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Home Other Heterocycles 71042-54-1
71042-54-1,MFCD00085364
Catalog No.:AA003BMC

71042-54-1 | (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene

Pack Size
Purity
Availability
Price(USD)
Quantity
  
100mg
98%
in stock  
$57.00   $40.00
- +
250mg
98%
in stock  
$95.00   $67.00
- +
1g
98%
in stock  
$378.00   $265.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003BMC
Chemical Name:
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene
CAS Number:
71042-54-1
Molecular Formula:
C33H30
Molecular Weight:
426.5913
MDL Number:
MFCD00085364
SMILES:
C1=C[C@H]2C[C@@H]1[C@@H]([C@H]2C(c1ccccc1)c1ccccc1)C(c1ccccc1)c1ccccc1
Properties
Properties
 
Form:
Solid  
MP:
120 °C  
Stability:
air sensitive  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
543  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
4  
Heavy Atom Count:
33  
Rotatable Bond Count:
6  
XLogP3:
6.9  

Downstream Synthesis Route

[1]Brunner,Henri;Muschiol,Manfred;Zabel,Manfred[Synthesis,2008,#3,p.405-408]

71042-54-1    12146-36-0   
Cr(CO)4C7H8P(C6H5)2P(C6H5)2 

[1]Brunner,Henri;Rahman,A.F.M.Mokhlesur[JournalofOrganometallicChemistry,1981,vol.214,#3,p.373-380]

71042-54-1   
dichloro(η3-allyl)palladium(II) 
 
palladium(S,S-norphos)(η3-allyl)ClO4 

[1]Auburn,PamelaR.;Mackenzie,PeterB.;Bosnich,B.[JournaloftheAmericanChemicalSociety,1985,vol.107,#7,p.2033-2046]

ammoniumhexafluorophosphate 
 
dichloro(pentamethylcyclopentadienyl)rhodium(III)dimer 
  71042-54-1   
Cp*Rh((2S,3S)-(+)-bis(diphenylphosphanyl)bicyclo2.2.1hept-5-ene)ClPF6 

[1]Brunner,Henri;Grau,Ilias;Zabel,Manfred[Organometallics,2004,vol.23,#16,p.3788-3799]

ammoniumhexafluorophosphate 
 
bisdichloro(pentamethylcyclopentadienyl)iridium(III) 
  71042-54-1   
Cp*Ir((2S,3S)-(+)-bis(diphenylphosphanyl)bicyclo2.2.1hept-5-ene)ClPF6 

[1]Brunner,Henri;Grau,Ilias;Zabel,Manfred[Organometallics,2004,vol.23,#16,p.3788-3799]

Literature
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SDS
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Tags:71042-54-1 Molecular Formula|71042-54-1 MDL|71042-54-1 SMILES|71042-54-1 (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene