline)manganese(II)]-mu-thiosulfato].

Journal: Acta crystallographica. Section C, Crystal structure communications 20020801

Title: Heme nitrosylation of deoxyhemoglobin by s-nitrosoglutathione requires copper.

Journal: The Journal of biological chemistry 20020705

Title: Investigation of the reaction of copper(I) with 2,9-dimethyl-1,10-phenanthroline at trace level by thermal lensing.

Journal: Talanta 20020703

Title: Synthesis and structural characterization of Cu(I) and Ni(II) complexes that contain the bis[2-(diphenylphosphino)phenyl]ether ligand. Novel emission properties for the Cu(I) species.

Journal: Inorganic chemistry 20020617

Title: Catalytic effect of sulfoxides on the fluxional motion of 2,9-dimethyl-1,10-phenanthroline in a platinum(II) complex: evaluation of steric and electronic contributions.

Journal: Inorganic chemistry 20020603

Title: Pairing of propellers: dimerization of octahedral ruthenium(II) and osmium(II) complexes of eilatin via pi-pi stacking featuring heterochiral recognition.

Journal: Journal of the American Chemical Society 20020515

Title: Synergic extraction of lanthanoids by mixtures of LIX 54 (high molecular weight beta-diketone) and bidentate neutral amines.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20020301

Title: Redox induced reversible structural transformations of dimeric and polymeric phenanthroline-based copper chelates.

Journal: Inorganic chemistry 20020225

Title: Synthesis, characterization, photophysical properties, and biological labeling studies of a series of luminescent rhenium(I) polypyridine maleimide complexes.

Journal: Inorganic chemistry 20020114

Title: Simple Cu(I) complexes with unprecedented excited-state lifetimes.

Journal: Journal of the American Chemical Society 20020109

Title: A approximately 35 kDa polypeptide from insect cells binds to yeast ACS like elements in the presence of ATP.

Journal: BMC biochemistry 20020101

Title: Low-density lipoprotein modification by normal, myeloperoxidase-deficient and NADPH oxidase-deficient granulocytes and the impact of redox active transition metal ions.

Journal: Redox report : communications in free radical research 20020101

Title: Chloro(2,9-dimethyl-1,10-phenanthroline-N,N')(isoquinoline-1-carboxylato-O,N)copper(II).

Journal: Acta crystallographica. Section C, Crystal structure communications 20011101

Title: Electrochemiluminescence of copper(I) bis(2,9-dimethyl-1,10- phenanthroline).

Journal: Analytical chemistry 20011001

Title: Oxidative DNA damage by capsaicin and dihydrocapsaicin in the presence of Cu(II).

Journal: Cancer letters 20010828

Title: Fluxional behavior of the dinitrogen ligand 2,9-dimethyl-1,10-phenanthroline in cationic methyl platinum(II) complexes.

Journal: Inorganic chemistry 20010702

Title: Nitric oxide initiates iron binding to neocuproine.

Journal: Nitric oxide : biology and chemistry 20010401

Title: Role of copper ions and cytochrome P450 in the vasodilator actions of the nitroxyl anion generator, Angeli's salt, on rat aorta.

Journal: European journal of pharmacology 20010202

Title: Evaluation of antioxidant activity of epigallocatechin gallate in biphasic model systems in vitro.

Journal: Molecular and cellular biochemistry 20010201

Title: Pre- and postjunctional protective effect of neocuproine on the nitrergic neurotransmitter in the mouse gastric fundus.

Journal: British journal of pharmacology 20010101

Application
Neocuproine emerges as a versatile ligand with diverse applications in synthetic chemistry. Its utility spans various transformations, including the aerobic oxidation of benzyl and allylic alcohols to yield carbonyl compounds catalyzed by Au(I), showcasing its significance in oxidation reactions. Furthermore, Neocuproine serves as a crucial component in the synthesis of the aqua(2,9-dimethyl-1,10-phenanthroline)NiCl2 complex, a precursor utilized in the preparation of uniform spherical NiO nanoparticles via thermal decomposition methods, contributing to the field of nanomaterial synthesis. Additionally, it plays a pivotal role in Zn-catalyzed allylation reactions of aldehydes with allyl boronates, facilitating the formation of α-addition products with high diastereoselectivities, thereby expanding its utility in asymmetric synthesis. With its broad range of applications and versatility as a ligand, Neocuproine stands as a valuable tool for synthetic chemists exploring diverse chemical transformations and nanomaterial synthesis methodologies.
Quotation Request
Company Name:
*
Contact Person:
*
Email:
*
Quantity Required:
*
Country:
Additional Info:
SDS
Tags:484-11-7 Molecular Formula|484-11-7 MDL|484-11-7 SMILES|484-11-7 2,9-dimethyl-1,10-phenanthroline