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865-47-4,MFCD00012162
Catalog No.:AA0035G0

865-47-4 | Potassium Tert-Butoxide

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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0035G0
Chemical Name:
Potassium Tert-Butoxide
CAS Number:
865-47-4
Molecular Formula:
C4H9KO
Molecular Weight:
112.2120
MDL Number:
MFCD00012162
SMILES:
[O-]C(C)(C)C.[K+]
Properties
Properties
 
BP:
275°C at 760 mmHg  
Form:
Solid  
MP:
256-258 °C (dec.)(lit.)  
Solubility:
Soluble in hexane, toluene, diethyl ether and terahydrofuran.  
Stability:
Moisture Sensitive  
Storage:
Room Temperature;Keep in dry area;Keep container tightly closed;  

Computed Properties
 
Complexity:
29  
Covalently-Bonded Unit Count:
2  
Heavy Atom Count:
6  
Hydrogen Bond Acceptor Count:
1  

Literature

Title: High yielding synthesis of N-ethyl dehydroamino acids.

Journal: Amino acids 20121001

Title: Intramolecular direct dehydrohalide coupling promoted by KO(t)Bu: total synthesis of Amaryllidaceae alkaloids anhydrolycorinone and oxoassoanine.

Journal: Organic letters 20120907

Title: Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes.

Journal: Chemical communications (Cambridge, England) 20120818

Title: Lipase-mediated synthesis of water-soluble plant stanol derivatives in tert-butanol.

Journal: Bioresource technology 20120601

Title: Neocuproine-KOtBu promoted intramolecular cross coupling to approach fused rings.

Journal: Chemical communications (Cambridge, England) 20110921

Title: Mizoroki-heck-type reaction mediated by potassium tert-butoxide.

Journal: Angewandte Chemie (International ed. in English) 20110509

Title: Cross coupling: When is free really free?

Journal: Nature chemistry 20101201

Title: An efficient organocatalytic method for constructing biaryls through aromatic C-H activation.

Journal: Nature chemistry 20101201

Title: Pd-catalyzed arylation of silyl enol ethers of substituted alpha-fluoroketones.

Journal: Organic & biomolecular chemistry 20090421

Title: 3-Aryltetronic acids: efficient preparation and use as precursors for vulpinic acids.

Journal: The Journal of organic chemistry 20090206

Title: Determination of carbamate, phenylurea and phenoxy acid herbicide residues by gas chromatography after potassium tert-butoxide/dimethyl sulphoxide/ethyl iodide derivatization reaction.

Journal: Journal of chromatography. A 20081031

Title: New synthetic routes to optically active alpha-quaternary alpha-aryl amino acid derivatives via the diastereoselective Stevens and Sommelet-Hauser rearrangements.

Journal: Organic & biomolecular chemistry 20081021

Title: Transition metal-free addition of ketones or nitriles to 1,3-dienes.

Journal: Chemical communications (Cambridge, England) 20080207

Title: Palladium-catalyzed cross-coupling reactions of silanolates: a paradigm shift in silicon-based cross-coupling reactions.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060623

Title: Bioassay monitoring of waste PCB samples during chemical destruction treatments.

Journal: Water science and technology : a journal of the International Association on Water Pollution Research 20060101

Title: Chemiluminescence in molecular recognition: base-induced decomposition of optically active dioxetanes bearing a bisnaphthol moiety with a complex of optically active crown ether-potassium tert-butoxide.

Journal: Chemical communications (Cambridge, England) 20050214

Title: Formation of 4-aminopyrimidines via the trimerization of nitriles using focused microwave heating.

Journal: Journal of combinatorial chemistry 20050101

Title: Synthesis of carbazoles via an intramolecular cyclization of 2-(6-substituted 3(Z)-hexen-1,5-diynyl)anilines and their related molecules.

Journal: The Journal of organic chemistry 20040319

Title: Utilizing capillary gas chromatography mass spectrometry to determine 4-benzotrifluoride t-butyl ether as a reaction by-product in fluoxetine synthesized using potassium t-butoxide as base.

Journal: Journal of pharmaceutical and biomedical analysis 20030205

Title: Synthesis and characterization of injectable, water-soluble copolymers of tertiary amine methacrylates and poly(ethylene glycol) containing methacrylates.

Journal: Biomaterials 20021101

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