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13991-08-7,MFCD00014081
Catalog No.:AA001BQ7

13991-08-7 | 1,2-Bis(diphenylphosphino)benzene

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250mg
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1g
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$21.00   $15.00
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5g
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA001BQ7
Chemical Name:
1,2-Bis(diphenylphosphino)benzene
CAS Number:
13991-08-7
Molecular Formula:
C30H24P2
Molecular Weight:
446.4591
MDL Number:
MFCD00014081
SMILES:
c1ccc(c(c1)P(c1ccccc1)c1ccccc1)P(c1ccccc1)c1ccccc1
Properties
Properties
 
BP:
546.9°C at 760 mmHg  
Form:
Solid  
MP:
184-189 °C  
Stability:
Air Sensitive  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
439  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
32  
Rotatable Bond Count:
6  
XLogP3:
7.3  

Downstream Synthesis Route

[1]Hart,F.A.[JournaloftheChemicalSociety,1960,p.3324-3328]

[1]Talay,Ridvan;Rehder,Dieter[ZeitschriftfurNaturforschung,TeilB:AnorganischeChemie,OrganischeChemie,1981,vol.36,#4,p.451-462]

13991-08-7   
chloro(diphenylphosphanyl)diphenylphosphoniumtetrachlorogallate 
 
triphenyl-2-(1,2,2-triphenyl-diphosphanyl)-phenyl-phosphonium;GENERICINORGANICANION 

[1]Burford,Neil;Ragogna,PaulJ.;McDonald,Robert;Ferguson,MichaelJ.[JournaloftheAmericanChemicalSociety,2003,vol.125,#47,p.14404-14410]

[2]Burford,Neil;Ragogna,PaulJ.;McDonald,Robert;Ferguson,MichaelJ.[JournaloftheAmericanChemicalSociety,2003,vol.125,#47,p.14404-14410]

[1]Hatano,Manabu;Takagi,Eri;Ishihara,Kazuaki[OrganicLetters,2007,vol.9,#22,p.4527-4530]

[2]Locationinpatent:experimentalpartMoussa,Ziad[Synthesis,2012,vol.44,#3,p.460-468]

[3]Pietraszkiewicz,Marek;Mal,Suraj;Pietraszkiewicz,Oksana;Gorski,Krzysztof;Chelwani,Nitin[ZeitschriftfurNaturforschung,B:ChemicalSciences,2014,vol.69,#2,p.239-247]

[4]Levason,William;Patel,Rina;Reid,Gillian[JournalofOrganometallicChemistry,2003,vol.688,#1-2,p.280-282]

13991-08-7    14074-80-7   
C118H78N8P2(2-)*2Zn(2+)*2PF6(1-) 

[1]Ruhlmann,Laurent;Gross,Maurice;Giraudeau,Alain[Chemistry-AEuropeanJournal,2003,vol.9,#20,p.5085-5096]

Literature

Title: Rhodium-catalyzed synthesis of diaryl sulfides using aryl fluorides and sulfur/organopolysulfides.

Journal: Organic letters 20121019

Title: Photoluminescence properties, molecular structures, and theoretical study of heteroleptic silver(I) complexes containing diphosphine ligands.

Journal: Inorganic chemistry 20120521

Title: Dual luminescent tetranuclear organogold(I) macrocycles of 5,5'-diethynyl-2,2'-bipyridine and their efficient sensitization of Yb(III) luminescence.

Journal: Inorganic chemistry 20120102

Title: Bis(imidate)palladium(II) complexes with labile ligands. Mimics of classical precursors?

Journal: Dalton transactions (Cambridge, England : 2003) 20111221

Title: Conjugate reduction and reductive aldol cyclization of α,β-unsaturated thioesters catalyzed by (BDP)CuH.

Journal: Organic & biomolecular chemistry 20110907

Title: Vapochromic and mechanochromic tetrahedral gold(I) complexes based on the 1,2-bis(diphenylphosphino)benzene ligand.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20101025

Title: Brilliant reversible luminescent mechanochromism of silver(I) complexes containing o-bis(diphenylphosphino)benzene and phosphinesulfide.

Journal: Chemical communications (Cambridge, England) 20100321

Title: Luminescent mononuclear Ag(I)-bis(diphosphine) complexes: correlation between the photophysics and the structures of mononuclear Ag(I)-bis(diphosphine) complexes.

Journal: Inorganic chemistry 20100201

Title: Vicinal diphosphoniums: electrostatic repulsion under covalent constraint.

Journal: Dalton transactions (Cambridge, England : 2003) 20091028

Title: Iron-catalysed fluoroaromatic coupling reactions under catalytic modulation with 1,2-bis(diphenylphosphino)benzene.

Journal: Chemical communications (Cambridge, England) 20090314

Title: Iron-catalysed Negishi coupling of benzyl halides and phosphates.

Journal: Chemical communications (Cambridge, England) 20090207

Title: Photochemistry and photophysics of the tetrahedral silver(I) complex with diphosphine ligands: [Ag(dppb)2]PF6 (dppb = 1, 2-bis[diphenylphosphino]benzene).

Journal: Chemical communications (Cambridge, England) 20081221

Title: Rhodium-catalyzed substitution reaction of aryl fluorides with disulfides: p-orientation in the polyarylthiolation of polyfluorobenzenes.

Journal: Journal of the American Chemical Society 20080917

Title: Kinetic and high-pressure mechanistic investigation of the aqua substitution in the trans-aquaoxotetracyano complexes of re(v) and tc(v): some implications for nuclear medicine.

Journal: Metal-based drugs 20080101

Title: Alkyl carbon-nitrogen reductive elimination from platinum(IV)-sulfonamide complexes.

Journal: Journal of the American Chemical Society 20070829

Title: Photophysical properties of highly luminescent copper(I) halide complexes chelated with 1,2-bis(diphenylphosphino)benzene.

Journal: Inorganic chemistry 20070319

Title: 1,2-Bis(diphenylphosphino)benzene and two related mono-methiodides, [o-C(6)H(4)(PR(2))(PR(2)Me)]I (R = Ph or Me).

Journal: Acta crystallographica. Section C, Crystal structure communications 20060701

Title: Mechanistic information on the reductive elimination from cationic trimethylplatinum(IV) complexes to form carbon-carbon bonds.

Journal: Inorganic chemistry 20051031

Title: Phosphine coordination complexes of the diphenylphosphenium cation: a versatile synthetic methodology for P-P bond formation.

Journal: Journal of the American Chemical Society 20031126

Title: Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles.

Journal: Journal of the American Chemical Society 20020814

Title: Studies of reductive elimination reactions to form carbon-oxygen bonds from Pt(IV) complexes.

Journal: Journal of the American Chemical Society 20010321

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