Home Other Building Blocks 637-50-3
637-50-3,MFCD00009280
Catalog No.:AA003S1J

637-50-3 | Beta-methylstyrene

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Purity
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1g
95% (stabilized with TBC)
in stock  
$23.00   $16.00
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5g
95% (stabilized with TBC)
in stock  
$72.00   $50.00
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25g
95% (stabilized with TBC)
in stock  
$304.00   $213.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003S1J
Chemical Name:
Beta-methylstyrene
CAS Number:
637-50-3
Molecular Formula:
C9H10
Molecular Weight:
118.1757
MDL Number:
MFCD00009280
SMILES:
CC=CC1=CC=CC=C1
UN Number:
2618
Properties
Properties
 
BP:
167.5°C at 760 mmHg  
Form:
Liquid  
MP:
-27.1°C  
Refractive Index:
n20/D 1.550(lit.)  
Storage:
Keep in dry area;2-8℃;  

Computed Properties
 
Complexity:
86.2  
Covalently-Bonded Unit Count:
1  
Defined Bond Stereocenter Count:
1  
Heavy Atom Count:
9  
Rotatable Bond Count:
1  
XLogP3:
3.2  

Downstream Synthesis Route

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[2]Gu,Yanlong;Karam,Ayman;Jerome,Francois;Barrault,Joel[OrganicLetters,2007,vol.9,#16,p.3145-3148]

[3]Bach,Thorsten;Loebel,Johannes[Synthesis,2002,#17,p.2521-2526]

[4]Kalkhambkar,RajeshG.;Jeong,YeonT.[SyntheticCommunications,2014,vol.44,#6,p.762-771]

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[1]JournaloftheAmericanChemicalSociety,1946,vol.68,p.2029,2032,2755

[1]Nair,Vijay;Panicker,SreelethaB;Augustine,Anu;George,TesmolG;Thomas,Siji;Vairamani[Tetrahedron,2001,vol.57,#34,p.7417-7422]

[2]Kulangiappar;Ramaprakash;Vasudevan;Raju[SyntheticCommunications,2016,vol.46,#2,p.145-153]

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[5]Radziszewski[ComptesRendusHebdomadairesdesSeancesdel'AcademiedesSciences,1874,vol.78,p.1154][JahresberichtueberdieFortschrittederChemieundVerwandterTheileAndererWissenschaften,1874,p.393]Ruegheimer[JustusLiebigsAnnalenderChemie,1874,vol.172,p.131]Perkin[JournaloftheChemicalSociety,1877,vol.32,p.667][JournaloftheChemicalSociety,1879,vol.35,p.140Anm.]

[6]Huston;Sager[JournaloftheAmericanChemicalSociety,1926,vol.48,p.1957]Ramart;Amagat[AnnalesdeChimie(Cachan,France),1927,vol.<10>8,p.295][ComptesRendusHebdomadairesdesSeancesdel'AcademiedesSciences,1926,vol.182,p.1343]Lagerew;Schamschurin[ZhurnalObshcheiKhimii,1939,vol.9,p.199,202][ChemischesZentralblatt,1939,vol.110,#II,p.1054]

[7]Spaeth;Koller[ChemischeBerichte,1925,vol.58,p.1269]

[8]Lardelli;Jeger[HelveticaChimicaActa,1949,vol.32,p.1817,1832]

[1]Fourneau;Kanao[BulletindelaSocieteChimiquedeFrance,1924,vol.<4>35,p.620]Fourneau;Puyal[AnalesdelaRealSociedadEspanoladeFisicayQuimica,vol.20,p.398][ChemischesZentralblatt,1924,vol.95,#I,p.1364]

[2]Wang,Zhihui;Li,Meiyi;Zhang,Wenqin;Jia,Jiangnan;Wang,Fei;Xue,Song[TetrahedronLetters,2011,vol.52,#45,p.5968-5971]

[3]Kim,Yongjin;Pak,HanKyu;Rhee,YoungHo;Park,Jaiwook[ChemicalCommunications,2016,vol.52,#39,p.6549-6552]

[4]Iakovenko,Roman;Hlaváč,Jan[GreenChemistry,2021,vol.23,#1,p.440-446]

[1]Liu,Changhui;Pan,Bin;Gu,Yanlong[CuihuaXuebao/ChineseJournalofCatalysis,2016,vol.37,#6,p.979-986]

[2]Albrecht,Martin;Olivares,Marta[JournalofOrganometallicChemistry,2020,vol.920]

[3]Wagner[ZhurnalRusskagoFiziko-KhimicheskagoObshchestva,1884,vol.16,p.324][ChemischeBerichte,17Ref.<1884>,317]

[4]Wagner[ZhurnalRusskagoFiziko-KhimicheskagoObshchestva,1884,vol.16,p.324][ChemischeBerichte,17Ref.<1884>,317]

[5]Klages[ChemischeBerichte,1902,vol.35,p.2263][ChemischeBerichte,1905,vol.38,p.913]

[6]Klages[ChemischeBerichte,1903,vol.36,p.621]

[7]Hell;Bauer[ChemischeBerichte,1903,vol.36,p.207]

[8]Spaeth;Koller[ChemischeBerichte,1925,vol.58,p.1269]

[9]Klages[ChemischeBerichte,1903,vol.36,p.621]Zincke;Zahn[ChemischeBerichte,1910,vol.43,p.855]

[10]Zhu,Zuolin;Espenson,JamesH.[JournalofOrganicChemistry,1996,vol.61,#1,p.324-328]

[11]BagheriMarandi;Pourjavadi;Hosseinzadeh[OrientalJournalofChemistry,2012,vol.28,#3,p.1141-1145]

[12]CurrentPatentAssignee:SINOVATION-CN106478709,2017,ALocationinpatent:Paragraph0108;0109

Literature

Title: Monomer- and polymer radicals of vinyl compounds: EPR and DFT studies of geometric and electronic structures in the adsorbed state.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20121201

Title: Tandem allylic oxidation-condensation/esterification catalyzed by silica gel: an expeditious approach towards antimalarial diaryldienones and enones from natural methoxylated phenylpropenes.

Journal: Organic & biomolecular chemistry 20110721

Title: Enantiospecificity of chloroperoxidase-catalyzed epoxidation: biased molecular dynamics study of a cis-β-methylstyrene/chloroperoxidase-compound I complex.

Journal: Biophysical journal 20110216

Title: Phenylpropanoid biosynthesis in leaves and glandular trichomes of basil (Ocimum basilicum L.).

Journal: Methods in molecular biology (Clifton, N.J.) 20100101

Title: mer-Bis[3,5-difluoro-2-(2-pyrid-yl)phenyl-κC,N]{5-(2-pyridyl-κN)-3-[3-(4-vinyl-benz-yloxy)phen-yl]-1,2,4-triazol-1-ido}iridium(III) methanol solvate.

Journal: Acta crystallographica. Section E, Structure reports online 20100101

Title: Identification of multiple constituents in the traditional Chinese medicine formula GuiZhiFuLing-Wan by HPLC-DAD-MS/MS.

Journal: Journal of pharmaceutical and biomedical analysis 20090220

Title: Polyelectrolyte Complexes: A Review of their Applicability in Drug Delivery Technology.

Journal: Indian journal of pharmaceutical sciences 20090101

Title: Trace evidence of trans-phenylpropene as a marker of smoked methamphetamine.

Journal: Journal of analytical toxicology 20081001

Title: [Structure-activity relationship of phenylallyl compounds inhibiting PGE2 release in mouse cerebral microvascular endothelial cells induced by IL-1beta].

Journal: Yao xue xue bao = Acta pharmaceutica Sinica 20070701

Title: Validation of a headspace GC method for the analysis of a pyrolytic product of methamphetamine in urine.

Journal: Journal of analytical toxicology 20061001

Title: Epoxidation of the methamphetamine pyrolysis product, trans-phenylpropene, to trans-phenylpropylene oxide by CYP enzymes and stereoselective glutathione adduct formation.

Journal: Toxicology and applied pharmacology 20060301

Title: Potential marker for smoked methamphetamine hydrochloride based on a gas chromatography-mass spectrometry quantification method for trans-phenylpropene.

Journal: Journal of analytical toxicology 20050901

Title: Synthetic cinchonidine receptors obtained by cross-linking linear poly(methacrylic acid) derivatives as an alternative molecular imprinting technique.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20040505

Title: Optimized chemical structure of nanoparticles as carriers for oral delivery of salmon calcitonin.

Journal: International journal of pharmaceutics 20020604

Title: Bis(oxazoline)copper complexes covalently bonded to insoluble support as catalysts in cyclopropanation reactions.

Journal: The Journal of organic chemistry 20011228

Title: Combination effects of antifungal nagilactones against Candida albicans and two other fungi with phenylpropanoids.

Journal: Journal of natural products 19930201

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