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4731-53-7,MFCD00015298
Catalog No.:AA0035OR

4731-53-7 | Trioctylphosphine

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Purity
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1g
95%
in stock  
$29.00   $20.00
- +
5g
95%
in stock  
$54.00   $38.00
- +
25g
95%
in stock  
$128.00   $90.00
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100g
min. 97% TOP
in stock  
$227.00   $159.00
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500g
min. 97% TOP
in stock  
$708.00   $496.00
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  • Technical Information
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0035OR
Chemical Name:
Trioctylphosphine
CAS Number:
4731-53-7
Molecular Formula:
C24H51P
Molecular Weight:
370.6355
MDL Number:
MFCD00015298
SMILES:
CCCCCCCCP(CCCCCCCC)CCCCCCCC
NSC Number:
102529
Properties
Properties
 
BP:
284-291 °C50 mm Hg(lit.)  
Form:
Solid  
MP:
30°C  
Refractive Index:
n20/D 1.468(lit.)  
Stability:
Air Sensitive  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
188  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
25  
Rotatable Bond Count:
21  
XLogP3:
10.2  

Literature

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Title: Unintended phosphorus doping of nickel nanoparticles during synthesis with TOP: a discovery through structural analysis.

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Journal: Physical chemistry chemical physics : PCCP 20120907

Title: Photoluminescent enhancement of CdSe/Cd(1-x) Zn(x)S quantum dots by hexadecylamine at room temperature.

Journal: Journal of nanoscience and nanotechnology 20120901

Title: Carbonate, acetate and phenolate phosphonium salts as catalysts in transesterification reactions for the synthesis of non-symmetric dialkyl carbonates.

Journal: Organic & biomolecular chemistry 20120828

Title: Hollow-fiber liquid phase microextraction for lignin pyrolysis acids in aerosol samples and gas chromatography-mass spectrometry analysis.

Journal: Journal of chromatography. A 20120803

Title: Molecular control of the nanoscale: effect of phosphine-chalcogenide reactivity on CdS-CdSe nanocrystal composition and morphology.

Journal: ACS nano 20120626

Title: Nanopatterned cadmium selenide Langmuir-Blodgett platform for leukemia detection.

Journal: Analytical chemistry 20120403

Title: Influence of the coordination mode in [Ni{RC(S)NP(S)(OiPr)2}2] for the formation of nickel-containing nanoparticles.

Journal: Dalton transactions (Cambridge, England : 2003) 20120227

Title: n-Type nanostructured thermoelectric materials prepared from chemically synthesized ultrathin Bi2Te3 nanoplates.

Journal: Nano letters 20120208

Title: A facile synthesis of MPd (M = Co, Cu) nanoparticles and their catalysis for formic acid oxidation.

Journal: Nano letters 20120208

Title: Fluorescent-magnetic dual-encoded nanospheres: a promising tool for fast-simultaneous-addressable high-throughput analysis.

Journal: Nanotechnology 20120127

Title: Size-tunable, hexagonal plate-like Cu3P and Janus-like Cu-Cu3P nanocrystals.

Journal: ACS nano 20120124

Title: Synthesis, alignment, and magnetic properties of monodisperse nickel nanocubes.

Journal: Journal of the American Chemical Society 20120118

Title: Noninjection facile synthesis of Gram-scale highly luminescent CdSe multipod nanocrystals.

Journal: Inorganic chemistry 20120102

Title: Contact printing of colloidal nanocrystal thin films for hybrid organic/quantum dot optoelectronic devices.

Journal: Nano reviews 20120101

Title: Alkyltrioctylphosphonium chloride ionic liquids: synthesis and physicochemical properties.

Journal: Dalton transactions (Cambridge, England : 2003) 20111221

Title: A precursor-limited nanoparticle coalescence pathway for tuning the thickness of laterally-uniform colloidal nanosheets: the case of SnSe.

Journal: ACS nano 20111122

Title: Phase-selective synthesis of nickel phosphide in high-boiling solvent for all-solid-state lithium secondary batteries.

Journal: Inorganic chemistry 20111107

Title: Surfactant effects on efficiency enhancement of infrared-to-visible upconversion emissions of NaYF4:Yb-Er.

Journal: ACS applied materials & interfaces 20111001

Title: Catalytic hydrolysis of ammonia borane via cobalt palladium nanoparticles.

Journal: ACS nano 20110823

Title: Biokinetics and in vivo distribution behaviours of silica-coated cadmium selenide quantum dots.

Journal: Biological trace element research 20110801

Title: Ternary cobalt-iron phosphide nanocrystals with controlled compositions, properties, and morphologies from nanorods and nanorice to split nanostructures.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20110516

Title: Growth and stability of ZnTe magic-size nanocrystals.

Journal: Small (Weinheim an der Bergstrasse, Germany) 20110509

Title: Synthesis and characterization of lead selenide nanocrystal quantum dots and wires.

Journal: Journal of nanoscience and nanotechnology 20110501

Title: Surfactant-induced postsynthetic modulation of Pd nanoparticle crystallinity.

Journal: Nano letters 20110413

Title: Continuous synthesis of CdSe(x)Te(1-x) nanocrystals: chemical composition gradient and single-step capping.

Journal: Journal of colloid and interface science 20110401

Title: Size-tunable, bright, and stable PbS quantum dots: a surface chemistry study.

Journal: ACS nano 20110322

Title: A dynamic covalent, luminescent metallopolymer that undergoes sol-to-gel transition on temperature rise.

Journal: Journal of the American Chemical Society 20110309

Title: Capillary electrophoretic separation of nanoparticles.

Journal: Analytical and bioanalytical chemistry 20110301

Title: Phase-selective chemical extraction of selenium and sulfur from nanoscale metal chalcogenides: a general strategy for synthesis, purification, and phase targeting.

Journal: Journal of the American Chemical Society 20110209

Title: A surfactant-free recipe for shape-controlled synthesis of CdSe nanocrystals.

Journal: Nanotechnology 20110128

Title: Problems and challenges in the development and validation of human cell-based assays to determine nanoparticle-induced immunomodulatory effects.

Journal: Particle and fibre toxicology 20110101

Title: Conjugated Quantum Dots Inhibit the Amyloid β (1-42) Fibrillation Process.

Journal: International journal of Alzheimer's disease 20110101

Title: Nanotherapeutics Using an HIV-1 Poly A and Transactivator of the HIV-1 LTR-(TAR-) Specific siRNA.

Journal: Pathology research international 20110101

Title: High-quality reduced graphene oxide-nanocrystalline platinum hybrid materials prepared by simultaneous co-reduction of graphene oxide and chloroplatinic acid.

Journal: Nanoscale research letters 20110101

Title: Novel hybrid organic/inorganic 2D quasiperiodic PC: from diffraction pattern to vertical light extraction.

Journal: Nanoscale research letters 20110101

Title: Inorganic-organic hybrid nanomaterials for therapeutic and diagnostic imaging applications.

Journal: International journal of molecular sciences 20110101

Title: Rational design of the gram-scale synthesis of nearly monodisperse semiconductor nanocrystals.

Journal: Nanoscale research letters 20110101

Title: Mitigation of quantum dot cytotoxicity by microencapsulation.

Journal: PloS one 20110101

Title: Entrapment in phospholipid vesicles quenches photoactivity of quantum dots.

Journal: International journal of nanomedicine 20110101

Title: ZnS, CdS and HgS nanoparticles via alkyl-phenyl dithiocarbamate complexes as single source precursors.

Journal: International journal of molecular sciences 20110101

Title: Recognition-mediated assembly of quantum dot polymer conjugates with controlled morphology.

Journal: International journal of molecular sciences 20110101

Title: Anisotropic nanomaterials: structure, growth, assembly, and functions.

Journal: Nano reviews 20110101

Title: Synthesis and characterization of hybrid nanostructures.

Journal: Nano reviews 20110101

Title: Precursor conversion kinetics and the nucleation of cadmium selenide nanocrystals.

Journal: Journal of the American Chemical Society 20101229

Title: Size- and shape-controlled synthesis of ZnSe nanocrystals using SeO2 as selenium precursor.

Journal: Dalton transactions (Cambridge, England : 2003) 20101221

Title: Synthesis and magnetic properties of Gd doped EuS nanocrystals with enhanced Curie temperatures.

Journal: Journal of the American Chemical Society 20101117

Title: Oxidation does not (always) kill reactivity of transition metals: solution-phase conversion of nanoscale transition metal oxides to phosphides and sulfides.

Journal: Journal of the American Chemical Society 20101117

Title: Synthesis and self-assembly of monodisperse Co(x)Ni(100-x) (x=50,80) colloidal nanoparticles by homogenous nucleation.

Journal: Journal of colloid and interface science 20101115

Title: Single-crystal colloidal nanosheets of GeS and GeSe.

Journal: Journal of the American Chemical Society 20101103

Title: Controlled synthesis and characterization of ZnSe quantum dots.

Journal: Journal of nanoscience and nanotechnology 20101101

Title: Mysteries of TOPSe revealed: insights into quantum dot nucleation.

Journal: Journal of the American Chemical Society 20100818

Title: Preparation of anisotropic transition metal phosphide nanocrystals: the case of nickel phosphide nanoplatelets, nanorods, and nanowires.

Journal: Journal of nanoscience and nanotechnology 20100801

Title: Tuning the emission of CdSe quantum dots by controlled trap enhancement.

Journal: Langmuir : the ACS journal of surfaces and colloids 20100706

Title: Low temperature synthesis of ZnS and CdZnS shells on CdSe quantum dots.

Journal: Nanotechnology 20100625

Title: Synthesis and characterization of cadmium phosphide quantum dots emitting in the visible red to near-infrared.

Journal: Journal of the American Chemical Society 20100428

Title: Synthesis of quaternary chalcogenide nanocrystals: stannite Cu(2)Zn(x)Sn(y)Se(1+x+2y).

Journal: Journal of the American Chemical Society 20100407

Title: Role of magic-sized clusters in the synthesis of CdSe nanorods.

Journal: ACS nano 20100323

Title: Synthesis, structures, and multinuclear NMR spectra of tin(II) and lead(II) complexes of tellurium-containing imidodiphosphinate ligands: preparation of two morphologies of phase-pure PbTe from a single-source precursor.

Journal: Inorganic chemistry 20100201

Title: A nonaqueous approach to the preparation of iron phosphide nanowires.

Journal: Nanoscale research letters 20100101

Title: Collision-induced dissociation of II-VI semiconductor nanocrystal precursors, Cd2+ and Zn2+ complexes with trioctylphosphine oxide, sulfide, and selenide.

Journal: The journal of physical chemistry. A 20090903

Title: Control of phase in phosphide nanoparticles produced by metal nanoparticle transformation: Fe2P and FeP.

Journal: ACS nano 20090825

Title: A single-step synthesis and the kinetic mechanism for monodisperse and hexagonal-phase NaYF4:Yb, Er upconversion nanophosphors.

Journal: Nanotechnology 20090708

Title: Chemical synthesis of Bi(0.5)Sb(1.5)Te3 nanocrystals and their surface oxidation properties.

Journal: ACS applied materials & interfaces 20090601

Title: Surface chemistry and photophysical properties of a diacetylene-peptide derivative capped quantum dots Langmuir monolayer.

Journal: Colloids and surfaces. B, Biointerfaces 20090501

Title: Cytotoxic effects of CdSe quantum dots on maturation of mouse oocytes, fertilization, and fetal development.

Journal: International journal of molecular sciences 20090501

Title: Electrogenerated chemiluminescence from PbS quantum dots.

Journal: Nano letters 20090201

Title: Natural organic matter-mediated phase transfer of quantum dots in the aquatic environment.

Journal: Environmental science & technology 20090201

Title: Quantum dots for live cell and in vivo imaging.

Journal: International journal of molecular sciences 20090201

Title: Synthesis of Monodisperse Nanocrystals via Microreaction: Open-to-Air Synthesis with Oleylamine as a Coligand.

Journal: Nanoscale research letters 20090101

Title: Nanoparticle thin films for gas sensors prepared by matrix assisted pulsed laser evaporation.

Journal: Sensors (Basel, Switzerland) 20090101

Title: Colloidal chemical synthesis and formation kinetics of uniformly sized nanocrystals of metals, oxides, and chalcogenides.

Journal: Accounts of chemical research 20081201

Title: Surface chemistry of colloidal PbSe nanocrystals.

Journal: Journal of the American Chemical Society 20081112

Title: Dependence of luminescence efficiency of cdse quantum dots on chemical environments.

Journal: Journal of nanoscience and nanotechnology 20081101

Title: Ruthenium-catalyzed stereoselective anti-Markovnikov-addition of thioamides to alkynes.

Journal: Organic letters 20081016

Title: Preparation and characterization of highly fluorescent, glutathione-coated near infrared quantum dots for in vivo fluorescence imaging.

Journal: International journal of molecular sciences 20081001

Title: Reaction chemistry and ligand exchange at cadmium-selenide nanocrystal surfaces.

Journal: Journal of the American Chemical Society 20080917

Title: Optical characteristics of CdSe quantum dots depending on growth conditions and surface passivation.

Journal: Journal of nanoscience and nanotechnology 20080901

Title: Time-dependent photoluminescence spectroscopy as a tool to measure the ligand exchange kinetics on a quantum dot surface.

Journal: ACS nano 20080801

Title: Shape control of PbS nanocrystals using multiple surfactants.

Journal: Nanotechnology 20080730

Title: Synthesis of cadmium telluride quantum wires and the similarity of their effective band gaps to those of equidiameter cadmium telluride quantum dots.

Journal: Journal of the American Chemical Society 20080625

Title: ZnSe colloidal nanoparticles synthesized by solvothermal method in the presence of ZrCl4.

Journal: Journal of colloid and interface science 20080615

Title: Attenuated total reflection infrared studies of oleate and trioctylphosphine oxide ligand adsorption and exchange reactions on CdS quantum dot films.

Journal: Langmuir : the ACS journal of surfaces and colloids 20080415

Title: 2D self-bundled CdS nanorods with micrometer dimension in the absence of an external directing process.

Journal: ACS nano 20080401

Title: Template-assisted synthesis of shape-controlled Rh2P nanocrystals.

Journal: Inorganic chemistry 20080121

Title: Facile Phosphine-Free Synthesis of CdSe/ZnS Core/Shell Nanocrystals Without Precursor Injection.

Journal: Nanoscale research letters 20080101

Title: Fluorescence enhancement of CdSe Q-Dots with intense femtosecond laser irradiation.

Journal: Journal of fluorescence 20071101

Title: Quantum mazes: luminescent labyrinthine semiconductor nanocrystals having a narrow emission spectrum.

Journal: ACS nano 20071101

Title: Ligand-dependent particle size control of PbSe quantum dots.

Journal: Journal of colloid and interface science 20070601

Title: Direct precursor conversion reaction for densely packed Ag2S nanocrystal thin films.

Journal: Langmuir : the ACS journal of surfaces and colloids 20070227

Title: Formation of hollow Ni2p nanoparticles based on the nanoscale Kirkendall effect.

Journal: Inorganic chemistry 20070122

Title: Mechanistic study of precursor evolution in colloidal group II-VI semiconductor nanocrystal synthesis.

Journal: Journal of the American Chemical Society 20070117

Title: Side chain mediated electronic contact between a tetrahydro-4H-thiopyran-4-ylidene-appended polythiophene and CdTe quantum dots.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20061025

Title: Magnetic properties of lanthanide chalcogenide semiconducting nanoparticles.

Journal: Journal of the American Chemical Society 20060830

Title: Solid state NMR studies of photoluminescent cadmium chalcogenide nanoparticles.

Journal: Physical chemistry chemical physics : PCCP 20060814

Title: High yield solution-liquid-solid synthesis of germanium nanowires.

Journal: Journal of the American Chemical Society 20051116

Title: Phosphine-free synthesis of CdSe nanocrystals.

Journal: The journal of physical chemistry. B 20051110

Title: Photoelectron spectroscopic investigations of chemical bonding in organically stabilized PbS nanocrystals.

Journal: The journal of physical chemistry. B 20050922

Title: A new route to zinc-blende CdSe nanocrystals: mechanism and synthesis.

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Title: Shape and size control of Ag2Se nanocrystals from a single precursor [(Ph3P)3Ag2(SeC{O}Ph)2].

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Journal: Nano letters 20050701

Title: Generalized synthesis of metal phosphide nanorods via thermal decomposition of continuously delivered metal-phosphine complexes using a syringe pump.

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Title: Ligand effects on optical properties of CdSe nanocrystals.

Journal: The journal of physical chemistry. B 20050421

Title: Synthesis of spherical silver nanoparticles by digestive ripening, stabilization with various agents, and their 3-D and 2-D superlattice formation.

Journal: Journal of colloid and interface science 20050415

Title: Colloidal CdSe nanocrystals from tri-n-octylphosphine: Part 1: growth and optical properties from polar and non-polar solvents.

Journal: Journal of nanoscience and nanotechnology 20050401

Title: Colloidal CdSe nanocrystals from tri-n-octylphosphine: Part II: control of growth rate for high quality and large-scale production by tuning Cd-to-Se stoichiometry.

Journal: Journal of nanoscience and nanotechnology 20050401

Title: Sequential synthesis of type II colloidal CdTe/CdSe core-shell nanocrystals.

Journal: Small (Weinheim an der Bergstrasse, Germany) 20050301

Title: Effect of reaction media on the growth and photoluminescence of colloidal CdSe nanocrystals.

Journal: Langmuir : the ACS journal of surfaces and colloids 20041207

Title: Solution-phase synthesis of single-crystalline iron phosphide nanorods/nanowires.

Journal: Journal of the American Chemical Society 20040204

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Tags:4731-53-7 Molecular Formula|4731-53-7 MDL|4731-53-7 SMILES|4731-53-7 Trioctylphosphine