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Home Boronic Acids 1582-24-7
1582-24-7,MFCD01074663
Catalog No.:AA001PZ0

1582-24-7 | 2,3,4,5,6-Pentafluorophenylboronic acid

Pack Size
Purity
Availability
Price(USD)
Quantity
  
1g
97%
in stock  
$21.00   $15.00
- +
5g
97%
in stock  
$33.00   $23.00
- +
25g
97%
in stock  
$80.00   $56.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA001PZ0
Chemical Name:
2,3,4,5,6-Pentafluorophenylboronic acid
CAS Number:
1582-24-7
Molecular Formula:
C6H2BF5O2
Molecular Weight:
211.8819
MDL Number:
MFCD01074663
SMILES:
Fc1c(F)c(B(O)O)c(c(c1F)F)F
Properties
Properties
 
BP:
244°C at 760 mmHg  
Form:
Solid  
MP:
176-179 °C  
Solubility:
Miscible with alcohols, acetonitrile and dichloromethane.  
Stability:
Moisture Sensitive  
Storage:
Inert atmosphere;-20 ℃;  

Computed Properties
 
Complexity:
191  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
14  
Hydrogen Bond Acceptor Count:
7  
Hydrogen Bond Donor Count:
2  
Rotatable Bond Count:
1  

Downstream Synthesis Route
1582-24-7   
potassiumperfluorophenyltrifluoroborate 

[1]Molander,GaryA.;Biolatto,Betina[JournalofOrganicChemistry,2003,vol.68,#11,p.4302-4314]

[2]Locationinpatent:experimentalpartOliveira,RobertaA.;Silva,RicardoO.;Molander,GaryA.;Menezes,PauloH.[MagneticResonanceinChemistry,2009,vol.47,#10,p.873-878]

[3]Santos-Filho,EveraldoF.;Sousa,JokderléaC.;Bezerra,NatérciaM.M.;Menezes,PauloH.;Oliveira,RobertaA.[TetrahedronLetters,2011,vol.52,#41,p.5288-5291]

[4]Molander,GaryA.;Trice,SarahL.J.;Kennedy,StevenM.;Dreher,SpencerD.;Tudge,MatthewT.[JournaloftheAmericanChemicalSociety,2012,vol.134,#28,p.11667-11673]

1582-24-7   
lithiumpentafluorophenylborohydride 

[1]Biscoe,MarkR.;Breslow,Ronald[JournaloftheAmericanChemicalSociety,2003,vol.125,#42,p.12718-12719]

1582-24-7   
ethyl(E)-(4RS,5RS)-6-benzyloxy-4,5-epoxy-2-hexenoate 
 
(E)-3-((4R,5R)-5-Benzyloxymethyl-2-pentafluorophenyl-1,3,2dioxaborolan-4-yl)-acrylicacidethylester 

[1]Hirai,Atsushi;Yu,Xiao-Qiang;Tonooka,Terumichi;Miyashita,Masaaki[ChemicalCommunications,2003,#19,p.2482-2483]

1003-09-4    1582-24-7    865-47-4   
2-(4-tert-butyloxy-2,3,5,6-tetrafluorophenyl)thiophene 

[1]Takimiya,Kazuo;Niihara,Naoto;Otsubo,Tetsuo[Synthesis,2005,#10,p.1589-1592]

[1]Takimiya,Kazuo;Niihara,Naoto;Otsubo,Tetsuo[Synthesis,2005,#10,p.1589-1592]

Literature

Title: Mild and general conditions for the cross-coupling of aryl halides with pentafluorobenzene and other perfluoroaromatics.

Journal: Organic letters 20061026

Title: Suzuki-Miyaura coupling reaction using pentafluorophenylboronic acid.

Journal: Organic letters 20051027

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Tags:1582-24-7 Molecular Formula|1582-24-7 MDL|1582-24-7 SMILES|1582-24-7 2,3,4,5,6-Pentafluorophenylboronic acid