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512-56-1,MFCD00008348
Catalog No.:AA003V0M

512-56-1 | Trimethyl phosphate

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25g
99.5%
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$13.00   $9.00
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500g
99.5%
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  • Technical Information
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA003V0M
Chemical Name:
Trimethyl phosphate
CAS Number:
512-56-1
Molecular Formula:
C3H9O4P
Molecular Weight:
140.0749
MDL Number:
MFCD00008348
SMILES:
COP(=O)(OC)OC
NSC Number:
58985
Properties
Properties
 
BP:
197°C at 760 mmHg  
Form:
Liquid  
MP:
-46 °C  
Refractive Index:
n20/D 1.395(lit.)  
Solubility:
1000g/l  
Stability:
Moisture Sensitive  
Storage:
Room Temperature;Keep in dry area;  

Computed Properties
 
Complexity:
82.4  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
8  
Hydrogen Bond Acceptor Count:
4  
Rotatable Bond Count:
3  
XLogP3:
-0.5  

Literature

Title: Affinities of organophosphate flame retardants to tumor suppressor gene p53: an integrated in vitro and in silico study.

Journal: Toxicology letters 20150122

Title: A method for simultaneous quantification of phospholipid species by routine 31P NMR.

Journal: Journal of pharmaceutical and biomedical analysis 20121101

Title: Oxidation of phosphorus centers by ferrate(VI): spectral observation of an intermediate.

Journal: Inorganic chemistry 20120618

Title: The synthesis of 2'-methylseleno adenosine and guanosine 5'-triphosphates.

Journal: Bioorganic & medicinal chemistry 20120401

Title: Development of an ultra-high-performance liquid chromatography-tandem mass spectrometry method for high throughput determination of organophosphorus flame retardants in environmental water.

Journal: Journal of chromatography. A 20110923

Title: Brominated and organophosphate flame retardants in selected consumer products on the Japanese market in 2008.

Journal: Journal of hazardous materials 20110915

Title: Conformations of trimethyl phosphite: a matrix isolation infrared and ab initio study.

Journal: The journal of physical chemistry. A 20110908

Title: Adsorption of trimethyl phosphate on maghemite, hematite, and goethite nanoparticles.

Journal: The journal of physical chemistry. A 20110818

Title: Adsorption of organophosphates into microporous and mesoporous NaX zeolites and subsequent chemistry.

Journal: Environmental science & technology 20110401

Title: Catechin suppresses an array of signalling molecules and modulates alcohol-induced endotoxin mediated liver injury in a rat model.

Journal: PloS one 20110101

Title: Gas-phase synchrotron FTIR spectroscopy of weakly volatile alkyl phosphonate and alkyl phosphate compounds: vibrational and conformational analysis in the terahertz/far-IR spectral domain.

Journal: The journal of physical chemistry. B 20101223

Title: Mechanistic and computational study of a palladacycle-catalyzed decomposition of a series of neutral phosphorothioate triesters in methanol.

Journal: Journal of the American Chemical Society 20101124

Title: 3-Methyl-quinoxaline-2-carb-oxy-lic acid 4-oxide monohydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20100701

Title: Facile small scale synthesis of nucleoside 5'-phosphate mixtures.

Journal: Nucleosides, nucleotides & nucleic acids 20100101

Title: The diatomic dication PO2+.

Journal: Physical chemistry chemical physics : PCCP 20090807

Title: Kinetics and mechanism for degradation of dichlorvos by permanganate in drinking water treatment.

Journal: Water research 20090801

Title: Rapid estimation of trace organophosphonate used as a scale inhibitor in aqueous systems by reactive pyrolysis-gas chromatography/mass spectrometry.

Journal: Journal of chromatography. A 20090703

Title: Gas-phase vibrational spectroscopy and ab initio study of organophosphorus compounds: discrimination between species and conformers.

Journal: The journal of physical chemistry. B 20081002

Title: Phosphorescent organic light-emitting devices: working principle and iridium based emitter materials.

Journal: International journal of molecular sciences 20080801

Title: Hydroxyapatite coating on Ti6Al4V alloy by a sol-gel method.

Journal: Journal of materials science. Materials in medicine 20080601

Title: A tetra-substituted chrysene: orientation of multiple electrophilic substitution and use of a tetra-substituted chrysene as a blue emitter for OLEDs.

Journal: Chemical communications (Cambridge, England) 20080528

Title: Are there pi* shape resonances in electron scattering from phosphate groups?

Journal: The journal of physical chemistry. A 20080501

Title: A simple model for metal cation-phosphate interactions in nucleic acids in the gas phase: alkali metal cations and trimethyl phosphate.

Journal: Journal of the American Society for Mass Spectrometry 20080201

Title: Mechanism of SN2 disulfide bond cleavage by phosphorus nucleophiles. Implications for biochemical disulfide reducing agents.

Journal: The Journal of organic chemistry 20071026

Title: Synthesis and biological evaluation of phosphate prodrugs of 4-phospho-D-erythronohydroxamic acid, an inhibitor of 6-phosphogluconate dehydrogenase.

Journal: ChemMedChem 20070813

Title: Liquid chromatography/tandem mass spectrometry determination of organophosphorus flame retardants and plasticizers in drinking and surface waters.

Journal: Rapid communications in mass spectrometry : RCM 20070101

Title: Mononuclear Schiff base boron halides: synthesis, characterization, and dealkylation of trimethyl phosphate.

Journal: Inorganic chemistry 20061113

Title: Air sampling with Empore solid phase extraction membranes and online single-channel desorption/liquid chromatography/mass spectrometry analysis: determination of volatile and semi-volatile organophosphate esters.

Journal: Journal of chromatography. A 20060929

Title: Total dissociative electron attachment cross sections for molecular constituents of DNA.

Journal: The Journal of chemical physics 20060807

Title: Synthesis, structural characterization and the first electroluminescent properties of tris- and bis-cycloiridiated complexes of sterically hindered electron-poor 2-(3,5-bis(trifluoromethyl)phenyl)-4-trifluoromethylpyridine.

Journal: Dalton transactions (Cambridge, England : 2003) 20060528

Title: Five-coordinate aluminum bromides: synthesis, structure, cation formation, and cleavage of phosphate ester bonds.

Journal: Journal of the American Chemical Society 20060201

Title: J-coupling nuclear magnetic resonance spectroscopy of liquids in nT fields.

Journal: Journal of the American Chemical Society 20060125

Title: Theoretical studies of the hydroxide-catalyzed P-O cleavage reactions of neutral phosphate triesters and diesters in aqueous solution: examination of the changes induced by H/Me substitution.

Journal: The journal of physical chemistry. B 20051201

Title: Tris(thioimidazolyl)borate-zinc-thiolate complexes for the modeling of biological thiolate alkylations.

Journal: Inorganic chemistry 20051114

Title: Does phosphoryl protonation occurs in aqueous phosphoesters solutions.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20051101

Title: Expression of mucin genes in the human testis and its relationship to spermatogenesis.

Journal: Yonsei medical journal 20051031

Title: The structure of an enzyme-product complex reveals the critical role of a terminal hydroxide nucleophile in the bacterial phosphotriesterase mechanism.

Journal: Biochimica et biophysica acta 20050831

Title: Thiolysis and alcoholysis of phosphate tri- and monoesters with alkyl and aryl leaving groups. An ab initio study in the gas phase.

Journal: The journal of physical chemistry. A 20050630

Title: Effect of the TBP and water on the complexation of uranyl nitrate and the dissolution of nitric acid into supercritical CO2. A Theoretical Study.

Journal: The journal of physical chemistry. A 20050616

Title: Zinc-thiolate complexes of the bis(pyrazolyl)(thioimidazolyl)hydroborate tripods for the modeling of thiolate alkylating enzymes.

Journal: Inorganic chemistry 20050516

Title: Gas-phase reactivity of the O=P(OCH3)2 + phosphonium ion towards alpha,beta-unsaturated esters in a quadrupole ion trap.

Journal: Journal of mass spectrometry : JMS 20050401

Title: Uranyl extraction by beta-diketonate ligands to SC-CO2: theoretical studies on the effect of ligand fluorination and on the synergistic effect of TBP.

Journal: The journal of physical chemistry. B 20050113

Title: Preparation of (cyanomethylene)trimethylphosphorane as a new Mitsunobu-type reagent.

Journal: Chemical & pharmaceutical bulletin 20030401

Title: Trimethyl phosphite as a trap for alkoxy radicals formed from the ring opening of oxiranylcarbinyl radicals. Conversion to alkenes. Mechanistic applications to the study of C-C versus C-O ring cleavage.

Journal: Journal of the American Chemical Society 20030319

Title: Zinc mediated methyl transfer from trimethyl phosphate to chelating and non-chelating alkyl thiols. Model for Zn-dependent methyltransferases.

Journal: Journal of inorganic biochemistry 20030201

Title: Gas chromatography-mass spectrometry assay of the (18)o enrichment of water as trimethyl phosphate.

Journal: Analytical biochemistry 20020715

Title: Chemistry. Whisper of magnetism tells molecules apart.

Journal: Science (New York, N.Y.) 20020322

Title: Overview of studies on rat sperm motion analysis using a Hamilton-Thorne Sperm Analyzer--collaborative working study.

Journal: The Journal of toxicological sciences 20011201

Title: Functional modeling of cobalamine-independent methionine synthase with pyrazolylborate-zinc-thiolate complexes.

Journal: Inorganic chemistry 20011119

Title: Synthesis of (S)-isoprenoid thiodiphosphates as substrates and inhibitors.

Journal: The Journal of organic chemistry 20011005

Title: Methylation of neutral pseudotetrahedral zinc thiolate complexes: model reactions for alkyl group transfer to sulfur by zinc-containing enzymes.

Journal: Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20010101

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