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859-65-4,MFCD00014088
Catalog No.:AA003F3H

859-65-4 | (Benzoylmethylene)triphenylphosphorane

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1g
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$6.00   $4.00
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5g
97%
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$8.00   $6.00
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25g
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$38.00   $27.00
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100g
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003F3H
Chemical Name:
(Benzoylmethylene)triphenylphosphorane
CAS Number:
859-65-4
Molecular Formula:
C26H21OP
Molecular Weight:
380.4181
MDL Number:
MFCD00014088
SMILES:
O=C(c1ccccc1)C=P(c1ccccc1)(c1ccccc1)c1ccccc1
NSC Number:
167167
Properties
Properties
 
BP:
550.9°C at 760 mmHg  
Form:
Solid  
MP:
183-186°C  
Solubility:
Soluble in Methanol (almost transparency).  
Stability:
Air Sensitive  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
489  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
28  
Hydrogen Bond Acceptor Count:
1  
Rotatable Bond Count:
5  
XLogP3:
5.2  

Downstream Synthesis Route

[1]Abdou,WafaaM.;Ganoub,NevenA.F.[Phosphorus,SulfurandSiliconandtheRelatedElements,1991,vol.60,#1.2,p.49-55]

[1]Li,Kangying;Alexakis,Alexandre[Chemistry-AEuropeanJournal,2007,vol.13,#13,p.3765-3771]

[2]Jeon,Minseok;Yun,Chaeyoung;Seo,SungYong[Synthesis,2022,vol.54,#12,p.2865-2875]

[3]Brown,PaulM.;Käppel,Nina;Murphy,PatrickJ.;Coles,SimonJ.;Hursthouse,MichaelB.[Tetrahedron,2007,vol.63,#5,p.1100-1106]

[4]Zhang,Xiao-Nan;Shi,Min[EuropeanJournalofOrganicChemistry,2012,#31,p.6271-6279]

[5]Montgomery,John;Savchenko,AlexeyV.;Zhao,Yunbo[JournalofOrganicChemistry,1995,vol.60,p.5699-5701]

[6]Aroyan,CarrieE.;Miller,ScottJ.[JournaloftheAmericanChemicalSociety,2007,vol.129,#2,p.256-257]

[7]Mojr,Viktor;Svobodová,Eva;Straková,Karolína;Neveselý,TomáŠ;Chudoba,Josef;Dvořáková,Hana;Cibulka,Radek[ChemicalCommunications,2015,vol.51,#60,p.12036-12039]

[1]Beauseigneur,Alice;Ericsson,Cecilia;Renaud,Philippe;Schenk,Kurt[OrganicLetters,2009,vol.11,#16,p.3778-3781]

Literature

Title: The 2:1 adducts of (benzoylmethylene)triphenylphosphorane with fumaric and terephthalic acids.

Journal: Acta crystallographica. Section C, Crystal structure communications 20041101

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