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74974-61-1,MFCD00143596
Catalog No.:AA0034DO

74974-61-1 | Aluminum trifluoromethanesulfonate

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1g
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$11.00   $8.00
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25g
95%
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100g
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  • Technical Information
  • Properties
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Technical Information
Catalog Number:
AA0034DO
Chemical Name:
Aluminum trifluoromethanesulfonate
CAS Number:
74974-61-1
Molecular Formula:
C3AlF9O9S3
Molecular Weight:
474.1889
MDL Number:
MFCD00143596
SMILES:
FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.[Al+3]
Properties
Properties
 
Form:
Solid  
MP:
300 °C(lit.)  
Stability:
Hygroscopic  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
145  
Covalently-Bonded Unit Count:
4  
Heavy Atom Count:
25  
Hydrogen Bond Acceptor Count:
18  

Literature

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Journal: The Journal of organic chemistry 20121019

Title: Synthesis of highly substituted oxazoles through iodine(III)-mediated reactions of ketones with nitriles.

Journal: Molecules (Basel, Switzerland) 20120913

Title: Michael addition/pericyclization/rearrangement--a multicomponent strategy for the synthesis of substituted resorcinols.

Journal: Organic & biomolecular chemistry 20120821

Title: Superelectrophilic amidine dications: dealkylation by triflate anion.

Journal: Angewandte Chemie (International ed. in English) 20120820

Title: Generation of polyfluoroaryl-fused H-pyrazolo[5,1-a]isoquinolines through a reaction of N'-(2-alkynylbenzylidene)hydrazide with polyfluoroarene.

Journal: Chemistry, an Asian journal 20120801

Title: Comparison of different imidazolium supported ionic liquid polymeric phases with strong anion-exchange character for the extraction of acidic pharmaceuticals from complex environmental samples.

Journal: Journal of separation science 20120801

Title: An unexpected silver triflate-catalyzed tandem reaction of N'-(2-alkynylbenzylidene)hydrazide with ketene.

Journal: Chemical communications (Cambridge, England) 20120718

Title: Multigram-scale synthesis of an orthogonally protected 2-acetamido-4-amino-2,4,6-trideoxy-D-galactose (AAT) building block.

Journal: Carbohydrate research 20120715

Title: Synthesis of cyclopropyl glycosides and their use as novel glycosyl donors.

Journal: Carbohydrate research 20120715

Title: Complications of modeling glycosylation reactions: can the anomeric conformation of a donor determine the glycopyranosyl oxacarbenium ring conformation?

Journal: Carbohydrate research 20120715

Title: Hg(OTf)(2)-catalyzed direct vinylation of tryptamines and versatile applications for tandem reactions.

Journal: Organic & biomolecular chemistry 20120607

Title: An efficient and recyclable catalyst for the cleavage of tert-butyldiphenylsilyl ethers.

Journal: Carbohydrate research 20120601

Title: An unexpected silver triflate catalyzed reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate.

Journal: Organic letters 20120601

Title: Silver triflate and palladium acetate co-catalyzed reaction of N'-(2-alkynylbenzylidene)hydrazide with N-allyl ynamide.

Journal: Organic letters 20120601

Title: Silver triflate catalyzed tandem heterocyclization/alkynylation of 1-((2-tosylamino)aryl)but-2-yne-1,4-diols to 2-alkynyl indoles.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120514

Title: Synthesis of pyridine and dihydropyridine derivatives by regio- and stereoselective addition to N-activated pyridines.

Journal: Chemical reviews 20120509

Title: A carbaboranylmercuric salt catalyzed reaction; highly regioselective cycloisomerization of 1,3-dienes.

Journal: Organic letters 20120504

Title: Generation of diverse 1-imidazolylisoquinolines via silver triflate-catalyzed reaction of 2-alkynylbenzaldoxime with imidazole.

Journal: Molecular diversity 20120501

Title: Silver triflate-copper(II) acetate cooperative catalysis in a cascade reaction for concise synthesis of 2-carbonyl H-pyrazolo[5,1-a]isoquinolines.

Journal: Chemical communications (Cambridge, England) 20120425

Title: Copper(II)/phenanthroline-mediated CD-enhancement and chiral memory effect on a meta-ethynylpyridine oligomer.

Journal: Chemical communications (Cambridge, England) 20120404

Title: Development of new hydrogenations of imines and benign reductive hydroaminations: zinc triflate as a catalyst.

Journal: ChemSusChem 20120401

Title: Significant contributions of ionic liquids containing tetrafluoroborate and trifluoromethanesulfonate to antagonisms and synergisms in multi-component mixtures.

Journal: Journal of hazardous materials 20120330

Title: Efficient synthesis of β-enaminones and β-enaminoesters catalyzed by gold (I)/silver (I) under solvent-free conditions.

Journal: Molecules (Basel, Switzerland) 20120306

Title: Enantioselective [4+2] cycloadditions of 2-vinyl-1H-indoles with 3-nitro-2H-chromenes catalyzed by a Zn(OTf)2/bis(oxazoline) complex: an efficient approach to fused heterocycles with a quaternary stereocenter.

Journal: Chemistry, an Asian journal 20120305

Title: Palladium-catalyzed direct hydroxymethylation of aryl halides and triflates with potassium acetoxymethyltrifluoroborate.

Journal: Organic letters 20120302

Title: Hg(OTf)2-catalyzed vinylogous semi-pinacol rearrangement leading to 1,4-dihydroquinolines.

Journal: Organic letters 20120302

Title: Chemoselective synthesis of ketones and ketimines by addition of organometallic reagents to secondary amides.

Journal: Nature chemistry 20120221

Title: Rhodium-catalyzed and zinc(II)-triflate-promoted asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones.

Journal: Organic letters 20120217

Title: Synthesis of pyrroles through a 4π-electrocyclic ring-closure reaction of 1-azapentadienyl cations.

Journal: The Journal of organic chemistry 20120217

Title: Gold nanoparticle probes: design and in vitro applications in cancer cell culture.

Journal: Colloids and surfaces. B, Biointerfaces 20120201

Title: Indium-mediated asymmetric Barbier-type propargylations: additions to aldehydes and ketones and mechanistic investigation of the organoindium reagents.

Journal: The Journal of organic chemistry 20120120

Title: Construction of a six-membered fused N-heterocyclic ring via a new 3-component reaction: synthesis of (pyrazolo)pyrimidines/pyridines.

Journal: Chemical communications (Cambridge, England) 20120111

Title: Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides.

Journal: Journal of the American Chemical Society 20111116

Title: On the influence of hydrated ionic liquids on the dynamical structure of model proteins: a computational study.

Journal: Physical chemistry chemical physics : PCCP 20111028

Title: Brønsted acid assisted activation of imide carbonyl group: regioselective synthesis of isoindoloisoquinolinone alkaloid (±)-nuevamine.

Journal: Organic & biomolecular chemistry 20111026

Title: Silver-mediated trifluoromethylation of arenes using TMSCF3.

Journal: Organic letters 20111021

Title: Solvent-induced anomeric diastereoselectivity switching using a single glycosyl donor.

Journal: Carbohydrate research 20111018

Title: Reverse orthogonal strategy for oligosaccharide synthesis.

Journal: Chemical communications (Cambridge, England) 20111014

Title: Highly diastereoselective vinylogous Mukaiyama aldol reaction of α-keto phosphonates with 2-(trimethylsilyloxy)furan catalyzed by Cu(OTf)2.

Journal: Organic & biomolecular chemistry 20111007

Title: Telomere targeting with a new G4 ligand enhances radiation-induced killing of human glioblastoma cells.

Journal: Molecular cancer therapeutics 20111001

Title: A new type of bis(sulfonamide)-diamine ligand for a Cu(OTf)2-catalyzed asymmetric Friedel-Crafts alkylation reaction of indoles with nitroalkenes.

Journal: Organic letters 20110916

Title: Reactivity switching and selective activation of C-1 or C-3 in 2,3-unsaturated thioglycosides.

Journal: Carbohydrate research 20110906

Title: Synthesis of γ-benzopyranone by TfOH-promoted regioselective cyclization of o-alkynoylphenols.

Journal: Organic letters 20110902

Title: An efficient route to 1-aminoisoquinolines via AgOTf-catalyzed reaction of 2-alkynylbenzaldoxime with amine.

Journal: Organic & biomolecular chemistry 20110707

Title: Proton transport in triflic acid pentahydrate studied via ab initio path integral molecular dynamics.

Journal: The journal of physical chemistry. A 20110616

Title: Triflic acid-mediated phenylation of N-acylaminoalkyl diethylacetals and N-acyl-2-phenyl cyclic amides.

Journal: Organic & biomolecular chemistry 20110607

Title: Protolytic defluorination of trifluoromethyl-substituted arenes.

Journal: Organic & biomolecular chemistry 20110602

Title: Silver triflate catalyzed reaction of 2-alkynylbenzaldoxime with aryne.

Journal: Organic letters 20110520

Title: Synthesis of α-aryl nitriles through palladium-catalyzed decarboxylative coupling of cyanoacetate salts with aryl halides and triflates.

Journal: Angewandte Chemie (International ed. in English) 20110502

Title: Existence of optical phonons in the room temperature ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate.

Journal: The Journal of chemical physics 20110407

Title: N-Alkylpyridinium isotope quaternization for matrix-assisted laser desorption/ionization Fourier transform mass spectrometric analysis of cholesterol and fatty alcohols in human hair.

Journal: Analytica chimica acta 20110325

Title: A novel Zn-catalyzed hydroamination of propargylamides: a general synthesis of di- and tri-substituted imidazoles.

Journal: Chemical communications (Cambridge, England) 20110221

Title: Indium triflate-catalyzed coupling between nitroalkenes and phenol/naphthols: a simple and direct synthesis of arenofurans by a cyclization reaction.

Journal: Chemistry, an Asian journal 20110201

Title: A Ritter-type reaction: direct electrophilic trifluoromethylation at nitrogen atoms using hypervalent iodine reagents.

Journal: Angewandte Chemie (International ed. in English) 20110201

Title: TfOH-catalyzed tandem cyclopropane ring enlargement/C-C formation/etherification of alkynylcyclopropanes and 1,3-diketones to cyclobutane-fused dihydrofurans.

Journal: Chemical communications (Cambridge, England) 20110114

Title: Electronic and vibrational spectra of some rare earth trifluoromethanesulfonates crystals.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20110101

Title: 1H and 13C NMR spectra, structure and physicochemical features of phenyl acridine-9-carboxylates and 10-methyl-9-(phenoxycarbonyl)acridinium trifluoromethanesulphonates--alkyl substituted in the phenyl fragment.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20110101

Title: Novel synthesis of optically active bishomotyrosine derivatives using the Friedel-Crafts reaction in triflic acid.

Journal: Bioscience, biotechnology, and biochemistry 20110101

Title: Versatile method for the synthesis of 4-aminocyclopentenones: dysprosium(III) triflate catalyzed aza-piancatelli rearrangement.

Journal: Angewandte Chemie (International ed. in English) 20101203

Title: Zinc triflate: a highly efficient reusable catalyst in the synthesis of functionalized quinolines via Friedlander annulation.

Journal: Molecular diversity 20101101

Title: Deglycosylated milin unfolds via inactive monomeric intermediates.

Journal: European biophysics journal : EBJ 20101101

Title: Silver triflate and N-heterocyclic carbene co-catalyzed reaction of N'-(2-alkynylbenzylidene)hydrazide, methanol with alpha,beta-unsaturated aldehyde.

Journal: Chemical communications (Cambridge, England) 20100914

Title: Metal trifluoromethanesulfonate-catalyzed regioselective acylation of myo-inositol 1,3,5-orthoformate.

Journal: Chemical communications (Cambridge, England) 20100814

Title: The mimic of type II aldolases chemistry: asymmetric synthesis of beta-hydroxy ketones by direct aldol reaction.

Journal: Chemical biology & drug design 20100801

Title: Anticancer activity of opened arene ruthenium metalla-assemblies.

Journal: Dalton transactions (Cambridge, England : 2003) 20100614

Title: N,N'-dioxide-Cu(OTf)(2) complex catalyzed highly enantioselective amination reaction of N-acetyl enamide.

Journal: Organic letters 20100521

Title: Tandem reactions of N'-(2-alkynylbenzylidene)hydrazides with silyl enolates: a facile route to H-pyrazolo[5,1-a]isoquinolines.

Journal: Journal of combinatorial chemistry 20100510

Title: Multicomponent cascade transformation of D-glucal to furan-appended triazole glycoconjugates.

Journal: The Journal of organic chemistry 20100507

Title: Catalytic asymmetric synthesis of 3-(alpha-hydroxy-beta-carbonyl) oxindoles by a Sc(III)-catalyzed direct aldol-type reaction.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20100322

Title: Superelectrophiles and the effects of trifluoromethyl substituents.

Journal: Journal of the American Chemical Society 20100317

Title: Dynamers at the solid-liquid interface: controlling the reversible assembly/reassembly process between two highly ordered supramolecular guanine motifs.

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Title: Stereoselective synthesis of highly functionalized alpha-diazo-beta-ketoalkanoates via catalytic one-pot Mukaiyama-Aldol reactions.

Journal: Organic letters 20100219

Title: Zn(OTf)2-catalyzed reactions of ethenetricarboxylates with 2-aminobenzaldehydes leading to tetrahydroquinoline derivatives.

Journal: The Journal of organic chemistry 20100219

Title: Hydroamination reactions by metal triflates: Brønsted acid vs. metal catalysis?

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Title: Syntheses, structures and spectroscopy of uni- and bi-dentate nitrogen base complexes of silver(I) trifluoromethanesulfonate.

Journal: Dalton transactions (Cambridge, England : 2003) 20100121

Title: H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.

Journal: Accounts of chemical research 20100119

Title: Indium triflate-assisted nucleophilic aromatic substitution reactions of nitrosobezene-derived cycloadducts with alcohols.

Journal: Organic letters 20100115

Title: Efficient access to extended Yagupolskii-Umemoto-type reagents: triflic acid catalyzed intramolecular cyclization of ortho-ethynylaryltrifluoromethylsulfanes.

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Title: Multistep microchemical synthesis enabled by microfluidic distillation.

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Title: Coordination of N-donor ligands to a uranyl(V) beta-diketiminate complex.

Journal: Inorganic chemistry 20091221

Title: A new approach to switching of enantioselectivity in NHC-Cu-catalyzed conjugate addition of alkylzincs to cyclic enones.

Journal: Chemical communications (Cambridge, England) 20091221

Title: Highly stereoselective synthesis of alpha-D-mannopyranosyl phosphosugars.

Journal: The Journal of organic chemistry 20091218

Title: Enhancement of 5-aminopenta-2,4-dienals electrophilicity via activation by O,N-bistrifluoroacetylation. application to an N-acyl Pictet-Spengler reaction.

Journal: The Journal of organic chemistry 20091218

Title: An enantiopure pseudo-C3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions.

Journal: Dalton transactions (Cambridge, England : 2003) 20091214

Title: CE-ESI-MS analysis of singly charged inorganic and organic anions using a dicationic reagent as a complexing agent.

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Journal: Chemical communications (Cambridge, England) 20091028

Title: Regio- and stereoselective indium triflate-mediated nucleophilic ring-opening reactions of 3-aza-2-oxabicyclo[2.2.1]hept-5-ene and -[2.2.2]oct-5-ene systems.

Journal: The Journal of organic chemistry 20091016

Title: Trifluoromethanesulfonic acid-based proteomic analysis of cell wall and secreted proteins of the ascomycetous fungi Neurospora crassa and Candida albicans.

Journal: Fungal genetics and biology : FG & B 20091001

Title: One-step transformation of tetrahydropyranyl ethers using indium(III) triflate as the catalyst.

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Title: Pd-catalyzed conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics.

Journal: Journal of the American Chemical Society 20090916

Title: Ruthenium-catalyzed transformation of alkenyl triflates to alkenyl halides.

Journal: Chemical communications (Cambridge, England) 20090914

Title: Use of comparative triazolinium triflate fragmentation rates as a tool to assay relative competency of Brønsted bases in N-->N proton transfer.

Journal: Bioorganic & medicinal chemistry letters 20090901

Title: Use of 4-piperidones in one-pot syntheses of novel, high-molecular-weight linear and virtually 100%-hyperbranched polymers.

Journal: Chemical communications (Cambridge, England) 20090807

Title: Fluorination of boronic acids mediated by silver(I) triflate.

Journal: Organic letters 20090702

Title: AgOTf-catalyzed tandem reaction of N'-(2-alkynylbenzylidene)hydrazide with alkyne.

Journal: Chemical communications (Cambridge, England) 20090621

Title: Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter.

Journal: Journal of the American Chemical Society 20090610

Title: Effective synthesis of optically active trifluoromethyldiazirinyl homophenylalanine and aroylalanine derivatives with the Friedel-Crafts reaction in triflic acid.

Journal: Bioscience, biotechnology, and biochemistry 20090601

Title: Direct alkylative Passerini reaction of aldehydes, isocyanides, and free aliphatic alcohols catalyzed by indium(III) triflate.

Journal: The Journal of organic chemistry 20090515

Title: Dynamic measurements of aqueous lanthanide triflate-catalyzed reactions using luminescence decay.

Journal: Journal of the American Chemical Society 20090513

Title: Catalytic enantioselective construction of all-carbon quaternary stereocenters by an organocatalytic Diels-Alder reaction of alpha-substituted alpha,beta-unsaturated aldehydes.

Journal: Chemical communications (Cambridge, England) 20090421

Title: Indium-catalyzed C-S cross-coupling of aryl halides with thiols.

Journal: The Journal of organic chemistry 20090417

Title: Efficient dehydrative sialylation of C-4-aminated sialyl-hemiketal donors with Ph2SO/Tf2O.

Journal: The Journal of organic chemistry 20090220

Title: Reactions of aquatitanium(II) with hypervalent chromium species.

Journal: Dalton transactions (Cambridge, England : 2003) 20090207

Title: Direct dehydrative N-pyridinylation of amides.

Journal: The Journal of organic chemistry 20090206

Title: FT-IR spectroscopic investigation of ionic interactions in PPG 4000: AgCF3SO3 polymer electrolyte.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20090101

Title: Lewis acid catalyzed formation of tetrahydroquinolines via an intramolecular redox process.

Journal: Organic letters 20090101

Title: Triflic acid catalyzed synthesis of spirocycles via acetylene cations.

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Title: Chemoselective allylation of ketones in ionic liquids containing sulfonate anions.

Journal: ChemSusChem 20090101

Title: Highly enantioselective carbonyl-ene reactions catalyzed by In(III)-PyBox complex.

Journal: Journal of the American Chemical Society 20081210

Title: Iron-catalyzed cross-coupling reactions between a bicyclic alkenyl triflate and Grignard reagents.

Journal: The Journal of organic chemistry 20081003

Title: One-pot Negishi cross-coupling reactions of in situ generated zinc reagents with aryl chlorides, bromides, and triflates.

Journal: The Journal of organic chemistry 20080919

Title: Investigations of glycosylation reactions with 2-N-acetyl-2N,3O-oxazolidinone-protected glucosamine donors.

Journal: The Journal of organic chemistry 20080919

Title: Using enantioselective indicator displacement assays to determine the enantiomeric excess of alpha-amino acids.

Journal: Journal of the American Chemical Society 20080917

Title: Synthesis of neutral glycosphingolipids from Zygomycetes.

Journal: Carbohydrate research 20080908

Title: Lewis acid-catalyzed intermolecular [4 + 2] cycloaddition of 3-alkoxycyclobutanones to aldehydes and ketones.

Journal: Journal of the American Chemical Society 20080903

Title: One-pot synthesis of oligosaccharides by combining reductive openings of benzylidene acetals and glycosylations.

Journal: Organic letters 20080807

Title: A stable, commercially available sulfenyl chloride for the activation of thioglycosides in conjunction with silver trifluoromethanesulfonate.

Journal: Carbohydrate research 20080721

Title: Indium triflate catalyzed peracetylation of carbohydrates.

Journal: Carbohydrate research 20080721

Title: Scope and mechanism for lewis acid-catalyzed cycloadditions of aldehydes and donor-acceptor cyclopropanes: evidence for a stereospecific intimate ion pair pathway.

Journal: Journal of the American Chemical Society 20080709

Title: Oxidative radical cyclisations for the synthesis of gamma-lactones.

Journal: Chemical communications (Cambridge, England) 20080614

Title: Lewis super-acid catalyzed cyclizations: a new route to fragrance compounds.

Journal: Chemistry & biodiversity 20080601

Title: A recyclable copper(ii) catalyst for the annulation of phenols with 1,3-dienes.

Journal: Chemical communications (Cambridge, England) 20080528

Title: Tetrakis(trifluoromethanesulfonyl)propane: highly effective Brønsted acid catalyst for vinylogous Mukaiyama-Michael reaction of alpha,beta-enones with silyloxyfurans.

Journal: Chemical communications (Cambridge, England) 20080528

Title: Cation-induced pi-stacking.

Journal: The Journal of organic chemistry 20080516

Title: Benzo[1,2-b:4,5-b']bis[b]benzothiophene as solution processible organic semiconductor for field-effect transistors.

Journal: Chemical communications (Cambridge, England) 20080407

Title: Ruthenium-catalyzed vinylic substitution reactions with nucleophiles via butatrienylidene intermediates.

Journal: Journal of the American Chemical Society 20080312

Title: Triflic acid-catalyzed highly stereoselective friedel-crafts aminoalkylation of indoles and pyrroles.

Journal: Organic letters 20080306

Title: Thermodynamics of hydrogen atom transfer to a high-valent iron imido complex.

Journal: Journal of the American Chemical Society 20080305

Title: On the nature of rate acceleration in the synthesis and fragmentation of triazolines by Brønsted acid: secondary catalysis by water (hydronium triflate).

Journal: Journal of the American Chemical Society 20080220

Title: Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel.

Journal: Journal of the American Chemical Society 20080109

Title: Aluminum triflate as a highly active and efficient nonprotic cocatalyst in the palladium-catalyzed methoxycarbonylation reaction.

Journal: Angewandte Chemie (International ed. in English) 20080101

Title: Catalytic enantioselective Hosomi-Sakurai conjugate allylation of cyclic unsaturated ketoesters.

Journal: Angewandte Chemie (International ed. in English) 20080101

Title: General zinc-catalyzed intermolecular hydroamination of terminal alkynes.

Journal: ChemSusChem 20080101

Title: Efficient ytterbium triflate catalyzed microwave-assisted synthesis of 3-acylacrylic acid building blocks.

Journal: Journal of combinatorial chemistry 20080101

Title: Knorr cyclizations and distonic superelectrophiles.

Journal: The Journal of organic chemistry 20071207

Title: Lewis acid- and organocatalyst-cocatalyzed multicomponent reactions of 2-alkynylbenzaldehydes, amines, and ketones.

Journal: Organic letters 20071122

Title: Cobalt-catalyzed cross-coupling of alkynyl Grignard reagents with alkenyl triflates.

Journal: Chemical communications (Cambridge, England) 20071121

Title: One-pot synthesis of carbazoles by palladium-catalyzed N-arylation and oxidative coupling.

Journal: Chemical communications (Cambridge, England) 20071121

Title: First synthesis of tepidopterin [2'-O-(2-acetamido-2-deoxy-beta-d-glucopyranosyl)-L-threo-biopterin].

Journal: Carbohydrate research 20071105

Title: Electrochemical generation of glycosyl triflate pools.

Journal: Journal of the American Chemical Society 20070905

Title: High-yielding one-pot synthesis of diaryliodonium triflates from arenes and iodine or aryl iodides.

Journal: Chemical communications (Cambridge, England) 20070628

Title: TLXI, a novel type of xylanase inhibitor from wheat (Triticum aestivum) belonging to the thaumatin family.

Journal: The Biochemical journal 20070501

Title: Evaluation of thioglycosides of Kdo as glycosyl donors.

Journal: Carbohydrate research 20070226

Title: Mild conditions for the synthesis of functionalized pyrrolidines via Pd-catalyzed carboamination reactions.

Journal: Organic letters 20070201

Title: Stille/Diels-Alder reaction sequences: diversity-oriented access to novel steroids.

Journal: Organic letters 20070201

Title: Silver(I) triflate-catalyzed direct synthesis of N-PMP protected alpha-aminopropargylphosphonates from terminal alkynes.

Journal: Organic letters 20070104

Title: Cu2(OTf)2-catalyzed and microwave-controlled preparation of tetrazoles from nitriles and organic azides under mild, safe conditions.

Journal: Angewandte Chemie (International ed. in English) 20070101

Title: AgOTf-catalyzed three-component reactions of 2-alkynylbenzaldehydes, amines, and diethylphosphite. An efficient route to 2,3-disubstituted-1,2-dihydroisoquinolin-1-ylphosphonates.

Journal: Journal of combinatorial chemistry 20070101

Title: [Photometric method determining trifluoromethanesulfonic acid in work-place air].

Journal: Meditsina truda i promyshlennaia ekologiia 20070101

Title: Odorless benzenethiols in synthesis of thioglycosides and its application for glycosylation reactions.

Journal: Bioorganic & medicinal chemistry letters 20061115

Title: An efficient access to novel enantiomerically pure steroidal delta-amino acids.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20061106

Title: Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates.

Journal: Organic letters 20060914

Title: Nickel-catalyzed coupling of alkenes, aldehydes, and silyl triflates.

Journal: Journal of the American Chemical Society 20060906

Title: Determination of purity degree and counter-ion content in lecirelin by capillary zone electrophoresis and capillary isotachophoresis.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20060901

Title: Aluminium(III) trifluoromethanesulfonate as an efficient catalyst for the intramolecular hydroalkoxylation of unactivated olefins: experimental and theoretical approaches.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060816

Title: Design and synthesis of hydrophobic and chiral anions from amino acids as precursor for functional ionic liquids.

Journal: Chemical communications (Cambridge, England) 20060807

Title: Magnesium bistrifluoromethanesulfonimide as a new and efficient acylation catalyst.

Journal: The Journal of organic chemistry 20060721

Title: Biobased contents of biodegradable poly(epsilon-caprolactone) composites polymerized and directly molded using aluminium triflate from caprolactone with cellulose and inorganic filler.

Journal: Macromolecular bioscience 20060714

Title: Zn(OTf)2-catalyzed cyclization of proparyl alcohols with anilines, phenols, and amides for synthesis of indoles, benzofurans, and oxazoles through different annulation mechanisms.

Journal: The Journal of organic chemistry 20060623

Title: Hydrogen-deuterium exchange between TpRu(PMe3)(L)X (L = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and deuterated arene solvents: evidence for metal-mediated processes.

Journal: Journal of the American Chemical Society 20060621

Title: Stereocontrolled synthesis of the D- and L-glycero-beta-D-manno-heptopyranosides and their 6-deoxy analogues. Synthesis of methyl alpha-l-rhamno-pyranosyl-(1-->3)-D-glycero-beta-D-manno-heptopyranosyl- (1-->3)-6-deoxy-glycero-beta-D-manno-heptopyranosyl-(1-->4)-alpha-L- rhamno-pyranoside, a tetrasaccharide subunit of the lipopolysaccharide from Plesimonas shigelloides.

Journal: Journal of the American Chemical Society 20060621

Title: Pyrrole synthesis catalyzed by AgOTf or cationic Au(I) complexes.

Journal: The Journal of organic chemistry 20060609

Title: In(OTf)3-catalyzed tandem nucleophilic addition and cyclization of ortho-alkynylarylaldimines to 1,2-dihydroisoquinolines.

Journal: Angewandte Chemie (International ed. in English) 20060602

Title: Diastereopure Fe(II) and Zn(II) complexes derived from a tridentate N,N',N-bis(methyl-L-prolinate)-substituted pyridine ligand.

Journal: Inorganic chemistry 20060515

Title: Operationally simple, efficient, and diastereoselective synthesis of cis-2,6-disubstituted-4-methylene tetrahydropyrans catalyzed by triflic acid.

Journal: Organic letters 20060427

Title: Development of the Pictet-Spengler reaction catalyzed by AuCl3/AgOTf.

Journal: The Journal of organic chemistry 20060317

Title: Catalytic asymmetric mannich-type reactions activated by ZnF2 chiral diamine in aqueous media.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060123

Title: Regioselective indium(III) trifluoromethanesulfonate-catalyzed hydrothiolation of non-activated olefins.

Journal: Chemical communications (Cambridge, England) 20060121

Title: Carbohydrate-derived amino-alcohol ligands for asymmetric alkynylation of aldehydes.

Journal: Organic letters 20060119

Title: Sc(OTf)3-catalyzed indolylation of 1,2-allenic ketones: controlled highly selective synthesis of beta-indolyl-alpha,beta-unsaturetated (E)-enones and beta,beta-bisindolyl ketones.

Journal: Organic letters 20051027

Title: Regioselective conversion of the secondary hydroxyl groups of D-glucuronic acid without the requirement of O-protecting groups.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20051021

Title: A mild and environmentally friendly scandium(III) trifluoromethanesulfonate-catalyzed synthesis of bis(3'-indolyl)alkanes and bis(3'-indolyl)-1-deoxyalditols.

Journal: Carbohydrate research 20051017

Title: Arylation reactions: the photo-S(N)1 path via phenyl cation as an alternative to metal catalysis.

Journal: Accounts of chemical research 20050901

Title: A facile one-pot benzylation of sodium enolates using trifluoromethanesulfonic anhydride and diphenyl sulfoxide.

Journal: Chemical & pharmaceutical bulletin 20050501

Title: Efficient radiosynthesis of carbon-11 labelled uncharged Thioflavin T derivatives using [11C]methyl triflate for beta-amyloid imaging in Alzheimer's Disease with PET.

Journal: Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine 20050401

Title: A practical catalytic method for preparing highly substituted cyclobutanes and cyclobutenes.

Journal: Journal of the American Chemical Society 20050323

Title: Triflic acid-catalyzed adamantylation of aromatics in [BMIM][OTf] ionic liquid; synthetic scope and mechanistic insight.

Journal: Organic & biomolecular chemistry 20050321

Title: A new class of substituted aryl bis(oxazoline) ligands for highly enantioselective copper-catalyzed asymmetric aldol addition of dienolsilane to pyruvate and glyoxylate esters.

Journal: Organic letters 20041028

Title: Alkylating agents stronger than alkyl triflates.

Journal: Journal of the American Chemical Society 20041006

Title: Induction of a TC1-mediated experimental autoimmune thyroiditis by deglycosylated porcine thyroglobulin.

Journal: Immunopharmacology and immunotoxicology 20040801

Title: Structure of the hydrated and dimethyl sulfoxide solvated rubidium ions in solution.

Journal: Inorganic chemistry 20040531

Title: Decarboxylative elimination of enol triflates as a general synthesis of acetylenes.

Journal: Organic & biomolecular chemistry 20040521

Title: Synthesis of O-aminodihydroartemisinin via TMS triflate catalyzed C-O coupling reaction.

Journal: The Journal of organic chemistry 20040430

Title: Superacid-catalyzed reactions of cinnamic acids and the role of superelectrophiles.

Journal: The Journal of organic chemistry 20040402

Title: Preparation and palladium-catalyzed cross-coupling of aryl triethylammonium bis(catechol) silicates with aryl triflates.

Journal: The Journal of organic chemistry 20040220

Title: Direct synthesis of sulfonamides and activated sulfonate esters from sulfonic acids.

Journal: Journal of the American Chemical Society 20040204

Title: Experimental and theoretical vibrational study of 2,2,2-trifluoroethyl trifluoromethanesulfonate, CF3SO2OCH2CF3.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20040201

Title: Palladium-catalyzed amination of aryl nonaflates.

Journal: The Journal of organic chemistry 20031212

Title: Deglycosylation of glycoproteins with trifluoromethanesulphonic acid: elucidation of molecular structure and function.

Journal: The Biochemical journal 20031201

Title: The 3,4-O-carbonate protecting group as a beta-directing group in rhamnopyranosylation in both homogeneous and heterogeneous glycosylations as compared to the chameleon-like 2,3-O-carbonates.

Journal: The Journal of organic chemistry 20031031

Title: Facile Cu(OTf)2-catalyzed preparation of per-O-acetylated hexopyranoses with stoichiometric acetic anhydride and sequential one-pot anomeric substitution to thioglycosides under solvent-free conditions.

Journal: The Journal of organic chemistry 20031031

Title: Efficient protocol for ring opening of spiroketals using trifluoroacetyl trifluoromethanesulfonate (TFAT).

Journal: Organic letters 20031002

Title: Billion-fold acceleration of the methanolysis of paraoxon promoted by La(OTf)3 in methanol.

Journal: Journal of the American Chemical Society 20030625

Title: Stereoblock copolymers and tacticity control in controlled/living radical polymerization.

Journal: Journal of the American Chemical Society 20030611

Title: Reaction of azulenes with 1-trifluoromethanesulfonylpyridinium trifluoromethanesulfonate (TPT) and synthesis of the parent azulene.

Journal: Organic & biomolecular chemistry 20030607

Title: Rhodium-catalyzed disulfide exchange reaction.

Journal: Journal of the American Chemical Society 20030604

Title: Super acid-induced Pummerer-type cyclization reaction: improvement in the synthesis of chiral 1,3-dimethyl-1,2,3,4-tetrahydroisoquinolines.

Journal: Chemical & pharmaceutical bulletin 20030601

Title: A study on the conversion of indanones into carbostyrils.

Journal: Bioorganic & medicinal chemistry 20030515

Title: Synthesis of 2,3,6-trideoxysugar-containing disaccharides by cyclization and glycosidation through the sequential activation of sulfoxide and methylsulfanyl groups in a one-pot procedure.

Journal: Angewandte Chemie (International ed. in English) 20030425

Title: Zinc triflate-benzoyl bromide: a versatile reagent for the conversion of ether into benzoate protecting groups and ether glycosides into glycosyl bromides.

Journal: Carbohydrate research 20030214

Title: Carbodiimide-mediated preparation of the tricyclic pyrido[3',2':4,5]pyrrolo[1,2-c]pyrimidine ring system and its application to the synthesis of the potent antitumoral marine alkaloid variolin B and analog.

Journal: The Journal of organic chemistry 20030124

Title: Microwave-promoted Pd-catalyzed cyanation of aryl triflates: a fast and versatile access to 3-cyano-3-desoxy-10-ketomorphinans.

Journal: Organic letters 20030123

Title: Scaleable and efficient synthesis of 2'-deoxy-2'-N-phthaloyl nucleoside phosphoramidites for oligonucleotide synthesis.

Journal: Bioorganic & medicinal chemistry letters 20021118

Title: Study of interhalogens/silver trifluoromethanesulfonate as promoter systems for high-yielding sialylations.

Journal: The Journal of organic chemistry 20021018

Title: A convenient method for the conversion of N-acyloxazolidinones to hydroxamic acids.

Journal: Organic letters 20021003

Title: Scandium(III) trifluoromethanesulfonate catalyzed aromatic nitration with inorganic nitrates and acetic anhydride.

Journal: Chemical & pharmaceutical bulletin 20020801

Title: Palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with 1-alkenyl halides or triflates: convenient synthesis of unsymmetrical 1,3-dienes via the borylation-coupling sequence.

Journal: Journal of the American Chemical Society 20020710

Title: Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts.

Journal: Chemical communications (Cambridge, England) 20020707

Title: Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines.

Journal: Organic letters 20020502

Title: Coupling of isoprenoid triflates with organoboron nucleophiles: synthesis and biological evaluation of geranylgeranyl diphosphate analogues.

Journal: Bioorganic & medicinal chemistry 20020501

Title: p-Methoxybenzyl ether cleavage by polymer-supported sulfonamides.

Journal: Organic letters 20020404

Title: Preparation of alpha-sulfenyl enones by thermal fragmentation of beta-sulfenyl enol triflates.

Journal: Organic letters 20020321

Title: Metal trifluoromethanesulfonate-catalyzed regioselective borane-reductive ring opening of benzylidene acetals: a concise synthesis of 1,4-dideoxy-1,4-imino-L-xylitol.

Journal: Organic letters 20020307

Title: Rare earth metal trifluoromethanesulfonates catalyzed benzyl-etherification.

Journal: Chemical & pharmaceutical bulletin 20020301

Title: Chemical deglycosylation can induce methylation, succinimide formation, and isomerization.

Journal: Journal of protein chemistry 20011001

Title: 1-Benzenesulfinyl piperidine/trifluoromethanesulfonic anhydride: a potent combination of shelf-stable reagents for the low-temperature conversion of thioglycosides to glycosyl triflates and for the formation of diverse glycosidic linkages.

Journal: Journal of the American Chemical Society 20010919

Title: Iodine monochloride/silver trifluoromethanesulfonate (ICI/AgOTf) as a convenient promoter system for O-glycoside synthesis.

Journal: Organic letters 20010322

Title: Cross-coupling reactions of potassium alkyltrifluoroborates with aryl and 1-alkenyl trifluoromethanesulfonates.

Journal: Organic letters 20010208

Title: Studies on the synthesis of 1,2-cis pentofuranosides from S-glycofuranosyl dithiocarbamates, dithiocarbonates and phosphorodithioates.

Journal: Carbohydrate research 20010115

Title: Structural studies of the O-specific polysaccharide of Vibrio cholerae O8 using solvolysis with triflic acid.

Journal: Carbohydrate research 20010115

Title: Brominations of steroidal hormone having alpha,beta-unsaturated ketone, 17-O-acetyltestosterone, in the presence of silver triflate.

Journal: Chemical & pharmaceutical bulletin 20010101

Title: Synthesis and anti-HIV-1 activity of novel 2,3-dihydro-7H-thiazolo[3,2-a]pyrimidin-7-ones.

Journal: Journal of medicinal chemistry 19980115

Title: Chitin-bound protein of sarcophagid larvae: metabolism of covalently linked aromatic constituents.

Journal: Biochemistry 19821207

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Tags:74974-61-1 Molecular Formula|74974-61-1 MDL|74974-61-1 SMILES|74974-61-1 Aluminum trifluoromethanesulfonate