Home Aldehydes 13679-70-4
13679-70-4,MFCD00005434
Catalog No.:AA0012AU

13679-70-4 | 5-Methyl-2-thiophenecarboxaldehyde

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Purity
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5g
98%
in stock  
$8.00   $6.00
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10g
98%
in stock  
$11.00   $8.00
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25g
98%
in stock  
$24.00   $17.00
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100g
98%
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$56.00   $39.00
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA0012AU
Chemical Name:
5-Methyl-2-thiophenecarboxaldehyde
CAS Number:
13679-70-4
Molecular Formula:
C6H6OS
Molecular Weight:
126.1762
MDL Number:
MFCD00005434
SMILES:
Cc1ccc(s1)C=O
NSC Number:
87542
FEMA Number:
3209
Properties
Properties
 
BP:
218.3°C at 760 mmHg  
Form:
Liquid  
Refractive Index:
n20/D 1.583(lit.)  
Solubility:
Soluble in ether and ethanol.  
Stability:
Air Sensitive  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
92.5  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
8  
Hydrogen Bond Acceptor Count:
2  
Rotatable Bond Count:
1  
XLogP3:
1.8  

Upstream Synthesis Route

[1]TetrahedronLetters,2012,vol.53,#9,p.1173-1176

[2]DyesandPigments,2014,vol.106,p.154-160

[3]Patent:EP1555257,2005,A1,.Locationinpatent:Page/Pagecolumn25-26

[4]PharmaceuticalChemistryJournal,1989,vol.23,#7,p.592-596

[5]Khimiko-FarmatsevticheskiiZhurnal,1989,vol.23,#7,p.840-843

[6]JournalofOrganicChemistry,2010,vol.75,#4,p.1047-1060

[7]JournalofMaterialsChemistry,2007,vol.17,#12,p.1166-1177

[8]JournaloftheAmericanChemicalSociety,1953,vol.75,p.989

[9]BioorganicandMedicinalChemistry,2004,vol.12,#5,p.1221-1230

[10]AdvancedSynthesisandCatalysis,2010,vol.352,#13,p.2116-2120

[11]DyesandPigments,2011,vol.91,#3,p.404-412

[12]AppliedOrganometallicChemistry,2013,vol.27,#5,p.283-289

[13]ChemicalCommunications,2015,vol.51,#18,p.3842-3845

[1]Molecules,2018,vol.23,#2,

[1]TetrahedronLetters,2018,vol.59,#32,p.3147-3150

[1]RSCAdvances,2015,vol.5,#111,p.91594-91600

[1]Patent:US5412106,1995,A,

Downstream Synthesis Route

[1]Locationinpatent:experimentalpartTanaka,Shota;Tanaka,Daiki;Sugie,Atsushi;Mori,Atsunori[TetrahedronLetters,2012,vol.53,#9,p.1173-1176]

[2]Jin,Huiyi;Li,Xianggao;Tan,Tingfeng;Wang,Shirong;Xiao,Yin;Tian,Jianhua[DyesandPigments,2014,vol.106,p.154-160]

[3]CurrentPatentAssignee:KUMIAICHEMICALINDUSTRYCOLTD-EP1555257,2005,A1Locationinpatent:Page/Pagecolumn25-26

[4]Surikova,T.P.;Zakharova,V.D.;Mochalov,S.S.;Shabarov,Yu.S.[PharmaceuticalChemistryJournal,1989,vol.23,#7,p.592-596][Khimiko-FarmatsevticheskiiZhurnal,1989,vol.23,#7,p.840-843]

[5]Liegault,Benoit;Petrov,Ivan;Gorelsky,SergeI.;Fagnou,Keith[JournalofOrganicChemistry,2010,vol.75,#4,p.1047-1060]

[6]Dufresne,Stephane;Bourgeaux,Marie;Skene[JournalofMaterialsChemistry,2007,vol.17,#12,p.1166-1177]

[7]Campaigne;Archer[JournaloftheAmericanChemicalSociety,1953,vol.75,p.989]

[8]RajenderKumar;Raju;SatishGoud;Sailaja;Sarma;OmReddy;PremKumar;KrishnaReddy;Suresh;Hegde,Pragathi[BioorganicandMedicinalChemistry,2004,vol.12,#5,p.1221-1230]

[9]Locationinpatent:schemeortableRene,Olivier;Fagnou,Keith[AdvancedSynthesisandCatalysis,2010,vol.352,#13,p.2116-2120]

[10]Locationinpatent:schemeortableZhou,Weiping;Zhao,Bin;Shen,Ping;Jiang,Shenghui;Huang,Hongduan;Deng,Lijun;Tan,Songting[DyesandPigments,2011,vol.91,#3,p.404-412]

[11]Aydin,A.Ebru[AppliedOrganometallicChemistry,2013,vol.27,#5,p.283-289]

[12]Zhang,Sheng;Yu,Xiaoqiang;Feng,Xiujuan;Yamamoto,Yoshinori;Bao,Ming[ChemicalCommunications,2015,vol.51,#18,p.3842-3845]

[13]CurrentPatentAssignee:WUHANZHIJINGCHENGPHARMACEUTICALTECH-CN112574169,2021,ALocationinpatent:Paragraph0028-0041

[1]Patent:US2769813,1951,

[1]CurrentPatentAssignee:FABPHARMASAS-WO2011/61214,2011,A1Locationinpatent:Page/Pagecolumn95

[2]Moradpour,Alec[JournaloftheChemicalSociety.PerkintransactionsI,1993,#1,p.7-8]

[3]Trahanovsky,WalterS.;Miller,DeborahLouise;Wang,Yili[JournalofOrganicChemistry,1997,vol.62,#26,p.8980-8986]

[4]Noe;Weigand;Pirker[MonatsheftefurChemie,1996,vol.127,#10,p.1081-1097]

[5]Boulos,John;Jakubik,Jan;Randakova,Alena;Avila,Cristina[JournalofHeterocyclicChemistry,2013,vol.50,#6,p.1363-1367]

[6]Randáková,Alena;Nelic,Dominik;Ungerová,Dana;Nwokoye,Peter;Su,Qiwen;Doležal,Vladimír;El-Fakahany,EsamE.;Boulos,John;Jakubík,Jan[BritishJournalofPharmacology,2020,vol.177,#9,p.2073-2089]

[7]CurrentPatentAssignee:BARRYUNIV-WO2020/181035,2020,A1Locationinpatent:Paragraph0060;0073;0076;00106

[8]Stratton,ThomasP.;Perryman,AlexanderL.;Vilchèze,Catherine;Russo,Riccardo;Li,Shao-Gang;Patel,JimmyS.;Singleton,Eric;Ekins,Sean;Connell,Nancy;Jacobs,WilliamR.;Freundlich,JoelS.[ACSMedicinalChemistryLetters,2017,vol.8,#10,p.1099-1104]

[9]Emerson;Patrick[JournalofOrganicChemistry,1949,vol.14,p.790,795]

[10]Borghi,R.;Cremonini,M.A.;Lunazzi,L.;Placucci,G.;Macciantelli,D.[JournalofOrganicChemistry,1991,vol.56,#22,p.6337-6341]

[11]Hofmann,Thomas;Schieberle,Peter[JournalofAgriculturalandFoodChemistry,1997,vol.45,#3,p.898-906]

[12]Wu,Xiaofeng;Liu,Jianke;Li,Xiaohong;Zanotti-Gerosa,Antonio;Hancock,Fred;Vinci,Daniele;Ruan,Jiwu;Xiao,Jianliang[AngewandteChemie-InternationalEdition,2006,vol.45,#40,p.6718-6722]

[13]CurrentPatentAssignee:PHARMACONFORSCHUNGUNDBERATUNG-US5929253,1999,A

[14]Nikolaienko,Pavlo;Pluta,Roman;Rueping,Magnus[Chemistry-AEuropeanJournal,2014,vol.20,#32,p.9867-9870]

[15]Zhang,Sheng;Yu,Xiaoqiang;Feng,Xiujuan;Yamamoto,Yoshinori;Bao,Ming[ChemicalCommunications,2015,vol.51,#18,p.3842-3845]

13679-70-4    495-69-2   
(4Z)-4-((5-methylthiophen-2-yl)methylene)-2-phenyloxazol-5(4H)-one 

[1]Locationinpatent:experimentalpartRostami,Mahbubeh;Khosropour,Ahmadreza;Mirkhani,Valiollah;Moghadam,Majid;Tangestaninejad,Shahram;Mohammadpoor-Baltork,Iraj[AppliedCatalysisA:General,2011,vol.397,#1-2,p.27-34]

[2]Locationinpatent:experimentalpartRostami,Mahboubeh;Khosropour,AhmadR.;Mirkhani,Valiollah;Mohammadpoor-Baltork,Iraj;Moghadam,Majid;Tangestaninejad,Shahram[ComptesRendusChimie,2011,vol.14,#10,p.869-877]

[3]Cativiela,C.;DiazdeVillegas,M.D.;Mayoral,J.A.;Melendez,E.[Synthesis,1983,#11,p.899-902]

[4]Kiyani,Hamzeh;Aslanpour,Shiva[Heterocycles,2018,vol.96,#2,p.297-303]

13679-70-4    153-78-6   
2-(5-Methyl-2-thienylmethylidenamino)fluoren 

[1]ZeitschriftfurNaturforschung,TeilB:AnorganischeChemie,OrganischeChemie,1986,vol.41,p.751-761

Literature

Title: 1,1'-(2,5-Dimethyl-thio-phene-3,4-di-yl)diethanone.

Journal: Acta crystallographica. Section E, Structure reports online 20110901

Title: 1-(2-Hydr-oxy-5-methyl-phen-yl)-3-(3-methylthiophen-2-yl)prop-2-en-1-one.

Journal: Acta crystallographica. Section E, Structure reports online 20100601

Title: Investigation of the aroma-active compounds formed in the maillard reaction between glutathione and reducing sugars.

Journal: Journal of agricultural and food chemistry 20100310

Title: 2-Methyl-3-(5-methyl-2-thien-yl)-5-phenyl-perhydro-pyrrolo[3,4-d]isoxazole-4,6-dione.

Journal: Acta crystallographica. Section E, Structure reports online 20090401

Title: N-[(E)-(5-Methyl-thio-phen-2-yl)methyl-idene]-1H-1,2,4-triazol-3-amine.

Journal: Acta crystallographica. Section E, Structure reports online 20090101

Title: Prediction of genotoxicity of chemical compounds by statistical learning methods.

Journal: Chemical research in toxicology 20050601

Title: GC-olfactometric characterization of aroma volatiles from the thermal degradation of thiamin in model orange juice.

Journal: Journal of agricultural and food chemistry 20030507

Title: DavutAvcı, et al. 5-Methyl-2-thiophenecarboxaldehyde: Experimental and TD/DFT study. Journal of Molecular Structure. 2018 Dec 15; 1174: 52-59.

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