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89343-06-6,MFCD00075452
Catalog No.:AA0034UL

89343-06-6 | (Triisopropylsilyl)acetylene

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1g
97%
in stock  
$10.00   $7.00
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5g
97%
in stock  
$13.00   $9.00
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10g
97%
in stock  
$19.00   $13.00
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25g
97%
in stock  
$39.00   $27.00
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50g
97%
in stock  
$75.00   $52.00
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100g
97%
in stock  
$132.00   $92.00
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250g
97%
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$239.00   $167.00
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  • Technical Information
  • Properties
  • Literature
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0034UL
Chemical Name:
(Triisopropylsilyl)acetylene
CAS Number:
89343-06-6
Molecular Formula:
C11H22Si
Molecular Weight:
182.3779
MDL Number:
MFCD00075452
SMILES:
CC([Si](C(C)C)(C(C)C)C#C)C
Properties
Properties
 
BP:
230.746 °C at 760 mmHg  
Form:
Liquid  
MP:
50-51°C  
Refractive Index:
n20/D 1.4527(lit.)  
Solubility:
Miscible with organic solvents.  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
159  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
12  
Rotatable Bond Count:
4  

Literature

Title: Substituent effects on the electronic characteristics of pentacene derivatives for organic electronic devices: dioxolane-substituted pentacene derivatives with triisopropylsilylethynyl functional groups.

Journal: Journal of the American Chemical Society 20120829

Title: Unexpected formation of a cyclic vinylene sulfate in the synthesis of ethynyl-substituted acenes.

Journal: Chemical communications (Cambridge, England) 20120707

Title: Highly chemoselective nickel-catalyzed three-component cross-trimerization between two distinct terminal alkynes and an internal alkyne.

Journal: Organic letters 20110107

Title: Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes.

Journal: Chemical communications (Cambridge, England) 20100928

Title: A stable heptacene derivative substituted with electron-deficient trifluoromethylphenyl and triisopropylsilylethynyl groups.

Journal: Organic letters 20100806

Title: (Butane-1,3-diyne-1,4-diyl)bis-(tri-isopropyl-silane).

Journal: Acta crystallographica. Section E, Structure reports online 20100801

Title: Efficient preparation of photoswitchable dithienylethene-linker-conjugates by palladium-catalyzed coupling reactions of terminal alkynes with thienyl chlorides and other aryl halides.

Journal: Chemistry, an Asian journal 20100503

Title: Electronic properties of pentacene versus triisopropylsilylethynyl-substituted pentacene: environment-dependent effects of the silyl substituent.

Journal: Journal of the American Chemical Society 20100120

Title: Nickel-catalyzed, regio- and stereoselective hydroalkynylation of methylenecyclopropanes with retention of the cyclopropane ring, leading to the synthesis of 1-methyl-1-alkynylcyclopropanes.

Journal: Journal of the American Chemical Society 20090415

Title: Nickel-catalyzed highly regio- and stereoselective cross-trimerization between triisopropylsilylacetylene and internal alkynes leading to 1,3-diene-5-ynes.

Journal: Journal of the American Chemical Society 20090311

Title: Nickel-catalyzed regioselective hydroalkynylation of styrenes: improved catalyst system, reaction scope, and mechanism.

Journal: Organic letters 20090205

Title: Wiring terpyridine: approaches to alkynylthienyl 2,2':6',2''-terpyridines.

Journal: Dalton transactions (Cambridge, England : 2003) 20081221

Title: Rhodium-catalyzed asymmetric ring-opening alkynylation of azabenzonorbornadienes.

Journal: Organic letters 20080918

Title: Rhodium-catalyzed (E)-selective cross-dimerization of terminal alkynes.

Journal: Chemical communications (Cambridge, England) 20080807

Title: Nickel-catalyzed addition of C-H bonds of terminal alkynes to 1,3-dienes and styrenes.

Journal: Journal of the American Chemical Society 20080423

Title: Synthesis of highly soluble and oxidatively stable tetraceno[2,3-b]thiophenes and pentacenes.

Journal: The Journal of organic chemistry 20070817

Title: Palladium-catalyzed selective cross-addition of triisopropylsilylacetylene to internal and terminal unactivated alkynes.

Journal: Organic letters 20070719

Title: Synthetic chlorins bearing auxochromes at the 3- and 13-positions.

Journal: The Journal of organic chemistry 20060526

Title: Structurally characterized hetero-oligopolyphenylenes: synthetic advances toward next-generation heterosuperbenzenes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060403

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Tags:89343-06-6 Molecular Formula|89343-06-6 MDL|89343-06-6 SMILES|89343-06-6 (Triisopropylsilyl)acetylene