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595-46-0,MFCD00004193
Catalog No.:AA0034OS

595-46-0 | Dimethylmalonic acid

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1g
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5g
98%
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10g
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25g
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100g
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  • Technical Information
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  • Technical Information
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Technical Information
Catalog Number:
AA0034OS
Chemical Name:
Dimethylmalonic acid
CAS Number:
595-46-0
Molecular Formula:
C5H8O4
Molecular Weight:
132.1146
MDL Number:
MFCD00004193
SMILES:
OC(=O)C(C(=O)O)(C)C
NSC Number:
836
Properties
Properties
 
BP:
310.199 °C at 760 mmHg  
Form:
Solid  
MP:
191-193 °C(lit.);  
Refractive Index:
1.4016 (estimate)  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
131  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
9  
Hydrogen Bond Acceptor Count:
4  
Hydrogen Bond Donor Count:
2  
Rotatable Bond Count:
2  
XLogP3:
0.4  

Literature

Title: Synthesis of PCP-supported nickel complexes and their reactivity with carbon dioxide.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120529

Title: Chiral ionic liquid/ESI-MS methodology as an efficient tool for the study of transformations of supported organocatalysts: deactivation pathways of Jørgensen-Hayashi-type catalysts in asymmetric Michael reactions.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20110523

Title: Poly[[aqua-μ(3)-2,2-dimethylmalonato-copper(II)] monohydrate] and poly[aqua-μ(3)-2,2-dimethylmalonato-copper(II)].

Journal: Acta crystallographica. Section C, Crystal structure communications 20101201

Title: Poly[diaquabis(mu3-2,2-dimethylpropanedioato)calcium(II)copper(II)].

Journal: Acta crystallographica. Section C, Crystal structure communications 20100701

Title: Poly[[diaqua(mu3-2,2-dimethylmalonato)cadmium(II)] tetrahydrate].

Journal: Acta crystallographica. Section C, Crystal structure communications 20090701

Title: Poly[[aqua(micro-2,2-dimethylmalonato)barium(II)] 2,2-dimethylmalonic acid solvate].

Journal: Acta crystallographica. Section C, Crystal structure communications 20081201

Title: catena-Poly[[[(dimethyl-malonato-κO:O')(perchlorato-κO)copper(II)]-μ-bis-(3-pyridylmeth-yl)piperazinediium-κN:N] perchlorate dihydrate].

Journal: Acta crystallographica. Section E, Structure reports online 20081201

Title: Bis(dimethyl-malonato-κO,O')bis-[4-(4-pyridylamino-κN)pyridinium]nickel(II) hexa-hydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20081201

Title: Origin of enantioselectivity in palladium-catalyzed asymmetric allylic alkylation reactions using chiral N,N-ligands with different rigidity and flexibility.

Journal: Dalton transactions (Cambridge, England : 2003) 20070421

Title: Replacement of chlorides with dicarboxylate ligands in anticancer active Ru(II)-DMSO compounds: a new strategy that might lead to improved activity.

Journal: Inorganic chemistry 20070205

Title: Electronic differentiation competes with transition state sensitivity in palladium-catalyzed allylic substitutions.

Journal: Beilstein journal of organic chemistry 20070101

Title: A superior P-H phosphonite: asymmetric allylic substitutions with fenchol-based palladium catalysts.

Journal: Beilstein journal of organic chemistry 20060101

Title: Catalysis with phosphine-containing amino acids in various 'turn' motifs.

Journal: The Journal of organic chemistry 20041112

Title: Biosynthesis of cervimycin C, an aromatic polyketide antibiotic bearing an unusual dimethylmalonyl moiety.

Journal: Organic & biomolecular chemistry 20040907

Title: Synthesis of orthogonally protected (R)- and (S)-2-methylcysteine via an enzymatic desymmeterization and Curtius rearrangement.

Journal: The Journal of organic chemistry 20030627

Title: Dimethylmalonyltrialkylphosphoranes: new general reagents for esterification reactions allowing controlled inversion or retention of configuration on chiral alcohols.

Journal: The Journal of organic chemistry 20030221

Title: Electron spin-lattice relaxation in radicals containing two methyl groups, generated by gamma-irradiation of polycrystalline solids.

Journal: Journal of magnetic resonance (San Diego, Calif. : 1997) 20021201

Title: Proline-based P, N ligands in asymmetric allylation and the Heck reaction.

Journal: The Journal of organic chemistry 20011102

Title: David A. Evans, et al. An Improved Procedure for the Preparation of 2,2-Bis-(S)- tert-butyl-1,3-oxazolinylpropane [(S,S)-tert-Butylbis(oxazoline) and Derived Copper(II) Complexes. J. Org. Chem. 1998, 63, 13, 4541-4544.

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