Home Amines 29841-69-8
29841-69-8,MFCD00082751
Catalog No.:AA00328X

29841-69-8 | (1S,2S)-(-)-1,2-Diphenylethylenediamine

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1g
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$6.00   $4.00
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5g
98%
in stock  
$16.00   $11.00
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10g
98%
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$27.00   $19.00
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25g
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$58.00   $41.00
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100g
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA00328X
Chemical Name:
(1S,2S)-(-)-1,2-Diphenylethylenediamine
CAS Number:
29841-69-8
Molecular Formula:
C14H16N2
Molecular Weight:
212.2902
MDL Number:
MFCD00082751
SMILES:
N[C@H]([C@H](c1ccccc1)N)c1ccccc1
Properties
Properties
 
BP:
353.9°C at 760 mmHg  
Form:
Solid  
MP:
83-85 °C(lit.)  
Refractive Index:
-103 ° (C=1, EtOH)  
Stability:
Air Sensitive  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
171  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
2  
Heavy Atom Count:
16  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
2  
Rotatable Bond Count:
3  
XLogP3:
1.4  

Upstream Synthesis Route

[1]Tetrahedron:Asymmetry,1995,vol.6,#1,p.3-6

[2]OrganicSyntheses,1993,vol.71,p.30-30

[1]OrganicandBiomolecularChemistry,2011,vol.9,#7,p.2505-2511

[2]JournalofOrganicChemistry,2004,vol.69,#4,p.1283-1289

[3]Patent:WO2010/120719,2010,A1,.Locationinpatent:Page/Pagecolumn194;196-197

[4]Patent:CN106496099,2017,A,.Locationinpatent:Paragraph0033;0034;0035;0048;0049

[5]OrganicSyntheses,2005,vol.82,p.10-17

[6]EuropeanJournalofOrganicChemistry,1999,#9,p.2315-2321

[7]TetrahedronAsymmetry,1997,vol.8,#13,p.2101-2108

[8]EuropeanJournalofOrganicChemistry,2000,#12,p.2247-2252

[9]Patent:EP1174426,2002,A1,.Locationinpatent:Page36

[10]Chemistry-AEuropeanJournal,2008,vol.14,#25,p.7687-7698

[1]Patent:EP1375477,2004,A2,.Locationinpatent:Page/Pagecolumn7-8

[2]Patent:EP1375477,2004,A2,.Locationinpatent:Page/Pagecolumn8

[3]Patent:US2005/59842,2005,A1,.Locationinpatent:Page/Pagecolumn5

[4]Patent:US2005/59842,2005,A1,.Locationinpatent:Page/Pagecolumn5

Downstream Synthesis Route

[1]Ao,Yu-Fei;Guo,Hao;Meng,Wei;Wang,De-Xian;Wang,Qi-Qiang;Zhang,Lie-Wei;Zhou,Hao[AngewandteChemie-InternationalEdition,2020,vol.59,#7,p.2623-2627][Angew.Chem.,2020,vol.132,p.2645-2649,5]

[2]Kanemasa,Shuji;Hayashi,Takeshi;Tanaka,Junji;Yamamoto,Hidetoshi;Sakurai,Tosio[JournalofOrganicChemistry,1991,vol.56,#14,p.4473-4481]

[3]Hu,Kejiang;Krakowiak,KrzysztofE.;Bradshaw,JeraldS.;Dalley,N.Kent;Xue,Guoping;Izatt,ReedM.[JournalofHeterocyclicChemistry,1999,vol.36,#2,p.347-354]

[1]Novacek,Johanna;Roiser,Lukas;Zielke,Katharina;Robiette,Raphaël;Waser,Mario[Chemistry-AEuropeanJournal,2016,vol.22,#32,p.11422-11428]

[2]Xu,Kuo-Xi;Kong,Hua-Jie;Zu,Fu-Li;Yang,Li;Wang,Chen-Juan[SpectrochimicaActaPartA:MolecularandBiomolecularSpectroscopy,2014,vol.118,p.811-815]

[3]Oi,Ryu;Sharpless,K.Barry[TetrahedronLetters,1991,vol.32,#37,p.4853-4854]

[1]TetrahedronAsymmetry,1995,vol.6,p.3-6

[2]OrganicSyntheses,1993,vol.71,p.30-30

29841-69-8    153759-58-1   
(S,S)-2,2'-(1,2-diphenyl-1,2-ethanediyl)bis(nitrilomethylidyne)bis4-bromo-6-(1,1-dimethylethy)phenol 

[1]Chemistry-AEuropeanJournal,1996,vol.2,p.974-980

[1]OrganicandBiomolecularChemistry,2011,vol.9,p.2505-2511

[2]JournalofOrganicChemistry,2004,vol.69,p.1283-1289

[3]Patent:WO2010/120719,2010,A1.Locationinpatent:Page/Pagecolumn194;196-197

[4]Patent:CN106496099,2017,A.Locationinpatent:Paragraph0033;0034;0035;0048;0049

[5]OrganicSyntheses,2005,vol.82,p.10-17

[6]EuropeanJournalofOrganicChemistry,1999,p.2315-2321

[7]TetrahedronAsymmetry,1997,vol.8,p.2101-2108

[8]EuropeanJournalofOrganicChemistry,2000,p.2247-2252

[9]Patent:EP1174426,2002,A1.Locationinpatent:Page36

[10]Chemistry-AEuropeanJournal,2008,vol.14,p.7687-7698

Literature

Title: A tripeptide-like prolinamide-thiourea as an aldol reaction catalyst.

Journal: Organic & biomolecular chemistry 20120807

Title: Construction of tertiary alcohols bearing perfluoroalkyl chains catalyzed by prolinamide-thioureas.

Journal: The Journal of organic chemistry 20120120

Title: Preparation of 1-C-glycosyl aldehydes by reductive hydrolysis.

Journal: Carbohydrate research 20110906

Title: Interplay between the diamine structure and absolute helicity in Ni-salen metallofoldamers.

Journal: Chemical communications (Cambridge, England) 20110407

Title: Synthesis and chromatographic evaluation of new polymeric chiral stationary phases based on three (1S,2S)-(-)-1,2-diphenylethylenediamine derivatives in HPLC and SFC.

Journal: Analytical and bioanalytical chemistry 20110301

Title: Iron complexes for the catalytic transfer hydrogenation of acetophenone: steric and electronic effects imposed by alkyl substituents at phosphorus.

Journal: Inorganic chemistry 20101101

Title: Mix and match: templating chiral Schiff base ligands to suit the needs of the metal ion.

Journal: Dalton transactions (Cambridge, England : 2003) 20100614

Title: Synthesis and characterization of some chiral metal-salen complexes bearing a ferrocenophane substituent.

Journal: Molecules (Basel, Switzerland) 20091026

Title: Studies of the mechanism of action of platinum(II) complexes with potent cytotoxicity in human cancer cells.

Journal: Journal of medicinal chemistry 20090910

Title: NMDA receptor affinities of 1,2-diphenylethylamine and 1-(1,2-diphenylethyl)piperidine enantiomers and of related compounds.

Journal: Bioorganic & medicinal chemistry 20090501

Title: Synthesis, characterization, and application of vanadium-salan complexes in oxygen transfer reactions.

Journal: Inorganic chemistry 20090420

Title: Effect of dioxins on regulation of tyrosine hydroxylase gene expression by aryl hydrocarbon receptor: a neurotoxicology study.

Journal: Environmental health : a global access science source 20090101

Title: Stereospecific synthesis of C2 symmetric diamines from the mother diamine by resonance-assisted hydrogen-bond directed diaza-Cope rearrangement.

Journal: Journal of the American Chemical Society 20080910

Title: 2D layered supramolecular host system derived from a 21-helical column, composed of 1,2-diphenylethylenediamine and N-phenyliminodiacetic acid.

Journal: Organic letters 20080904

Title: Synthesis, characterization and antiproliferative studies of the enantiomers of cis-[(1,2-camphordiamine)dichloro]platinum(II) complexes.

Journal: Bioorganic & medicinal chemistry 20080215

Title: Efficient optical resolution of secondary alkyl alcohols by chiral supramolecular hosts.

Journal: Chemical communications (Cambridge, England) 20050714

Title: Magnetism of [Ni(dmit)2] salts with [meso- and (1S, 2S)-diphenyl-1,2-ethanediammonium]([18]crown-6)2 supramolecular cations.

Journal: Inorganic chemistry 20050627

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Tags:29841-69-8 Molecular Formula|29841-69-8 MDL|29841-69-8 SMILES|29841-69-8 (1S,2S)-(-)-1,2-Diphenylethylenediamine |Organic_Building_Blocks