Home Other Building Blocks 6737-42-4
6737-42-4,MFCD00003050
Catalog No.:AA0032II

6737-42-4 | 1,3-Bis(diphenylphosphino)propane

Pack Size
Purity
Availability
Price(USD)
Quantity
  
5g
97%
in stock  
$6.00   $4.00
- +
10g
97%
in stock  
$7.00   $5.00
- +
25g
97%
in stock  
$16.00   $11.00
- +
100g
97%
in stock  
$62.00   $43.00
- +
500g
97%
in stock  
$165.00   $116.00
- +
  • Technical Information
  • Properties
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0032II
Chemical Name:
1,3-Bis(diphenylphosphino)propane
CAS Number:
6737-42-4
Molecular Formula:
C27H26P2
Molecular Weight:
412.4429
MDL Number:
MFCD00003050
SMILES:
C(CP(c1ccccc1)c1ccccc1)CP(c1ccccc1)c1ccccc1
NSC Number:
193753
Properties
Properties
 
BP:
529.667 °C at 760 mmHg  
Form:
Solid  
MP:
63-65 °C(lit.)  
Stability:
Air Sensitive  
Storage:
Room Temperature;  

Computed Properties
 
Complexity:
350  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
29  
Rotatable Bond Count:
8  
XLogP3:
6.2  

Literature

Title: Bis[1,3-bis-(diphenyl-phosphan-yl)propane]-copper(I) tetra-chlorido-gallate(III).

Journal: Acta crystallographica. Section E, Structure reports online 20120701

Title: Charge retention by gold clusters on surfaces prepared using soft landing of mass selected ions.

Journal: ACS nano 20120124

Title: A selective intramolecular 5-exo-dig or 6-endo-dig cyclization en route to 2-furanone or 2-pyrone containing tricyclic scaffolds.

Journal: The Journal of organic chemistry 20111202

Title: [1,3-Bis(diphenyl-phosphan-yl)propane-κP,P'](1,10-phenanthroline-κN,N')copper(I) perchlorate.

Journal: Acta crystallographica. Section E, Structure reports online 20111201

Title: Synthesis of functionalized cinnamaldehyde derivatives by an oxidative Heck reaction and their use as starting materials for preparation of Mycobacterium tuberculosis 1-deoxy-D-xylulose-5-phosphate reductoisomerase inhibitors.

Journal: The Journal of organic chemistry 20111104

Title: Poly[bis-[μ-1,3-bis-(diphenyl-phosphan-yl)propane-κP:P']-di-μ-thio-cyanato-κS:N;κN:S-disilver(I)].

Journal: Acta crystallographica. Section E, Structure reports online 20111101

Title: Reaction mechanism governing formation of 1,3-bis(diphenylphosphino)propane-protected gold nanoclusters.

Journal: Inorganic chemistry 20111017

Title: Preparation of η2-complexes of fullerenes by reduction. Crystal structure and optical properties of {Ni(dppp)·(η2-C70)}·(C6H4Cl2)0.5.

Journal: Dalton transactions (Cambridge, England : 2003) 20110928

Title: catena-Poly[[[μ-1,3-bis(diphenylphosphanyl)propane-κ2P:P'][O-ethyl (4-methoxyphenyl)phosphonodithioato-κ2S,S']silver(I)] chloroform monosolvate].

Journal: Acta crystallographica. Section C, Crystal structure communications 20110901

Title: Multimetallic complexes of group 10 and 11 metals based on polydentate dithiocarbamate ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20110614

Title: Nickel-catalyzed cross-coupling of phenols and arylboronic acids through an in situ phenol activation mediated by PyBroP.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20110328

Title: Reactions of a gold(I) thiolate complex [Au(Tab)(2)](2)(PF(6))(2) (Tab = 4-(trimethylammonio)benzenethiolate) with diphosphine ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20110121

Title: Diversity-oriented synthesis based on the DPPP-catalyzed mixed double-Michael reactions of electron-deficient acetylenes and β-amino alcohols.

Journal: Molecules (Basel, Switzerland) 20110101

Title: Synthesis and spectrosopic identification of hybrid 3-(triethoxysilyl)propylamine phosphine ruthenium(II) complexes.

Journal: Molecules (Basel, Switzerland) 20100517

Title: Efficient synthesis of alkyl aryl ketones & ketals via palladium-catalyzed regioselective arylation of vinyl ethers.

Journal: Organic & biomolecular chemistry 20100507

Title: Synthesis, characterization and cytotoxic activities of the [RuCl2(NO)(dppp)(L)]PF6 complexes.

Journal: Journal of inorganic biochemistry 20100501

Title: Diphosphine-catalyzed mixed double-Michael reaction: a unified synthesis of indolines, dihydropyrrolopyridines, benzimidazolines, tetrahydroquinolines, tetrahydroisoquinolines, dihydrobenzo-1,4-oxazines, and dihydrobenzo-3,1-oxazines.

Journal: Organic letters 20100305

Title: Tertiary carbinamine synthesis by rhodium-catalyzed [3+2] annulation of N-unsubstituted aromatic ketimines and alkynes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20100222

Title: Sterically-directed consecutive and size-selective self-assembly of palladium diphosphane complexes with an Ar-BIAN ligand: unexpected formation of pentameric and hexameric aggregates.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20091012

Title: Externally initiated regioregular P3HT with controlled molecular weight and narrow polydispersity.

Journal: Journal of the American Chemical Society 20090916

Title: Aromatic C-F activation by complexes containing the {Pt2S2} core via nucleophilic substitution: a combined experimental and theoretical study.

Journal: Dalton transactions (Cambridge, England : 2003) 20090814

Title: Regioselective Heck vinylation of electron-rich olefins with vinyl halides: is the neutral pathway in operation?

Journal: The Journal of organic chemistry 20090403

Title: Iron-catalysed Negishi coupling of benzyl halides and phosphates.

Journal: Chemical communications (Cambridge, England) 20090207

Title: Mechanistic insights into the rhodium-catalyzed intramolecular ketone hydroacylation.

Journal: Journal of the American Chemical Society 20090128

Title: Characterization of self-assembled metallodendrimers in solution, in the gas phase, and at air/solid interfaces.

Journal: Small (Weinheim an der Bergstrasse, Germany) 20081001

Title: [1,3-Bis(diphenyl-phosphino)propane-κP,P']diiodido(perfluoro-propyl)rhodium(III) dichloro-methane solvate.

Journal: Acta crystallographica. Section E, Structure reports online 20081001

Title: Metallo-supramolecular self-assembly: the case of triangle-square equilibria.

Journal: Inorganic chemistry 20080901

Title: Bis[1,3-bis-(diphenyl-phosphino)propane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)triphenyl-stannate(IV).

Journal: Acta crystallographica. Section E, Structure reports online 20080501

Title: Reaction chemistry of complexes containing Pt--H, Pt--SH, or Pt--S fragments: from their apparent simplicity to the maze of reactions underlying their interconversion.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

Title: Development of potential manufacturing routes for substituted thiophenes--preparation of halogenated 2-thiophenecarboxylic acid derivatives as building blocks for a new family of 2,6-dihaloaryl 1,2,4-triazole insecticides.

Journal: Beilstein journal of organic chemistry 20070101

Title: Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid.

Journal: Chemical communications (Cambridge, England) 20060914

Title: Rhodium(I)-catalyzed carboxylation of aryl- and alkenylboronic esters with CO2.

Journal: Journal of the American Chemical Society 20060712

Title: Structural variations and spectroscopic properties of luminescent mono- and multinuclear silver(I) and copper(I) complexes bearing phosphine and cyanide ligands.

Journal: Inorganic chemistry 20050307

Title: Cobalt-catalyzed cross-coupling reactions of alkyl halides with allylic and benzylic Grignard reagents and their application to tandem radical cyclization/cross-coupling reactions.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20041105

Title: Self-assembly of flexible supramolecular metallacyclic ensembles: structures and adsorption properties of their nanoporous crystalline frameworks.

Journal: Journal of the American Chemical Society 20040901

Title: Palladium-catalyzed alkylation of vinyl oxiranes with substituted allenes. Direct access to bifunctionalized allylic alcohols.

Journal: The Journal of organic chemistry 20040709

Title: Hydrosilylation of alkynes with a cationic rhodium species formed in an anionic micellar system.

Journal: Organic letters 20040624

Title: Facile palladium-catalysed synthesis of 1-aryl-1H-indazoles from 2-bromobenzaldehydes and arylhydrazines.

Journal: Chemical communications (Cambridge, England) 20040107

Title: Square-planar coordinated polyanions of palladium, platinum, and gold stannaborate [SnB11H11]2- coordination chemistry.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20030922

Title: A new regioselective Heck vinylation with enamides. Synthesis and investigation of fluorous-tagged bidentate ligands for fast separation.

Journal: The Journal of organic chemistry 20030822

Title: A novel palladium-catalyzed synthesis of 1,2-dihydroquinoxalines and 3,4-dihydroquinoxalinones.

Journal: Organic letters 20020418

Title: Gold(I) macrocycles and topologically chiral [2]catenanes.

Journal: Journal of the American Chemical Society 20020417

Title: Aryl-aryl coupling reaction using a novel and highly active palladium reagent prepared from Pd(OAc)2, 1,3-bis[diphenylphosphino]propane (DPPP), and Bu3P.

Journal: Chemical & pharmaceutical bulletin 20020401

Title: [Bis(diphenylphosphino)methane][1,3-bis(diphenylphosphino)propane]platinum(II) dibromide.

Journal: Acta crystallographica. Section C, Crystal structure communications 20011101

Title: A meso-helical coordination polymer from achiral dinuclear [Cu2(H3CCN)2(micro-pydz)3][PF6]2 and 1,3-bis(diphenylphosphanyl)propane-synthesis and crystal structure of 1 to infinity Cu(mu-pydz)2][PF6 (pydz=pyridazine).

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20010917

Title: Iridium-catalyzed transfer hydrogenation of alpha,beta-unsaturated and saturated carbonyl compounds with 2-propanol.

Journal: The Journal of organic chemistry 20010629

Title: Heterobimetallic, cubane-like Mo(3)S(4)M' cluster cores containing the noble metals M' = Ru, Os, Rh, Ir. Unprecedented tri(mu-carbonyl) bridge between ruthenium atoms in [(eta(5)-Cp')(3)Mo(3)S(4)Ru)2(mu-CO)3]2+.

Journal: Inorganic chemistry 20010618

Quotation Request
Company Name:
*
Contact Person:
*
Email:
*
Quantity Required:
*
Country:
Additional Info:
SDS
Tags:6737-42-4 Molecular Formula|6737-42-4 MDL|6737-42-4 SMILES|6737-42-4 1,3-Bis(diphenylphosphino)propane