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87-40-1,MFCD00000588
Catalog No.:AA003FJY

87-40-1 | 2,4,6-Trichloroanisole

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1g
98%(GC)
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$27.00   $19.00
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5g
98%
in stock  
$37.00   $26.00
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25g
98%
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$53.00   $37.00
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100g
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003FJY
Chemical Name:
2,4,6-Trichloroanisole
CAS Number:
87-40-1
Molecular Formula:
C7H5Cl3O
Molecular Weight:
211.4730
MDL Number:
MFCD00000588
SMILES:
COc1c(Cl)cc(cc1Cl)Cl
NSC Number:
35142
Properties
Properties
 
BP:
241.0°C  
Form:
Solid  
MP:
60-62°C(lit.)  
Refractive Index:
1.5510 (estimate)  
Solubility:
benzene: soluble(lit.)  
Storage:
Keep in dry area;2-8℃;  

Computed Properties
 
Complexity:
119  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
11  
Hydrogen Bond Acceptor Count:
1  
Rotatable Bond Count:
1  
XLogP3:
4  

Downstream Synthesis Route

[1]Zerbe;Jage[Brennstoff-Chemie,1935,vol.16,p.88,90][ChemischesZentralblatt,1935,vol.106,#I,p.2806]

[1]Barberetal.[JournalofAppliedChemistry,1953,vol.3,p.409,411]

87-40-1   
trichloromethyl-(2,4,6-trichloro-phenyl)-ether 

[1]Barberetal.[JournalofAppliedChemistry,1953,vol.3,p.409,411]

[1]Waller,StephenC.;He,YouAi;Harlow,GregR.;He,YouQun;Mash,EugeneA.;Halpert,JamesR.[ChemicalResearchinToxicology,1999,vol.12,#8,p.690-699]

[2]Hugounenq[AnnalesdeChimie(Cachan,France),1890,vol.<6>20,p.530,544]

[1]Kohn;Heller[MonatsheftefurChemie,1925,vol.46,p.95]

[2]Hugounenq[AnnalesdeChimie(Cachan,France),1890,vol.<6>20,p.530,544]

Literature

Title: Headspace-multicapillary column-ion mobility spectrometry for the direct analysis of 2,4,6-trichloroanisole in wine and cork samples.

Journal: Journal of chromatography. A 20121123

Title: A framework for identifying characteristic odor compounds in municipal wastewater effluent.

Journal: Water research 20121115

Title: Method development and validation for the determination of 2,4,6-tribromoanisole, 2,4,6-tribromophenol, 2,4,6-trichloroanisole, and 2,4,6-trichlorophenol in various drug products using stir bar sorptive extraction and gas chromatography-tandem mass spectrometry detection.

Journal: Journal of chromatography. A 20121102

Title: Headspace-single drop microextraction with a commercial capillary electrophoresis instrument.

Journal: Electrophoresis 20121001

Title: [Determination of 2,4,6-trichloroanisole in wine by head-space solid phase micro-extraction and gas chromatography-mass spectrometry].

Journal: Wei sheng yan jiu = Journal of hygiene research 20120701

Title: Accurate analysis of trace earthy-musty odorants in water by headspace solid phase microextraction gas chromatography-mass spectrometry.

Journal: Journal of separation science 20120601

Title: The potential of ion mobility spectrometry (IMS) for detection of 2,4,6-trichloroanisole (2,4,6-TCA) in wine.

Journal: Talanta 20120515

Title: Trace level analysis of corky off-flavor compounds: development of a new analytical method based on solid phase extraction and analysis by multidimensional gas chromatography with mass spectrometric detection.

Journal: Journal of chromatography. A 20120224

Title: Concentrations of organochlorine pesticides and 2,4,6-trichloroanisole in cork bark.

Journal: Chemosphere 20120201

Title: Destruction of chloroanisoles by using a hydrogen peroxide activated method and its application to remove chloroanisoles from cork stoppers.

Journal: Journal of agricultural and food chemistry 20111214

Title: Odorous compounds in municipal wastewater effluent and potable water reuse systems.

Journal: Environmental science & technology 20111101

Title: Direct determination of 2,4,6-tricholoroanisole in wines by single-drop ionic liquid microextraction coupled with multicapillary column separation and ion mobility spectrometry detection.

Journal: Journal of chromatography. A 20111021

Title: Determination of 2,4,6-tricholoroanisole in water and wine samples by ionic liquid-based single-drop microextraction and ion mobility spectrometry.

Journal: Analytica chimica acta 20110930

Title: Volatile compounds in samples of cork and also produced by selected fungi.

Journal: Journal of agricultural and food chemistry 20110622

Title: Selectable one-dimensional or two-dimensional gas chromatography-olfactometry/mass spectrometry with preparative fraction collection for analysis of ultra-trace amounts of odor compounds.

Journal: Journal of chromatography. A 20110527

Title: Prolactin induces Jak2 phosphorylation of RUSHY195.

Journal: Molecular and cellular endocrinology 20110516

Title: Development of a cellular biosensor for the detection of 2,4,6-trichloroanisole (TCA).

Journal: Talanta 20110515

Title: Development of a dispersive liquid-liquid microextraction method for the simultaneous determination of the main compounds causing cork taint and Brett character in wines using gas chromatography-tandem mass spectrometry.

Journal: Journal of chromatography. A 20110325

Title: Optimisation of a dispersive liquid-liquid microextraction method for the simultaneous determination of halophenols and haloanisoles in wines.

Journal: Journal of chromatography. A 20101203

Title: Concentrations of viable airborne fungal spores and trichloroanisole in wine cellars.

Journal: International journal of food microbiology 20101115

Title: Identification of a new source of contamination of Quercus sp. oak wood by 2,4,6-trichloroanisole and its impact on the contamination of barrel-aged wines.

Journal: Journal of agricultural and food chemistry 20101013

Title: Sensitive determination of 2,4,6-trichloroanisole in water samples by ultrasound assisted emulsification microextraction prior to gas chromatography-tandem mass spectrometry analysis.

Journal: Talanta 20100615

Title: Ultrasound-assisted emulsification microextraction for determination of 2,4,6-trichloroanisole in wine samples by gas chromatography tandem mass spectrometry.

Journal: Journal of agricultural and food chemistry 20100428

Title: Development of a microwave assisted extraction method for the analysis of 2,4,6-trichloroanisole in cork stoppers by SIDA-SBSE-GC-MS.

Journal: Analytica chimica acta 20100215

Title: Biochemistry and occurrence of o-demethylation in plant metabolism.

Journal: Frontiers in physiology 20100101

Title: Evaluation of three electronic noses for detecting incipient wood decay.

Journal: Sensors (Basel, Switzerland) 20100101

Title: Metal oxide sensors for electronic noses and their application to food analysis.

Journal: Sensors (Basel, Switzerland) 20100101

Title: Sensory screening for large-format natural corks by 'dry soak' testing and its correlation to headspace solid-phase microextraction (SPME) gas chromatography/mass spectrometry (GC/MS) releasable trichloroanisole (TCA) analysis.

Journal: Journal of agricultural and food chemistry 20090909

Title: Ozonation catalyzed by the raw bauxite for the degradation of 2,4,6-trichloroanisole in drinking water.

Journal: Journal of hazardous materials 20090830

Title: Modeling quality of premium spanish red wines from gas chromatography-olfactometry data.

Journal: Journal of agricultural and food chemistry 20090826

Title: Off-odor compounds produced in cork by isolated bacteria and fungi: a gas chromatography-mass spectrometry and gas chromatography-olfactometry study.

Journal: Journal of agricultural and food chemistry 20090826

Title: Catalytic ozonation for degradation of 2, 4, 6-trichloroanisole in drinking water in the presence of gamma-AlOOH.

Journal: Water environment research : a research publication of the Water Environment Federation 20090601

Title: Comparison of two SPME fibers for the extraction of some off-flavor cork-taint compounds in bottled wines investigated by GC-HRMS.

Journal: Analytical and bioanalytical chemistry 20090401

Title: Copper UPD as non-specific adsorption barrier in electrochemical displacement immunosensors.

Journal: Biosensors & bioelectronics 20090315

Title: Biodegradation of 2,4,6-TCA by the white-rot fungus Phlebia radiata is initiated by a phase I (O-demethylation)-phase II (O-conjugation) reactions system: implications for the chlorine cycle.

Journal: Environmental microbiology 20090101

Title: Haloanisole and halophenol contamination in Spanish aged red wines.

Journal: Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment 20090101

Title: Application of robust NiTi-ZrO2-PEG SPME fiber in the determination of haloanisoles in cork stopper samples.

Journal: Analytica chimica acta 20081123

Title: Determination of 2,4,6-trichloroanisole and 2,4,6-tribromoanisole in wine using microextraction in packed syringe and gas chromatography-mass spectrometry.

Journal: Journal of agricultural and food chemistry 20080709

Title: Comparison of stir bar sorptive extraction and solid-phase microextraction to determine halophenols and haloanisoles by gas chromatography-ion trap tandem mass spectrometry.

Journal: Talanta 20080515

Title: Transformation ability of fungi isolated from cork and grape to produce 2,4,6-trichloroanisole from 2,4,6-trichlorophenol.

Journal: Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment 20080301

Title: 1,3,5-Trichloro-2-methoxy-benzene.

Journal: Acta crystallographica. Section E, Structure reports online 20080201

Title: Abstracts of papers presented at the 2008 pittsburgh conference.

Journal: Journal of automated methods & management in chemistry 20080101

Title: Environmental significance of O-demethylation of chloroanisoles by soil bacterial isolates as a mechanism that improves the overall biodegradation of chlorophenols.

Journal: Environmental microbiology 20071001

Title: Multiple headspace solid-phase microextraction for eliminating matrix effect in the simultaneous determination of haloanisoles and volatile phenols in wines.

Journal: Journal of chromatography. A 20070928

Title: Optimisation of a microwave-assisted extraction method for the simultaneous determination of haloanisoles and halophenols in cork stoppers.

Journal: Journal of chromatography. A 20070518

Title: Application of fractional factorial experimental and Box-Behnken designs for optimization of single-drop microextraction of 2,4,6-trichloroanisole and 2,4,6-tribromoanisole from wine samples.

Journal: Journal of chromatography. A 20070504

Title: Fungal strains isolated from cork stoppers and the formation of 2,4,6-trichloroanisole involved in the cork taint of wine.

Journal: Food microbiology 20070501

Title: Analysis for chloroanisoles and chlorophenols in cork by stir bar sorptive extraction and gas chromatography-mass spectrometry.

Journal: Talanta 20070330

Title: Assessment of the matrix effect on the headspace solid-phase microextraction (HS-SPME) analysis of chlorophenols in wines.

Journal: Journal of separation science 20070301

Title: Rapid headspace solid-phase microextraction/gas chromatographic/mass spectrometric assay for the quantitative determination of some of the main odorants causing off-flavours in wine.

Journal: Journal of chromatography. A 20070202

Title: Comparative study of two chromatographic methods for quantifying 2,4,6-trichloranisole in wines.

Journal: Journal of chromatography. A 20070105

Title: Fast and sensitive method to determine chloroanisoles in cork using an internally cooled solid-phase microextraction fiber.

Journal: Journal of chromatography. A 20070105

Title: Automated trace determination of earthy-musty odorous compounds in water samples by on-line purge-and-trap-gas chromatography-mass spectrometry.

Journal: Journal of chromatography. A 20061215

Title: Determination of haloanisols in white wine by immunosorbent solid-phase extraction followed by enzyme-linked immunosorbent assay.

Journal: Journal of agricultural and food chemistry 20061129

Title: Multiple response optimisation based on desirability functions of a microwave-assisted extraction method for the simultaneous determination of chloroanisoles and chlorophenols in oak barrel sawdust.

Journal: Journal of chromatography. A 20061103

Title: Assays on the simultaneous determination and elimination of chloroanisoles and chlorophenols from contaminated cork samples.

Journal: Journal of chromatography. A 20060728

Title: Non-destructive method to determine halophenols and haloanisoles in cork stoppers by headspace sorptive extraction.

Journal: Journal of chromatography. A 20060512

Title: Use of multiple headspace solid-phase microextraction and pervaporation for the determination of off-flavours in wine.

Journal: Journal of chromatography. A 20060421

Title: Determination of 2,4,6-trichloroanisole and 2,4,6-tribromoanisole on ng L-1 to pgL-1 levels in wine by solid-phase microextraction and gas chromatography-high-resolution mass spectrometry.

Journal: Journal of chromatography. A 20060407

Title: Quantification of chloroanisoles in cork using headspace solid-phase microextraction and gas chromatography with electron capture detection.

Journal: Journal of chromatography. A 20060224

Title: Ethanol/Water extraction combined with solid-phase extraction and solid-phase microextraction concentration for the determination of chlorophenols in cork stoppers.

Journal: Journal of agricultural and food chemistry 20060208

Title: Routine analysis of off-flavor compounds in water at sub-part-per-trillion level by large-volume injection GC/MS with programmable temperature vaporizing inlet.

Journal: Water research 20060201

Title: Determination of 2,4,6-trichloroanisole and guaiacol in cork stoppers by pressurised fluid extraction and gas chromatography-mass spectrometry.

Journal: Journal of chromatography. A 20060113

Title: Simultaneous picogram determination of 'earthy-musty' odorous compounds in water using solid-phase microextraction and gas chromatography-mass spectrometry coupled with initial cool programmable temperature vaporizer inlet.

Journal: Journal of chromatography. A 20051209

Title: Highly selective solid-phase extraction and large volume injection for the robust gas chromatography-mass spectrometric analysis of TCA and TBA in wines.

Journal: Journal of chromatography. A 20050930

Title: Migration of contaminants by gas phase transfer from carton board and corrugated board box secondary packaging into foods.

Journal: Food additives and contaminants 20050801

Title: Identification of 2,4,6-trichloroanisole (TCA) causing a musty/muddy off-flavor in sake and its production in rice koji and moromi mash.

Journal: Journal of bioscience and bioengineering 20050801

Title: Detection of 2,4,6-trichloroanisole in chlorinated water at nanogram per litre levels by SPME-GC-ECD.

Journal: Analytical and bioanalytical chemistry 20050501

Title: Determination of odour-causing volatile organic compounds in cork stoppers by multiple headspace solid-phase microextraction.

Journal: Journal of chromatography. A 20050318

Title: Analysis of earthy and musty odors in water samples by solid-phase microextraction coupled with gas chromatography/ion trap mass spectrometry.

Journal: Talanta 20050130

Title: Determination of odorous mixed chloro-bromoanisoles in water by solid-phase micro-extraction and gas chromatography-mass detection.

Journal: Journal of chromatography. A 20050128

Title: Removal of earthy-musty odorants in drinking water by powdered activated carbon.

Journal: Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering 20050101

Title: Purge-and-trap preconcentration system coupled to capillary gas chromatography with atomic emission detection for 2,4,6-trichloroanisole determination in cork stoppers and wines.

Journal: Journal of chromatography. A 20041217

Title: Optimisation of a headspace solid-phase microextraction method for the direct determination of chloroanisoles related to cork taint in red wine.

Journal: Journal of chromatography. A 20041112

Title: Dynamic headspace coupled to perevaporation for the analysis of anisoles in wine by gas chromatography-ion-trap tandem mass spectrometry.

Journal: Journal of chromatography. A 20041112

Title: Determination of chloroanisole compounds in red wine by headspace solid-phase microextraction and gas chromatography-mass spectrometry.

Journal: Journal of chromatography. A 20041015

Title: Analysis of anisoles in wines using pervaporation coupled to gas chromatography-mass spectrometry.

Journal: Journal of chromatography. A 20040917

Title: Isolation and identification of 2-methoxy-3,5-dimethylpyrazine, a potent musty compound from wine corks.

Journal: Journal of agricultural and food chemistry 20040825

Title: Stir bar sorptive extraction for the analysis of wine cork taint.

Journal: Journal of chromatography. A 20040409

Title: Optimization of stir bar sorptive extraction applied to the determination of odorous compounds in drinking water.

Journal: Water science and technology : a journal of the International Association on Water Pollution Research 20040101

Title: Formation and emission of chloroanisoles as indoor pollutants.

Journal: Environmental science and pollution research international 20040101

Title: Immunochemical determination of 2,4,6-trichloroanisole as the responsible agent for the musty odor in foods. 1. Molecular modeling studies for antibody production.

Journal: Journal of agricultural and food chemistry 20030702

Title: Immunochemical determination of 2,4,6-trichloroanisole as the responsible agent for the musty odor in foods. 2. Immunoassay evaluation.

Journal: Journal of agricultural and food chemistry 20030702

Title: Accurate determination of 2,4,6-trichloroanisole in wines at low parts per trillion by solid-phase microextraction followed by GC-ECD.

Journal: Journal of agricultural and food chemistry 20030604

Title: Fast screening method for determining 2,4,6-trichloroanisole in wines using a headspace-mass spectrometry (HS-MS) system and multivariate calibration.

Journal: Analytical and bioanalytical chemistry 20030601

Title: Analysis of off-flavors in the aquatic environment by stir bar sorptive extraction-thermal desorption-capillary GC/MS/olfactometry.

Journal: Analytical and bioanalytical chemistry 20030501

Title: Application of stir bar sorptive extraction for wine analysis.

Journal: Analytical and bioanalytical chemistry 20030401

Title: Determination of 2,4,6-trichloroanisole in wines by headspace solid-phase microextraction and gas chromatography-electron-capture detection.

Journal: Journal of chromatography. A 20021115

Title: Evaluation of an extraction method in the determination of the 2,4,6-trichloroanisole content of tainted cork.

Journal: Journal of chromatography. A 20020412

Title: Application of low-temperature glassy carbon films in solid-phase microextraction.

Journal: Analytical chemistry 20011215

Title: Determination of trace amounts of off-flavor compounds in drinking water by stir bar sorptive extraction and thermal desorption GC-MS.

Journal: The Analyst 20011001

Title: The determination of six taste and odour compounds in water using Ambersorb 572 and high resolution mass spectrometry.

Journal: The Analyst 20010601

Title: Trends of organochlorine compounds in Finnish inland waters. Results of mussel incubation monitoring 1984-1998.

Journal: Environmental science and pollution research international 20010101

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Tags:87-40-1 Molecular Formula|87-40-1 MDL|87-40-1 SMILES|87-40-1 2,4,6-Trichloroanisole