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1538-75-6,MFCD00008842
Catalog No.:AA0035F4

1538-75-6 | Trimethylacetic anhydride

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5g
98%
in stock  
$16.00   $11.00
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25g
98%
in stock  
$34.00   $24.00
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100g
98%
in stock  
$79.00   $55.00
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500g
98%
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$261.00   $183.00
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  • Technical Information
  • Properties
  • Literature
  • Request for Quotation
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0035F4
Chemical Name:
Trimethylacetic anhydride
CAS Number:
1538-75-6
Molecular Formula:
C10H18O3
Molecular Weight:
186.2481
MDL Number:
MFCD00008842
SMILES:
O=C(C(C)(C)C)OC(=O)C(C)(C)C
Properties
Properties
 
BP:
193 °C at 760 mmHg  
Form:
Liquid  
Refractive Index:
n20/D 1.409(lit.)  
Solubility:
Miscible with acetonitrile.  
Stability:
Moisture Sensitive  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
191  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
13  
Hydrogen Bond Acceptor Count:
3  
Rotatable Bond Count:
4  
XLogP3:
2.7  

Literature

Title: A new method for production of chiral 2-aryl-2-fluoropropanoic acids using an effective kinetic resolution of racemic 2-aryl-2-fluoropropanoic acids.

Journal: Molecules (Basel, Switzerland) 20120614

Title: [Development of novel methods for preparing chiral non-steroidal anti-inflammatory drugs (NSAIDs) by asymmetric esterification].

Journal: Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 20120101

Title: (R)-(+)-N-methylbenzoguanidine ((R)-NMBG) catalyzed kinetic resolution of racemic secondary benzylic alcohols with free carboxylic acids by asymmetric esterification.

Journal: Organic & biomolecular chemistry 20111021

Title: Kinetic resolution of racemic alpha-arylalkanoic acids with achiral alcohols via the asymmetric esterification using carboxylic anhydrides and acyl-transfer catalysts.

Journal: Journal of the American Chemical Society 20100825

Title: Kinetic resolution of the racemic 2-hydroxyalkanoates using the enantioselective mixed-anhydride method with pivalic anhydride and a chiral acyl-transfer catalyst.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20100104

Title: 6-Amino-2,5-bis-(pivaloylamino)pyrimidin-4(3H)-one dihydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20090701

Title: Synthetic efforts for stereo structure determination of cytotoxic marine natural product pericosines as metabolites of Periconia sp. from sea hare.

Journal: International journal of molecular sciences 20080301

Title: N,N-Bis(2,2-dimethyl-propano-yl)benzene-1,3-dicarbohydrazide.

Journal: Acta crystallographica. Section E, Structure reports online 20080101

Title: Steric effects in the uncatalyzed and DMAP-catalyzed acylation of alcohols-quantifying the window of opportunity in kinetic resolution experiments.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060724

Title: Synthesis of novel (1-alkanoyloxy-4-alkanoylaminobutylidene)-1,1-bisphosphonic acid derivatives.

Journal: Beilstein journal of organic chemistry 20060101

Title: Nucleophilic acyl substitutions of anhydrides with protic nucleophiles catalyzed by amphoteric, oxomolybdenum species.

Journal: The Journal of organic chemistry 20050218

Title: Measurement of N7-(2'-hydroxyethyl)guanine in human DNA by gas chromatography electron capture mass spectrometry.

Journal: Chemical research in toxicology 20050101

Title: DNA display II. Genetic manipulation of combinatorial chemistry libraries for small-molecule evolution.

Journal: PLoS biology 20040701

Title: A mild and efficient protocol for the conversion of carboxylic acids to olefins by a catalytic decarbonylative elimination reaction.

Journal: Chemical communications (Cambridge, England) 20040321

Title: Pivalate-generating prodrugs and carnitine homeostasis in man.

Journal: Pharmacological reviews 20021201

Title: New Pd-catalyzed selective reduction of carboxylic acids to aldehydes.

Journal: Chemical communications (Cambridge, England) 20020421

Title: Highly powerful and practical acylation of alcohols with acid anhydride catalyzed by Bi(OTf)(3).

Journal: The Journal of organic chemistry 20011228

Title: Observation and elimination of N-acetylation of oligonucleotides prepared using fast-deprotecting phosphoramidites and ultra-mild deprotection.

Journal: Bioorganic & medicinal chemistry letters 20010507

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Tags:1538-75-6 Molecular Formula|1538-75-6 MDL|1538-75-6 SMILES|1538-75-6 Trimethylacetic anhydride