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70197-13-6,MFCD00192332
Catalog No.:AA003S1T

70197-13-6 | Methyltrioxorhenium

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100mg
>97.0%(T)
in stock  
$44.00   $31.00
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1g
97%
in stock  
$350.00   $245.00
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2g
98%
in stock  
$643.00   $450.00
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5g
97%
in stock  
$1,272.00   $890.00
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  • Technical Information
  • Properties
  • Literature
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA003S1T
Chemical Name:
Methyltrioxorhenium
CAS Number:
70197-13-6
Molecular Formula:
CH3O3Re
Molecular Weight:
249.2397
MDL Number:
MFCD00192332
SMILES:
C[Re](=O)(=O)=O
Properties
Properties
 
BP:
65°C 0mm  
Form:
Solid  
MP:
111 °C(lit.)  
Stability:
Moisture & Light Sensitive  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
65.5  
Covalently-Bonded Unit Count:
2  
Formal Charge:
-1  
Heavy Atom Count:
5  
Hydrogen Bond Acceptor Count:
4  

Literature

Title: Methyltrioxorhenium-catalyzed epoxidation of homoallylic alcohols with hydrogen peroxide.

Journal: The Journal of organic chemistry 20121102

Title: Methyltrioxorhenium catalysis in nonconventional solvents: a great catalyst in a safe reaction medium.

Journal: ChemSusChem 20100525

Title: H2-driven deoxygenation of epoxides and diols to alkenes catalyzed by methyltrioxorhenium.

Journal: Inorganic chemistry 20091102

Title: One-pot synthesis of nitrones from primary amines and aldehydes catalyzed by methyltrioxorhenium.

Journal: ChemSusChem 20080101

Title: Modification of protein by disulfide S-monoxide and disulfide S-dioxide: distinctive effects on PKC.

Journal: Biochemistry 20070220

Title: Catalytic oxidation of imines based on methyltrioxorhenium/urea hydrogen peroxide: a mild and easy chemo- and regioselective entry to nitrones.

Journal: Organic letters 20070201

Title: An efficient and stereoselective dearylation of asarinin and sesamin tetrahydrofurofuran lignans to acuminatolide by methyltrioxorhenium/H(2)O(2) and UHP systems.

Journal: Journal of natural products 20070101

Title: Immobilized methyltrioxo rhenium (MTO)/H2O2 systems for the oxidation of lignin and lignin model compounds.

Journal: Bioorganic & medicinal chemistry 20060801

Title: Regio and stereoselective oxidations of unsaturated steroidal compounds with H2O2 mediated by CH3ReO3.

Journal: Steroids 20060701

Title: Methyltrioxorhenium catalysed synthesis of highly oxidised aryltetralin lignans with anti-topoisomerase II and apoptogenic activities.

Journal: Bioorganic & medicinal chemistry 20051101

Title: Methyltrioxorhenium: a new catalyst for the activation of hydrogen peroxide to the oxidation of lignin and lignin model compounds.

Journal: Bioorganic & medicinal chemistry 20050401

Title: Kinetics of MTO-catalyzed olefin epoxidation in ambient temperature ionic liquids: UV/Vis and 2H NMR study.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20020702

Title: CH(3)ReO(3)-catalyzed oxidation of cholesta-5,7-dien-3beta-yl acetate with the urea-hydrogen peroxide adduct under various conditions. Synthesis of the natural epoxy sterol 9alpha,11alpha-epoxy-5alpha-cholest-7-en-3beta,5,6beta-triol.

Journal: Steroids 20020601

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