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945-51-7,MFCD00002085
Catalog No.:AA003UDZ

945-51-7 | Diphenyl sulfoxide

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  • Technical Information
  • Properties
  • Literature
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA003UDZ
Chemical Name:
Diphenyl sulfoxide
CAS Number:
945-51-7
Molecular Formula:
C12H10OS
Molecular Weight:
202.2722
MDL Number:
MFCD00002085
SMILES:
O=S(c1ccccc1)c1ccccc1
Properties
Properties
 
BP:
206-208 °C13 mm Hg(lit.)  
Form:
Solid  
MP:
69-71 °C(lit.)  
Refractive Index:
1.6090 (estimate)  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
171  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
14  
Hydrogen Bond Acceptor Count:
2  
Rotatable Bond Count:
2  
XLogP3:
2.1  

Literature

Title: Mechanistic studies on a sulfoxide transfer reaction mediated by diphenyl sulfoxide/triflic anhydride.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120305

Title: Tunable stereoselectivity during sialylation using an N-acetyl-5-N,4-O-oxazolidinone-protected p-toluene 2-thio-sialoside donor with Tf(2)O/Ph(2)SO/TTBPy.

Journal: Carbohydrate research 20110816

Title: Li⁺ selective podand-type fluoroionophore based on a diphenyl sulfoxide derivative bearing two pyrene groups.

Journal: Molecules (Basel, Switzerland) 20110810

Title: Fluorescence emission mechanism and fluorescence properties of ternary Tb(III) complex with diphenyl sulphoxide and bipyridine.

Journal: Luminescence : the journal of biological and chemical luminescence 20110101

Title: Gold-catalyzed oxidative ring expansions and ring cleavages of alkynylcyclopropanes by intermolecular reactions oxidized by diphenylsulfoxide.

Journal: Angewandte Chemie (International ed. in English) 20101217

Title: Investigating the coenzyme specificity of phenylacetone monooxygenase from Thermobifida fusca.

Journal: Applied microbiology and biotechnology 20101101

Title: Calyculins and related marine natural products as serine-threonine protein phosphatase PP1 and PP2A inhibitors and total syntheses of calyculin A, B, and C.

Journal: Marine drugs 20100101

Title: [Study on photoluminescence of 2-(4-chloro-benzoyl)benzoic acid complexes].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20091101

Title: Polystyrene bound oxidovanadium(IV) and dioxidovanadium(V) complexes of histamine derived ligand for the oxidation of methyl phenyl sulfide, diphenyl sulfide and benzoin.

Journal: Dalton transactions (Cambridge, England : 2003) 20090328

Title: Efficient dehydrative sialylation of C-4-aminated sialyl-hemiketal donors with Ph2SO/Tf2O.

Journal: The Journal of organic chemistry 20090220

Title: Photosensitized oxidation of alkyl phenyl sulfoxides. C-S bond cleavage in alkyl phenyl sulfoxide radical cations.

Journal: The Journal of organic chemistry 20080801

Title: Toward prediction of alkane/water partition coefficients.

Journal: Journal of medicinal chemistry 20080710

Title: DNA cleavage by photolysis of aryl sulfoxides.

Journal: Bioorganic & medicinal chemistry letters 20071115

Title: Pyramidal inversion mechanism of simple chiral and achiral sulfoxides: a theoretical study.

Journal: Chirality 20070701

Title: Use of simple docking methods to screen a virtual library for heteroactivators of cytochrome P450 2C9.

Journal: Journal of medicinal chemistry 20070322

Title: On the use of 3,5-O-benzylidene and 3,5-O-(di-tert-butylsilylene)-2-O-benzylarabinothiofuranosides and their sulfoxides as glycosyl donors for the synthesis of beta-arabinofuranosides: importance of the activation method.

Journal: The Journal of organic chemistry 20070302

Title: Microsphere-based protease assays and screening application for lethal factor and factor Xa.

Journal: Cytometry. Part A : the journal of the International Society for Analytical Cytology 20060501

Title: Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane.

Journal: Organic letters 20060302

Title: Synthesis and spectroscopic behavior of highly luminescent Eu(3+)-dibenzoylmethanate (DBM) complexes with sulfoxide ligands.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20050901

Title: Photosensitized oxygenation of sulfides within an amphiphilic dendrimer containing a benzophenone core.

Journal: The journal of physical chemistry. B 20050512

Title: Calculating virtual log P in the alkane/water system (log P(N)(alk)) and its derived parameters deltalog P(N)(oct-alk) and log D(pH)(alk).

Journal: Journal of medicinal chemistry 20050505

Title: A facile one-pot benzylation of sodium enolates using trifluoromethanesulfonic anhydride and diphenyl sulfoxide.

Journal: Chemical & pharmaceutical bulletin 20050501

Title: Synthesis, characterization, and photochemical behavior of {Ru(arene)}2+ derivatives of alpha-[PW11O39]7-: an organometallic way to ruthenium-substituted heteropolytungstates.

Journal: Inorganic chemistry 20050418

Title: Determination of the sulphoxides and sulphones of three simple sulphides in rat urine: effects of phenobarbitone, beta-naphthoflavone and methimazole.

Journal: Biomedical chromatography : BMC 20050101

Title: [Influence of Pr3+ on Eu3+ luminescence in three component complex system of Eu(ClO4)3-DPSO-phen].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20041101

Title: Hammett correlations in the photosensitized oxidation of 4-substituted thioanisoles.

Journal: The Journal of organic chemistry 20040206

Title: Ph2SO/Tf2O: a powerful promotor system in chemoselective glycosylations using thioglycosides.

Journal: Organic letters 20030501

Title: [Fluorescence enhancement character of terbium perchlorate and thulium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20021201

Title: HPLC analysis of 4-chlorophenyl methyl sulphide and diphenyl sulphide and their corresponding sulphoxides and sulphones in rat liver microsomes.

Journal: Journal of pharmaceutical and biomedical analysis 20020101

Title: Novel pyrimidine-bridged platinum(II) complexes: multinuclear magnetic resonance spectroscopy and crystal structures of (NR4)2[(PtCl3)2(mu-pyrimidine)] and cis- and trans-[Pt(R2SO)Cl2]2(mu-pyrimidine).

Journal: Inorganic chemistry 20010924

Title: Total synthesis of natural dysidiolide.

Journal: The Journal of organic chemistry 20010223

Title: Diarylsulfones, a new chemical class of nonnucleoside antiviral inhibitors of human immunodeficiency virus type 1 reverse transcriptase.

Journal: Antimicrobial agents and chemotherapy 19930401

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