Home Carboxes 492994-20-4
492994-20-4,MFCD00001989
Catalog No.:AA01X3UC

492994-20-4 | Acetic acid, 2-diazo-, ethyl ester, homopolymer

This product is typically in stock,please click "Inquire" below or
contact us at [email protected] for pricing and availability information.
  • Technical Information
  • Properties
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA01X3UC
Chemical Name:
Acetic acid, 2-diazo-, ethyl ester, homopolymer
CAS Number:
492994-20-4
Molecular Formula:
C4H6N2O2
Molecular Weight:
114.1026
MDL Number:
MFCD00001989
SMILES:
[N-]=[N+]=CC(=O)OCC
NSC Number:
79147
Properties
Computed Properties
 
Complexity:
126  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
8  
Hydrogen Bond Acceptor Count:
3  
Rotatable Bond Count:
3  
Undefined Bond Stereocenter Count:
1  
XLogP3:
0.7  

Literature

Title: BOROX catalysis: self-assembled amino-BOROX and imino-BOROX chiral Brønsted acids in a five component catalyst assembly/catalytic asymmetric aziridination.

Journal: The Journal of organic chemistry 20120921

Title: Chromatographic examination of the chemical composition and sequence distribution of copolymers from ethyl and benzyl diazoacetate.

Journal: Journal of chromatography. A 20120914

Title: Intramolecular cycloaddition of azomethine ylides, from imines of O-acylsalicylic aldehyde and ethyl diazoacetate, to ester carbonyl--experimental and DFT computational study.

Journal: Organic & biomolecular chemistry 20120807

Title: Development of the enantioselective addition of ethyl diazoacetate to aldehydes: asymmetric synthesis of 1,2-diols.

Journal: Journal of the American Chemical Society 20120201

Title: Stable N-heterocyclic carbene (NHC)-palladium(0) complexes as active catalysts for olefin cyclopropanation reactions with ethyl diazoacetate.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20111223

Title: Asymmetric cycloaddition reactions of diazoesters with 2-alkenoic acid derivatives catalyzed by binaphthyldiimine-Ni(II) complexes.

Journal: The Journal of organic chemistry 20110916

Title: Exploring the synthetic versatility of the Lewis acid induced decomposition reaction of α-diazo-β-hydroxy esters. The case of ethyl diazo(3-hydroxy-2-oxo-2,3-dihydro-1H-indol-3-yl)acetate.

Journal: The Journal of organic chemistry 20110916

Title: Silver-catalyzed C-C bond formation between methane and ethyl diazoacetate in supercritical CO₂.

Journal: Science (New York, N.Y.) 20110513

Title: Cobalt-mediated selective B-H activation and formation of a Co-B bond in the reaction of the 16-electron CpCo half-sandwich complex containing an o-carborane-1,2-dithiolate ligand with ethyl diazoacetate.

Journal: Inorganic chemistry 20110502

Title: Highly cis-selective Rh(I)-catalyzed cyclopropanation reactions.

Journal: The Journal of organic chemistry 20110415

Title: Cu(I) complexes containing a multidentate and conformationally flexible dibenzylidene acetone ligand (dbathiophos): application in catalytic alkene cyclopropanation.

Journal: Dalton transactions (Cambridge, England : 2003) 20110414

Title: Bimetallic catalysis involving dipalladium(I) and diruthenium(I) complexes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20101227

Title: Synthesis of β-keto esters in-flow and rapid access to substituted pyrimidines.

Journal: The Journal of organic chemistry 20101217

Title: Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate.

Journal: Chemical communications (Cambridge, England) 20101214

Title: Readily accessible bicyclononynes for bioorthogonal labeling and three-dimensional imaging of living cells.

Journal: Angewandte Chemie (International ed. in English) 20101203

Title: Tin(II) chloride assisted synthesis of N-protected γ-amino β-keto esters through semipinacol rearrangement.

Journal: Organic & biomolecular chemistry 20101107

Title: 'Carbene radicals' in Co(II)(por)-catalyzed olefin cyclopropanation.

Journal: Journal of the American Chemical Society 20100811

Title: Iridium compounds with kappa-P,P,Si (biPSi) pincer ligands: favoring reactive structures in unsaturated complexes.

Journal: Journal of the American Chemical Society 20100707

Title: Computational study of cyclopropanation reactions with halodiazoacetates.

Journal: The Journal of organic chemistry 20100402

Title: Synthesis of Biginelli dihydropyrimidinone derivatives with various substituents on aluminium-planted mesoporous silica catalyst.

Journal: Organic & biomolecular chemistry 20100307

Title: An efficient and convenient synthesis of ethyl 1-(4-methoxyphenyl)-5-phenyl-1H-1,2,3-triazole-4-carboxylate.

Journal: Chemistry, an Asian journal 20100201

Title: Component match in rhodium catalyzed three-component reactions of ethyl diazoacetate, H2O and aryl imines: a highly diastereoselective one-step synthesis of beta-aryl isoserine derivatives.

Journal: Organic & biomolecular chemistry 20091207

Title: Synthesis of [n,5]-spiroketals by ring enlargement of donor-acceptor-substituted cyclopropane derivatives.

Journal: The Journal of organic chemistry 20091120

Title: Efficient method for the synthesis of functionalized pyrazoles by catalyst-free one-pot tandem reaction of nitroalkenes with ethyl diazoacetate.

Journal: Organic & biomolecular chemistry 20091107

Title: Rhodium-catalyzed synthesis of 3-hydroxy-beta-lactams via oxonium ylide generation: three-component reaction between azetidine-2,3-diones, ethyl diazoacetate, and alcohols.

Journal: The Journal of organic chemistry 20091106

Title: Evidence for a boroxinate based Brønsted acid derivative of VAPOL as the active catalyst in the catalytic asymmetric aziridination reaction.

Journal: Journal of the American Chemical Society 20091104

Title: Tandem asymmetric Aza-Darzens/ring-opening reactions: dual functionality from the silane lewis acid.

Journal: Journal of the American Chemical Society 20091021

Title: Organocatalytic aziridine synthesis using F+ salts.

Journal: Organic letters 20091015

Title: Catalytic enantioselective 1,3-dipolar cycloadditions of alkyl diazoacetates with alpha,beta-disubstituted acroleins.

Journal: Chemical communications (Cambridge, England) 20090928

Title: Highly active gold-based catalyst for the reaction of benzaldehyde with ethyl diazoacetate.

Journal: Chemical communications (Cambridge, England) 20090914

Title: Palladium(II) carboxylates and palladium(I) carbonyl carboxylate complexes as catalysts for olefin cyclopropanation with ethyl diazoacetate.

Journal: Dalton transactions (Cambridge, England : 2003) 20090907

Title: Formal aromatic C-H insertion for stereoselective isoquinolinone synthesis and studies on mechanistic insights into the C-C bond formation.

Journal: The Journal of organic chemistry 20090821

Title: Enantioselective aza-Darzens reaction catalyzed by a chiral phosphoric acid.

Journal: Organic letters 20090604

Title: Platinum(II) tetramesityltetraphosphane-1,4-diides.

Journal: Dalton transactions (Cambridge, England : 2003) 20090428

Title: Synthesis, transformations, and comparative studies of porphyryl acrylic acids and their homologues.

Journal: The Journal of organic chemistry 20090220

Title: Magnesium-catalyzed asymmetric direct aldol addition of ethyl diazoacetate to aromatic, aliphatic, and alpha,beta-unsaturated aldehydes.

Journal: Journal of the American Chemical Society 20090211

Title: Highly cis-selective cyclopropanations with ethyl diazoacetate using a novel Rh(I) catalyst with a chelating N-heterocyclic iminocarbene ligand.

Journal: Organic letters 20090205

Title: Unusually reactive and selective carbonyl ylides for three-component cycloaddition reactions.

Journal: Journal of the American Chemical Society 20090128

Title: Reactions of diazo compounds with alkenes catalysed by [RuCl(cod)(Cp)]: effect of the substituents in the formation of cyclopropanation or metathesis products.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20090101

Title: A simple one-pot preparation of diazoacetoacetate derivatives from aldehydes.

Journal: The Journal of organic chemistry 20081107

Title: Highly efficient formation of halodiazoacetates and their use in stereoselective synthesis of halocyclopropanes.

Journal: Organic & biomolecular chemistry 20081021

Title: 1,3-Dipolar cycloadditions of acetylenic sulfones in solution and on solid supports.

Journal: The Journal of organic chemistry 20081017

Title: Synthesis of indoles via domino reaction of N-aryl amides and ethyl diazoacetate.

Journal: Journal of the American Chemical Society 20081015

Title: Synthesis of substituted 6-cyclopropylpurine bases and nucleosides by cross-coupling reactions or cyclopropanations.

Journal: Organic & biomolecular chemistry 20080707

Title: Synthesis of stable derivatives of cycloprop-2-ene carboxylic acid.

Journal: The Journal of organic chemistry 20080606

Title: Gold(I) ethylene and copper(I) ethylene complexes supported by a polyhalogenated triazapentadienyl ligand.

Journal: Inorganic chemistry 20080602

Title: Modularly designed transition metal PNP and PCP pincer complexes based on aminophosphines: synthesis and catalytic applications.

Journal: Accounts of chemical research 20080201

Title: Catalytic asymmetric aziridination with borate catalysts derived from VANOL and VAPOL ligands: scope and mechanistic studies.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

Title: Selective C-C coupling of Ir-ethene and Ir-carbenoid radicals.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

Title: A simple and efficient approach to the synthesis of endo and exo bicyclo[6.1.0]nona-3,5-diene-9-carboxaldehyde.

Journal: Molecules (Basel, Switzerland) 20071030

Title: Ph3As-catalyzed wittig-type olefination of aldehydes with diazoacetate in the presence of Na2S2O4.

Journal: The Journal of organic chemistry 20070817

Title: Palladium-catalyzed cross-coupling of aryl or vinyl iodides with ethyl diazoacetate.

Journal: Journal of the American Chemical Society 20070718

Title: Mo and W dihalide complexes with uncommon trigonal-prismatic geometry imposed by the linear tetraphosphine ancillary ligand and their reactivities toward diazoalkanes.

Journal: Inorganic chemistry 20070611

Title: Direct access to N-H-aziridines from asymmetric catalytic aziridination with borate catalysts derived from vaulted binaphthol and vaulted biphenanthrol ligands.

Journal: Journal of the American Chemical Society 20070606

Title: BH3-catalyzed oligomerization of ethyl diazoacetate: the role of C-boron enolates.

Journal: Journal of the American Chemical Society 20070425

Title: Structure and reaction mechanism of basil eugenol synthase.

Journal: PloS one 20070101

Title: Alkene cyclopropanation catalyzed by Halterman iron porphyrin: participation of organic bases as axial ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20061028

Title: 9-{[3-fluoro-2-(hydroxymethyl)cyclopropylidene]methyl}adenines and -guanines. Synthesis and antiviral activity of all stereoisomers1.

Journal: Journal of medicinal chemistry 20061005

Title: Rhodium-mediated stereoselective polymerization of 'carbenes'.

Journal: Journal of the American Chemical Society 20060802

Title: Trace level detection and quantitation of ethyl diazoacetate by reversed-phase high performance liquid chromatography and UV detection.

Journal: Journal of pharmaceutical and biomedical analysis 20060607

Title: A non-fluorous copper catalyst for the styrene cyclopropanation reaction in a fluorous medium.

Journal: Chemical communications (Cambridge, England) 20060307

Title: Very efficient, reusable copper catalyst for carbene transfer reactions under biphasic conditions using ionic liquids.

Journal: Organic letters 20060216

Title: Unprecedented stereoselective synthesis of catalytically active chiral Mo3CuS4 clusters.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060201

Title: Chiral organometallic triangles with Rh-Rh bonds. 2. Compounds prepared from enantiopure cis-Rh2(C6H4PPh2)2(OAc)2(HOAc)2 and their catalytic potentials.

Journal: Inorganic chemistry 20051114

Title: Catalysis of enantioselective [2+1]-cycloaddition reactions of ethyl diazoacetate and terminal acetylenes using mixed-ligand complexes of the series Rh2(RCO2)n(L*4-n). Stereochemical heuristics for ligand exchange and catalyst synthesis.

Journal: Journal of the American Chemical Society 20051019

Title: Steric and electronic tuning of chiral bis(oxazoline) ligands with 3,3'-bithiophene backbone.

Journal: The Journal of organic chemistry 20050916

Title: A gold catalyst for carbene-transfer reactions from ethyl diazoacetate.

Journal: Angewandte Chemie (International ed. in English) 20050819

Title: Copper-catalyzed addition of ethyl diazoacetate to furans: an alternative to dirhodium(II) tetraacetate.

Journal: The Journal of organic chemistry 20050722

Title: A flexible and versatile strategy for the covalent immobilization of chiral catalysts based on pyridinebis(oxazoline) ligands.

Journal: The Journal of organic chemistry 20050708

Title: Reaction kinetics and critical phenomena: rates of some first order gas evolution reactions in binary solvents with a consolute point.

Journal: The journal of physical chemistry. A 20050602

Title: Novel ozone-mediated cleavage of the benzhydryl protecting group from aziridinyl esters.

Journal: Organic letters 20050526

Title: Mechanism and origin of enantioselectivity in the Rh2(OAc)(DPTI)3-catalyzed cyclopropenation of alkynes.

Journal: Journal of the American Chemical Society 20050504

Title: Surface-catalyzed growth of polymethylene-rich copolymer films on gold.

Journal: Journal of the American Chemical Society 20050309

Title: Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines.

Journal: Chemical communications (Cambridge, England) 20041107

Title: Acid-catalyzed reactions of aromatic aldehydes with ethyl diazoacetate: an investigation on the synthesis of 3-hydroxy-2-arylacrylic acid ethyl esters.

Journal: The Journal of organic chemistry 20041029

Title: Ruthenium porphyrin catalyzed tandem sulfonium/ammonium ylide formation and [2,3]-sigmatropic rearrangement. A concise synthesis of (+/-)-platynecine.

Journal: The Journal of organic chemistry 20041015

Title: Complete control of the chemoselectivity in catalytic carbene transfer reactions from ethyl diazoacetate: an N-heterocyclic carbene-Cu system that suppresses diazo coupling.

Journal: Journal of the American Chemical Society 20040908

Title: Group 11 metal complexes of SPS-based pincer ligands: syntheses, X-ray structures and reactivity.

Journal: Dalton transactions (Cambridge, England : 2003) 20040821

Title: A new chiral Rh(II) catalyst for enantioselective [2 + 1]-cycloaddition. mechanistic implications and applications.

Journal: Journal of the American Chemical Society 20040728

Title: Automated structure elucidation of two unexpected products in a reaction of an alpha,beta-unsaturated pyruvate.

Journal: Magnetic resonance in chemistry : MRC 20040701

Title: The role of binding constants in the efficiency of chiral catalysts immobilized by electrostatic interactions: the case of azabis(oxazoline)-copper complexes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20040621

Title: Vitamin B12 derivatives as natural asymmetric catalysts: enantioselective cyclopropanation of alkenes.

Journal: The Journal of organic chemistry 20040402

Title: Nitrosation of glycine ethyl ester and ethyl diazoacetate to give the alkylating agent and mutagen ethyl chloro(hydroximino)acetate.

Journal: Chemical research in toxicology 20040301

Title: Synthesis and antiviral activity of monofluorinated cyclopropanoid nucleosides.

Journal: Organic & biomolecular chemistry 20040121

Title: Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations.

Journal: Journal of the American Chemical Society 20031224

Title: Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature.

Journal: The Journal of organic chemistry 20031212

Title: Diastereoselective and enantioselective cyclopropanation of alkenes catalyzed by cobalt porphyrins.

Journal: The Journal of organic chemistry 20031017

Title: Electronically tuned chiral ruthenium porphyrins: extremely stable and selective catalysts for asymmetric epoxidation and cyclopropanation.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20031006

Title: Activation of alkyl halides via a silver-catalyzed carbene insertion process.

Journal: Journal of the American Chemical Society 20030806

Title: Acid-promoted olefination of ketones by an iron(III) porphyrin complex.

Journal: Organic letters 20030710

Title: Synthesis, molecular structure, and C-C coupling reactions of carbeneruthenium(II) complexes with C5H5Ru(=CRR') and C5Me5Ru(=CRR') as molecular units.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20030606

Title: Generation of phosphoranes derived from phosphites. A new class of phosphorus ylides leading to high E selectivity with semi-stabilizing groups in Wittig olefinations.

Journal: Journal of the American Chemical Society 20030521

Title: Copper(II)-catalyzed [2,3]-sigmatropic rearrangement of N-methyltetrahydropyridinium ylids.

Journal: The Journal of organic chemistry 20030516

Title: Iron(III) and ruthenium(II) porphyrin complex-catalyzed selective olefination of aldehydes with ethyl diazoacetate.

Journal: The Journal of organic chemistry 20030502

Title: Direct catalytic asymmetric aldol-type reaction of aldehydes with ethyl diazoacetate.

Journal: Organic letters 20030501

Title: Highly regioselective functionalization of aliphatic carbon-hydrogen bonds with a perbromohomoscorpionate copper(I) catalyst.

Journal: Journal of the American Chemical Society 20030212

Title: Transition metal-catalyzed cyclopropanation of alkenes in water: catalyst efficiency and in situ generation of the diazo reagent.

Journal: Organic letters 20021212

Title: Remarkably stable iron porphyrins bearing nonheteroatom-stabilized carbene or (alkoxycarbonyl)carbenes: isolation, X-ray crystal structures, and carbon atom transfer reactions with hydrocarbons.

Journal: Journal of the American Chemical Society 20021106

Title: The first immobilization of pyridine-bis(oxazoline) chiral ligands.

Journal: Organic letters 20021031

Title: Improvement of ligand economy controlled by polymer morphology: the case of polymer-supported bis(oxazoline) catalysts.

Journal: Bioorganic & medicinal chemistry letters 20020722

Title: The [2 + 1] and [4 + 3] cyclization reactions of fulvenes with Fischer carbene complexes: new access to annulated cyclopentanones.

Journal: Journal of the American Chemical Society 20020529

Title: Dendritic ruthenium porphyrins: a new class of highly selective catalysts for alkene epoxidation and cyclopropanation.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20020402

Title: The first enantiomerically pure [n]triangulanes and analogues: sigma-[n]helicenes with remarkable features.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20020215

Title: Copper(I)-homoscorpionate catalysts for the preferential, kinetically controlled cis cyclopropanation of alpha-olefins with ethyl diazoacetate.

Journal: Journal of the American Chemical Society 20020213

Title: A new and efficient method for the selective olefination of aldehydes with ethyl diazoacetate catalyzed by an iron(II) porphyrin complex.

Journal: Journal of the American Chemical Society 20020116

Title: Asymmetric cyclopropanation catalyzed by a series of copper-(Schiff-base) complexes with two chiral centers.

Journal: Enantiomer 20020101

Title: Bis(oxazoline)copper complexes covalently bonded to insoluble support as catalysts in cyclopropanation reactions.

Journal: The Journal of organic chemistry 20011228

Title: Reactivity of 2-methylene-1,3-dicarbonyl compounds. 1,3-dipolar cycloaddition reaction with ethyl diazoacetate.

Journal: Chemical & pharmaceutical bulletin 20011201

Title: Catalytic asymmetric cyclopropanation of heteroaryldiazoacetates.

Journal: The Journal of organic chemistry 20011005

Title: A family of highly active copper(I)-homoscorpionate catalysts for the alkyne cyclopropenation reaction.

Journal: Chemical communications (Cambridge, England) 20010921

Title: 1,2-aryl and 1,2-hydride migration in transition metal complex catalyzed diazo decomposition: a novel approach to alpha-aryl-beta-enamino esters.

Journal: Organic letters 20010920

Title: Bidentate carbenoid ester coordination in ruthenium(II) Schiff-base complexes leading to excellent levels of diastereo- and enantioselectivity in catalytic alkene cyclopropanation.

Journal: Chemical communications (Cambridge, England) 20010907

Title: Asymmetric inter- and intramolecular cyclopropanation of alkenes catalyzed by chiral ruthenium porphyrins. Synthesis and crystal structure of a chiral metalloporphyrin carbene complex.

Journal: Journal of the American Chemical Society 20010509

Quotation Request
Company Name:
*
Contact Person:
*
Email:
*
Quantity Required:
*
Country:
Additional Info:
SDS
Related Products of 492994-20-4
Tags:492994-20-4 Molecular Formula|492994-20-4 MDL|492994-20-4 SMILES|492994-20-4 Acetic acid, 2-diazo-, ethyl ester, homopolymer