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3002-81-1,MFCD00243277
Catalog No.:AA003M7F

3002-81-1 | 5,6-Dimethyl-1,10-phenanthroline

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100mg
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$28.00   $20.00
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250mg
98%
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$35.00   $25.00
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1g
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$114.00   $80.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003M7F
Chemical Name:
5,6-Dimethyl-1,10-phenanthroline
CAS Number:
3002-81-1
Molecular Formula:
C14H12N2
Molecular Weight:
208.2585
MDL Number:
MFCD00243277
SMILES:
Cc1c(C)c2cccnc2c2c1cccn2
Properties
Properties
 
BP:
396.976°C at 760 mmHg  
Form:
Solid  
MP:
266-269 °C(lit.);  
Stability:
Hygroscopic  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
227  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
16  
Hydrogen Bond Acceptor Count:
2  
XLogP3:
3.2  

Downstream Synthesis Route

[1]Locationinpatent:experimentalpartHigashi,Toshinori;Inami,Keiko;Mochizuki,Masataka[JournalofHeterocyclicChemistry,2008,vol.45,#6,p.1889-1892]

[2]Hartl,Frantisek;Vernier,Sandrine;Belser,Peter[CollectionofCzechoslovakChemicalCommunications,2005,vol.70,#11,p.1891-1908]

3002-81-1   
rhodium(III)chloridetrihydrate 
 
{Rh(C12H6N2(CH3)2)3}(3+)*3ClO4(1-)={Rh(C12H6N2(CH3)2)3}(ClO4)3 

[1]Creutz,Carol;Keller,AndrewD.;Sutin,Norman;Zipp,ArdenP.[JournaloftheAmericanChemicalSociety,1982,vol.104,#13,p.3618-3627]

[2][GmelinHandbuchderAnorganischenChemie,GmelinHandbook:Rh:SVol.B2,2.6.12,page289-290]

3002-81-1   
rhodium(III)chloridetrihydrate 
  66415-84-7 

[1]Creutz,Carol;Keller,AndrewD.;Sutin,Norman;Zipp,ArdenP.[JournaloftheAmericanChemicalSociety,1982,vol.104,#13,p.3618-3627]

Ru(NCMe)4(C6H4-2-C5H4N)PF6 
  3002-81-1    388500-55-8 

[1]Ryabov;Sukbarev;Alexandrova;LeLagadec;Pfeffer[InorganicChemistry,2001,vol.40,#25,p.6529-6532]

[2]Ryabov;Sukbarev;Alexandrova;LeLagadec;Pfeffer[InorganicChemistry,2001,vol.40,#25,p.6529-6532]

[1]Selvi,PitchumonyTamil;Palaniandavar,Mallayan[InorganicaChimicaActa,2002,vol.337,p.420-428]

Literature

Title: New [Ru(5,6-dmp/3,4,7,8-tmp)₂(diimine)]²⁺ complexes: non-covalent DNA and protein binding, anticancer activity and fluorescent probes for nuclear and protein components.

Journal: Journal of inorganic biochemistry 20121101

Title: Tris(5,6-dimethyl-1,10-phenanthroline-κ(2)N,N')copper(II) bis-(hexa-fluorido-phosphate) acetonitrile monosolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20120701

Title: Cytotoxicity and cellular impact of dinuclear organoiridium DNA intercalators and nucleases with long rigid bridging ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20120514

Title: Synthesis and cellular impact of diene-ruthenium(II) complexes: a new class of organoruthenium anticancer agents.

Journal: Journal of inorganic biochemistry 20120101

Title: Spectral and electrochemical studies of bis(diimine)copper(II) complexes in anionic, cationic and nonionic micelles.

Journal: Journal of colloid and interface science 20111015

Title: Ternary dinuclear copper(II) complexes of a hydroxybenzamide ligand with diimine coligands: the 5,6-dmp ligand enhances DNA binding and cleavage and induces apoptosis.

Journal: Inorganic chemistry 20110718

Title: DNA interaction studies of cobalt (II) mixed-ligand complexes containing dimethyl-1, 10-phenanthroline and dipyrido[3,2-a:2',3'-c]phenazine: the role of methyl substitutions on the mode of binding.

Journal: DNA and cell biology 20110701

Title: Tumor cytotoxicity of 5,6-dimethyl-1,10-phenanthroline and its corresponding gold(III) complex.

Journal: Journal of inorganic biochemistry 20110501

Title: DNA binding, prominent DNA cleavage and efficient anticancer activities of tris(diimine)iron(II) complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20110414

Title: Cellular selectivity and biological impact of cytotoxic rhodium(III) and iridium(III) complexes containing methyl-substituted phenanthroline ligands.

Journal: ChemMedChem 20110307

Title: Effect of ancillary ligands on the DNA interaction of [Cr(diimine)3]3+ complexes containing the intercalating dipyridophenazine ligand.

Journal: Inorganic chemistry 20100201

Title: Anionic PAMAM dendrimers as drug delivery vehicles for transition metal-based anticancer drugs.

Journal: Journal of inorganic biochemistry 20090301

Title: Strategy for the stereochemical assignment of tris-heteroleptic Ru(II) complexes by NMR spectroscopy.

Journal: Inorganic chemistry 20090202

Title: catena-Poly[[bis-(5-chloro-2-nitro-benzoato)copper(II)]-bis-(μ-5-chloro-2-nitro-benzoato)].

Journal: Acta crystallographica. Section E, Structure reports online 20090201

Title: Laser spectroscopy for atmospheric and environmental sensing.

Journal: Sensors (Basel, Switzerland) 20090101

Title: Concurrent sensing of benzene and oxygen by a crystalline salt of tris(5,6-dimethyl-1,10-phenanthroline)ruthenium(II).

Journal: Inorganic chemistry 20081020

Title: Interaction of rac-[Cu(diimine)3]2+ and rac-[Zn(diimine)3]2+ complexes with CT DNA: effect of fluxional Cu(II) geometry on DNA binding, ligand-promoted exciton coupling and prominent DNA cleavage.

Journal: Dalton transactions (Cambridge, England : 2003) 20080807

Title: Degradation of bidentate-coordinated platinum(II)-based DNA intercalators by reduced L-glutathione.

Journal: Journal of medicinal chemistry 20080508

Title: Non-covalent DNA binding and cytotoxicity of certain mixed-ligand ruthenium(II) complexes of 2,2'-dipyridylamine and diimines.

Journal: Dalton transactions (Cambridge, England : 2003) 20080428

Title: Microsphere-based protease assays and screening application for lethal factor and factor Xa.

Journal: Cytometry. Part A : the journal of the International Society for Analytical Cytology 20060501

Title: Structures, spectra, and DNA-binding properties of mixed ligand copper(II) complexes of iminodiacetic acid: the novel role of diimine co-ligands on DNA conformation and hydrolytic and oxidative double strand DNA cleavage.

Journal: Journal of inorganic biochemistry 20060301

Title: Interaction of rac-[Ru(5,6-dmp)3]2+ with DNA: enantiospecific DNA binding and ligand-promoted exciton coupling.

Journal: Inorganic chemistry 20060109

Title: Synthesis, characterization and DNA-binding properties of rac-[Ru(5,6-dmp)2(dppz)]2+--enantiopreferential DNA binding and co-ligand promoted exciton coupling.

Journal: Journal of inorganic biochemistry 20060101

Title: Effects of supercoiling on the sequence-specific photo-modification of DNA by a vanadium(V)-peroxo complex.

Journal: Journal of inorganic biochemistry 20051001

Title: Photophysical, spectroscopic, and computational studies of a series of Re(I) tricarbonyl complexes containing 2,6-dimethylphenylisocyanide and 5- and 6-derivatized phenanthroline ligands.

Journal: Inorganic chemistry 20050404

Title: Use of polymeric indicator for electrochemical DNA sensors: poly(4-vinylpyridine) derivative bearing [Os(5,6-dimethyl-1,10-phenanthroline)2Cl]2+.

Journal: Analytical chemistry 20040515

Title: Synthesis of heteroleptic bis(diimine)carbonylchlororuthenium(II) complexes from photodecarbonylated precursors.

Journal: Inorganic chemistry 20040503

Title: DNA binding and biological activity of some platinum(II) intercalating compounds containing methyl-substituted 1,10-phenanthrolines.

Journal: Dalton transactions (Cambridge, England : 2003) 20040421

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Tags:3002-81-1 Molecular Formula|3002-81-1 MDL|3002-81-1 SMILES|3002-81-1 5,6-Dimethyl-1,10-phenanthroline |Organic_Building_Blocks