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52340-78-0,MFCD00064254
Catalog No.:AA003C9Q

52340-78-0 | (R,R)-(+)-Hydrobenzoin

Pack Size
Purity
Availability
Price(USD)
Quantity
  
250mg
97%
in stock  
$7.00   $5.00
- +
1g
97%
in stock  
$23.00   $16.00
- +
5g
97%
in stock  
$41.00   $29.00
- +
10g
97%
in stock  
$80.00   $56.00
- +
25g
97%
in stock  
$198.00   $139.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003C9Q
Chemical Name:
(R,R)-(+)-Hydrobenzoin
CAS Number:
52340-78-0
Molecular Formula:
C14H14O2
Molecular Weight:
214.2598
MDL Number:
MFCD00064254
SMILES:
O[C@@H]([C@@H](c1ccccc1)O)c1ccccc1
Properties
Properties
 
BP:
373°C at 760 mmHg  
Form:
Solid  
MP:
146-149 °C(lit.)  
Refractive Index:
95 ° (C=1, CHCl3)  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
171  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
2  
Heavy Atom Count:
16  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
2  
Rotatable Bond Count:
3  
XLogP3:
1.6  

Downstream Synthesis Route

[1]Clegg,William;Johann,ThorstenR.F.;Marder,ToddB.;Norman,NicholasC.;Orpen,A.Guy;Peakman,TorrenM.;Quayle,MichaelJ.;Rice,CraigR.;Scott,AndrewJ.[JournaloftheChemicalSociety,DaltonTransactions,1998,#9,p.1431-1438]

[2]Clegg,William;Johann,ThorstenR.F.;Marder,ToddB.;Norman,NicholasC.;Orpen,A.Guy;Peakman,TorrenM.;Quayle,MichaelJ.;Rice,CraigR.;Scott,AndrewJ.[JournaloftheChemicalSociety,DaltonTransactions,1998,#9,p.1431-1438]

108-16-7    52340-78-0   
C19H24BNO3 

[1]EuropeanJournalofOrganicChemistry,1999,p.1775-1786

[1]Huang,Jinkun;Corey[OrganicLetters,2003,vol.5,#19,p.3455-3458]

[2]Branco,LuisC.;Afonso,CarlosA.M.[JournalofOrganicChemistry,2004,vol.69,#13,p.4381-4389]

[3]MallaReddy;Srinivasulu;VenkatReddy;Narasimhulu;Venkateswarlu[TetrahedronLetters,2006,vol.47,#30,p.5285-5288]

[4]Dehury,SanjayK.;Hariharakrishnan[TetrahedronLetters,2007,vol.48,#14,p.2493-2496]

[5]Kuang,Yong-Qing;Zhang,Sheng-Yong;Wei,Ling-Ling[TetrahedronLetters,2001,vol.42,#34,p.5925-5927]

[6]Choudary,BoyapatiM.;Roy,Moumita;Roy,Sarabindu;Kantam,M.Lakshmi;Sreedhar,Bojja;Kumar,KarasalaVijay[AdvancedSynthesisandCatalysis,2006,vol.348,#12-13,p.1734-1742]

[7]Byoung,SeLee;Mahajan,Suresh;Janda,KimD.[TetrahedronLetters,2005,vol.46,#26,p.4491-4493]

[8]Donohoe,TimothyJ.;Harris,RobertM.;Butterworth,Sam;Burrows,JeremyN.;Cowley,Andrew;Parker,JeremyS.[JournalofOrganicChemistry,2006,vol.71,#12,p.4481-4489]

[9]Choudary,BoyapatiM.;Jyothi,Karangula;Roy,Moumita;Kantam,MannepalliL.;Sreedhar,Bojja[AdvancedSynthesisandCatalysis,2004,vol.346,#12,p.1471-1480]

[10]Krief;Castillo-Colaux[Synlett,2001,#4,p.501-504]

[11]Lacour,Jérôme;Londez,Anne[JournalofOrganometallicChemistry,2002,vol.643-644,p.392-403]

[12]Harris,LisaD.;Jenkins,RobertL.;Tomkinson,NicholasC.O.[TetrahedronLetters,2005,vol.46,#10,p.1627-1629]

[13]Junttila,MikkoH.;Hormi,OsmoE.O.[JournalofOrganicChemistry,2004,vol.69,#14,p.4816-4820]

[14]Trudeau,Stephane;Morgan,JeremyB.;Shrestha,Mohanish;Morken,JamesP.[JournalofOrganicChemistry,2005,vol.70,#23,p.9538-9544]

[15]Hoevelmann,ClaasH.;Muniz,Kilian[Chemistry-AEuropeanJournal,2005,vol.11,#13,p.3951-3958]

[16]Hoevelmann,ClaasH.;Muniz,Kilian[Chemistry-AEuropeanJournal,2005,vol.11,#13,p.3951-3958]

[17]Hoevelmann,ClaasH.;Muniz,Kilian[Chemistry-AEuropeanJournal,2005,vol.11,#13,p.3951-3958]

[18]Hoevelmann,ClaasH.;Muniz,Kilian[Chemistry-AEuropeanJournal,2005,vol.11,#13,p.3951-3958]

[19]Trudeau,Stephane;Morgan,JeremyB.;Shrestha,Mohanish;Morken,JamesP.[JournalofOrganicChemistry,2005,vol.70,#23,p.9538-9544]

[1]JournalofOrganicChemistry,2003,vol.68,p.3241-3245

[1]JournalofOrganicChemistry,2003,vol.68,p.3241-3245

Literature

Title: Asymmetric synthesis by the intramolecular haloetherification reaction of ene acetal: discrimination of prochiral dienes in cyclohexane systems.

Journal: Chemical & pharmaceutical bulletin 20050801

Title: Kwan SooKim, et al. Synthesis of enantiopure cyclopentitols and aminocyclopentitols mediated by oxyselenenylation of cyclopentene with (R,R)-hydrobenzoin. Tetrahedron Letters. 1988.

Title: (+)-(1R,2R)-1,2-Diphenylethane-1,2-diol.

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SDS
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