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16545-68-9,MFCD19707103
Catalog No.:AA001W32

16545-68-9 | Cyclopropanol

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  • Technical Information
  • Properties
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Technical Information
Catalog Number:
AA001W32
Chemical Name:
Cyclopropanol
CAS Number:
16545-68-9
Molecular Formula:
C3H6O
Molecular Weight:
58.0791
MDL Number:
MFCD19707103
SMILES:
OC1CC1
Properties
Properties
 
BP:
90.4°C at 760 mmHg  
Form:
Liquid  
MP:
180℃  
Refractive Index:
1.4129 (589.3 nm 20℃)  
Storage:
Keep in dry area;2-8℃;  

Computed Properties
 
Complexity:
22.5  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
4  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
1  
XLogP3:
0.1  

Literature

Title: The Kulinkovich hydroxycyclopropanation reaction in natural product synthesis.

Journal: Organic & biomolecular chemistry 20121014

Title: Design of protein congeners containing β-cyclopropylalanine.

Journal: Molecular bioSystems 20121001

Title: Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates.

Journal: Chemical communications (Cambridge, England) 20120211

Title: Mn(III)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles.

Journal: Chimia 20120101

Title: Asymmetric synthesis of cis-2-aminocyclopropanols by intramolecular Mannich addition of silyloxy benzyl carbanions.

Journal: The Journal of organic chemistry 20110520

Title: Diasteroselective preparation of cyclopropanols using methylene bis(iodozinc).

Journal: Organic letters 20110506

Title: Design of potent and selective GPR119 agonists for type II diabetes.

Journal: Bioorganic & medicinal chemistry letters 20110501

Title: Mn(III)-mediated formal [3+3]-annulation of vinyl azides and cyclopropanols: a divergent synthesis of azaheterocycles.

Journal: Journal of the American Chemical Society 20110427

Title: Structure-function relationships of the antigenicity of mycolic acids in tuberculosis patients.

Journal: Chemistry and physics of lipids 20101101

Title: Quantum chemistry of C(3)H(6)O molecules: structure and stability, isomerization pathways, and chirality changing mechanisms.

Journal: The journal of physical chemistry. A 20100916

Title: Thermodynamic control of diastereoselectivity in the formal nucleophilic substitution of bromocyclopropanes.

Journal: Organic letters 20100402

Title: One-pot catalytic enantio- and diastereoselective syntheses of anti-, syn-cis-disubstituted, and syn-vinyl cyclopropyl alcohols.

Journal: Journal of the American Chemical Society 20100113

Title: Stereospecific construction of chiral tertiary and quaternary carbon by nucleophilic cyclopropanation with bis(iodozincio)methane.

Journal: Chemistry, an Asian journal 20100104

Title: Fe-catalyzed highly selective ring expansion of alkynylcyclopropyl alkanols to cyclobutanols.

Journal: Chemical communications (Cambridge, England) 20091128

Title: Mn(III)-mediated reactions of cyclopropanols with vinyl azides: synthesis of pyridine and 2-azabicyclo[3.3.1]non-2-en-1-ol derivatives.

Journal: Journal of the American Chemical Society 20090909

Title: Applications of 1-alkenyl-1,1-heterobimetallics in the stereoselective synthesis of cyclopropylboronate esters, trisubstituted cyclopropanols and 2,3-disubstituted cyclobutanones.

Journal: Journal of the American Chemical Society 20090513

Title: Cyclization and ring-expansion processes involving samarium diiodide promoted reductive formation and subsequent oxidative ring opening of cyclopropanol derivatives.

Journal: The Journal of organic chemistry 20090320

Title: Stereoselective, dual-mode ruthenium-catalyzed ring expansion of alkynylcyclopropanols.

Journal: Journal of the American Chemical Society 20081224

Title: Synthesis of carbasugar C-1 phosphates via Pd-catalyzed cyclopropanol ring opening.

Journal: Organic letters 20080821

Title: Diastereoselective Prins-type reaction of cycloalkenylcyclopropanol silyl ethers and alpha,beta-unsaturated aldehyde acetals.

Journal: The Journal of organic chemistry 20071012

Title: A cyclopropanol-based strategy for subunit coupling: total synthesis of (+)-spirolaxine methyl ether.

Journal: Organic letters 20070705

Title: Stereoselective synthesis of 2,4,6-trisubstituted tetrahydropyrans by the use of cyclopropanols as homoenols.

Journal: Angewandte Chemie (International ed. in English) 20070101

Title: Thiacetazone, an antitubercular drug that inhibits cyclopropanation of cell wall mycolic acids in mycobacteria.

Journal: PloS one 20070101

Title: Cleavage of activated cyclic amines: Unprecedented approach toward 2-substituted cyclobutanones.

Journal: Organic letters 20060914

Title: Use of cyclopropanols as conformational constraints in RCM.

Journal: Organic letters 20060622

Title: Catalytic asymmetric Simmons-Smith cyclopropanation of silyl enol ethers. Efficient synthesis of optically active cyclopropanol derivatives.

Journal: Organic letters 20060622

Title: Synthesis of (-)-sordarin.

Journal: Journal of the American Chemical Society 20060531

Title: Development of an anomalous Heck reaction: skeletal rearrangement of divinyl and enyne carbinols.

Journal: Organic letters 20051222

Title: Enantioselective total synthesis of isoedunol and beta-araneosene featuring unconventional strategy and methodology.

Journal: Journal of the American Chemical Society 20051012

Title: Gold(I)-catalyzed ring expansion of cyclopropanols and cyclobutanols.

Journal: Journal of the American Chemical Society 20050713

Title: Two-step metal-mediated transformation of isoxazolidine-5-spirocyclopropanes into pyridone derivatives.

Journal: The Journal of organic chemistry 20050708

Title: Chromium-catalyzed pinacol-type cross-coupling: studies on stereoselectivity.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20050506

Title: 1,2-Acyl transfer reaction for the construction of multiple carbonyl-functionalized architecture by Sm(II)-induced tandem formation and breaking of cyclopropanol.

Journal: The Journal of organic chemistry 20050218

Title: A cyclopropane fragmentation approach to heterocycle assembly: a convergent synthesis of oxepanes.

Journal: Organic letters 20050203

Title: pi-1,1-Dimethyleneallylmetal and homologous complexes: their application in organic synthesis.

Journal: Chemical reviews 20050101

Title: Stereocontrolled synthesis of cyclopropanol amino acids from allylic sulfones: conformationally restricted building blocks.

Journal: Organic letters 20031002

Title: Stereocontrolled preparation of a nonpeptidal (-)-spirobicyclic NK-1 receptor antagonist.

Journal: The Journal of organic chemistry 20020222

Title: How persistent is cyclopropyl upon nucleophilic substitution, and is frontside displacement possible? A model study.

Journal: The Journal of organic chemistry 20011019

Title: First stereocontrolled synthesis of (S)-cleonin and related cyclopropyl-substituted amino acids.

Journal: Organic letters 20011018

Title: Dissection of a flavoenzyme active site: the reaction catalyzed by cholesterol oxidase.

Journal: Antioxidants & redox signaling 20011001

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Tags:16545-68-9 Molecular Formula|16545-68-9 MDL|16545-68-9 SMILES|16545-68-9 Cyclopropanol