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1660-93-1,MFCD00004974
Catalog No.:AA0033FC

1660-93-1 | 3,4,7,8-Tetramethyl-1,10-phenanthroline

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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA0033FC
Chemical Name:
3,4,7,8-Tetramethyl-1,10-phenanthroline
CAS Number:
1660-93-1
Molecular Formula:
C16H16N2
Molecular Weight:
236.3116
MDL Number:
MFCD00004974
SMILES:
Cc1c(C)cnc2c1ccc1c2ncc(c1C)C
Properties
Properties
 
BP:
435.2°C at 760 mmHg  
Form:
Solid  
MP:
277-280 °C(lit.)  
Refractive Index:
1.5635 (estimate)  
Solubility:
Soluble in 1,4-dioxane, acetone, dichloromethane, N,N-dimethylformamide, N,N-dimethylacetamide, methanol and hot toluene.  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
274  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
18  
Hydrogen Bond Acceptor Count:
2  
XLogP3:
3.9  

Upstream Synthesis Route

[1]JournaloftheAmericanChemicalSociety,1949,vol.71,p.1828

[1]JournalofHeterocyclicChemistry,1981,vol.18,p.641-642

[1]JournaloftheAmericanChemicalSociety,1949,vol.71,p.1828

[1]JournaloftheAmericanChemicalSociety,1949,vol.71,p.1828

[1]JournaloftheAmericanChemicalSociety,1949,vol.71,p.1828

Downstream Synthesis Route

[1]Ekstrom,Alfred;Leong,AnthonyJ.;Lindoy,LeonardF.;Rodger,Alison;Harrison,BarbaraA.;Tregloan,PeterA.[InorganicChemistry,1983,vol.22,#9,p.1404-1407]

20759-14-2    1660-93-1   
cis-Ru(3,4,7,8-tetramethyl-1,10-phenanthroline)2Cl2 

[1]InorganicChemistry,2012,vol.51,p.3355-3365

zinc(II)nitratehexahydrate 
  1660-93-1    7717-76-2   
Zn(3,4,7,8-tetramethyl-1,10-phenanthroline)2(H2odpa)0.88-hydrate 

[1]SynthesisandReactivityinInorganic,Metal-Organic,andNano-MetalChemistry,2013,vol.43,p.456-460

zinc(II)nitratehexahydrate 
  1660-93-1    7717-76-2   
Zn(3,4,7,8-tetramethyl-1,10-phenanthroline)2(H2odpa)n 

[1]SynthesisandReactivityinInorganic,Metal-Organic,andNano-MetalChemistry,2013,vol.43,p.456-460

19567-78-3    1660-93-1    7732-18-5   
CASUnavailable 

[1]Pandrala,Mallesh;Li,Fangfei;Wallace,Lynne;Steel,PeterJ.;MooreIi,Barry;Autschbach,Jochen;Collins,J.Grant;Keene,F.Richard[AustralianJournalofChemistry,2013,vol.66,#9,p.1065-1073]

Literature

Title: New [Ru(5,6-dmp/3,4,7,8-tmp)₂(diimine)]²⁺ complexes: non-covalent DNA and protein binding, anticancer activity and fluorescent probes for nuclear and protein components.

Journal: Journal of inorganic biochemistry 20121101

Title: Modulation in selectivity and allosteric properties of small-molecule ligands for CC-chemokine receptors.

Journal: Journal of medicinal chemistry 20120927

Title: 3,4,7,8-Tetra-methyl-1,10-phenanthrolin-1-ium nitrate monohydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20120601

Title: Poly[[diaqua-hexa-μ-cyanido-cerium(III)ferrate(III)] dihydrate].

Journal: Acta crystallographica. Section E, Structure reports online 20120501

Title: Spectral and electrochemical studies of bis(diimine)copper(II) complexes in anionic, cationic and nonionic micelles.

Journal: Journal of colloid and interface science 20111015

Title: Effect of a photoactivated rhodium complex in melanoma.

Journal: Anti-cancer drugs 20111001

Title: Light-induced excited spin state trapping and charge transfer in trigonal bipyramidal cyanide-bridged complexes.

Journal: Inorganic chemistry 20110404

Title: Luminescent cyclometallated iridium(III) bis(quinolylbenzaldehyde) diimine complexes--synthesis, photophysics, electrochemistry, protein cross-linking properties, cytotoxicity and cellular uptake.

Journal: Dalton transactions (Cambridge, England : 2003) 20110314

Title: Structural diversity and thermochromic properties of iodobismuthate materials containing d-metal coordination cations: observation of a high symmetry [Bi3I11]2- anion and of isolated I- anions.

Journal: Journal of the American Chemical Society 20110126

Title: Excited-state dynamics in fac-[Re(CO)3(Me4phen)(L)]+.

Journal: The journal of physical chemistry. A 20101125

Title: Dinuclear Cu(II) hypocrellin B complexes with enhanced photonuclease activity.

Journal: Inorganic chemistry 20101101

Title: Trigonal bipyramidal magnetic molecules based on [Mo(III)(CN)(6)](3-).

Journal: Chemical communications (Cambridge, England) 20100707

Title: Effect of ancillary ligands on the DNA interaction of [Cr(diimine)3]3+ complexes containing the intercalating dipyridophenazine ligand.

Journal: Inorganic chemistry 20100201

Title: Trigonal-bipyramidal metal cyanide complexes: a versatile platform for the systematic assessment of the magnetic properties of Prussian blue materials.

Journal: Inorganic chemistry 20090420

Title: Photoswitches and luminescent rigidity sensors based on fac-[Re(CO)3(Me4phen)(L)]+.

Journal: Inorganic chemistry 20081201

Title: Resonance energy transfer in the solution phase photophysics of -Re(CO)3 L+ pendants bonded to poly(4-vinylpyridine).

Journal: The journal of physical chemistry. B 20080918

Title: Enantioselective DNA binding of iron(II) complexes of methyl-substituted phenanthroline.

Journal: Journal of inorganic biochemistry 20080801

Title: An improved Cu-based catalyst system for the reactions of alcohols with aryl halides.

Journal: The Journal of organic chemistry 20080104

Title: Cleavage of proteins by a mixed-ligand copper(II) phenolate complex: hydrophobicity of the diimine co-ligand promotes cleavage.

Journal: Inorganic chemistry 20071210

Title: Molecular organization of a water-insoluble iridium(III) complex in mixed monolayers.

Journal: Journal of colloid and interface science 20071101

Title: Differential modulation of Alzheimer's disease amyloid beta-peptide accumulation by diverse classes of metal ligands.

Journal: The Biochemical journal 20071101

Title: Mixed-ligand copper(II)-phenolate complexes: effect of coligand on enhanced DNA and protein binding, DNA cleavage, and anticancer activity.

Journal: Inorganic chemistry 20071001

Title: Properties of Prussian blue materials manifested in molecular complexes: observation of cyanide linkage isomerism and spin-crossover behavior in pentanuclear cyanide clusters.

Journal: Journal of the American Chemical Society 20070516

Title: Lanthanide-3d cyanometalate chains Ln(III)-M(III) (Ln=Pr, Nd, Sm, Eu, Gd, Tb; M=Fe) with the tridentate ligand 2,4,6-tri(2-pyridyl)-1,3,5-triazine (tptz): evidence of ferromagnetic interactions for the Sm(III)-M(III) compounds (M=Fe, Cr).

Journal: Dalton transactions (Cambridge, England : 2003) 20070227

Title: Cyclometalated iridium(III) diimine bis(biotin) complexes as the first luminescent biotin-based cross-linkers for avidin.

Journal: Inorganic chemistry 20070205

Title: A simple method for estimating activation energies using the fragmentation yield: collision-induced dissociation of iron(II)-phenanthroline complexes in an electrospray ionization mass spectrometer.

Journal: Journal of the American Society for Mass Spectrometry 20060701

Title: Effect of ring methylation on the photophysical, photochemical and photobiological properties of cis-dichlorobis(1,10-phenanthroline)rhodium(III)Chloride.

Journal: Photochemistry and photobiology 20060101

Title: Synthesis, characterization, crystal structure, and electrochemical, photophysical, and protein-binding properties of luminescent rhenium(I) diimine indole complexes.

Journal: Inorganic chemistry 20050822

Title: Prediction of genotoxicity of chemical compounds by statistical learning methods.

Journal: Chemical research in toxicology 20050601

Title: A spectroscopic and computational study on the effects of methyl and phenyl substituted phenanthroline ligands on the electronic structure of Re(I) tricarbonyl complexes containing 2,6-dimethylphenylisocyanide.

Journal: Dalton transactions (Cambridge, England : 2003) 20050321

Title: Design of rhenium(I) polypyridine biotin complexes as a new class of luminescent probes for avidin.

Journal: Inorganic chemistry 20050321

Title: Role of the orbitally degenerate Mn(III) ions in the single-molecule magnet behavior of the cyanide cluster ([MnII(tmphen)2]3[Mn(III)(CN)6]2) (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline).

Journal: Journal of the American Chemical Society 20041229

Title: Tetraaqua(3,4,7,8-tetramethyl-1,10-phenanthroline-kappa2N,N')zinc(II) thiosulfate.

Journal: Acta crystallographica. Section C, Crystal structure communications 20040901

Title: In vitro antimalarial activity of a series of cationic 2,2'-bipyridyl- and 1,10-phenanthrolineplatinum(II) benzoylthiourea complexes.

Journal: Journal of medicinal chemistry 20040520

Title: Recognition of topological isomerism: synthesis, structure, and magnetic properties of two pentanuclear high-spin molecules of the type [NiI(N-N)2]3[FeIII(CN)6]2.

Journal: Inorganic chemistry 20030602

Title: Synthesis, photophysical and electrochemical properties, and biological labeling studies of cyclometalated iridium(III) bis(pyridylbenzaldehyde) complexes: novel luminescent cross-linkers for biomolecules.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20030120

Title: Two nickel complexes stabilized by nitrate counter-ions.

Journal: Acta crystallographica. Section C, Crystal structure communications 20020401

Title: Synthesis, characterization, photophysical properties, and biological labeling studies of a series of luminescent rhenium(I) polypyridine maleimide complexes.

Journal: Inorganic chemistry 20020114

Title: A density functional study of the reactivity and stability of mixed copper complexes. Is hardness the reason?

Journal: Inorganic chemistry 20010115

Title: Inhibition of human immunodeficiency virus type 1 integrase by a hydrophobic cation: the phenanthroline-cuprous complex.

Journal: AIDS research and human retroviruses 19950101

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Tags:1660-93-1 Molecular Formula|1660-93-1 MDL|1660-93-1 SMILES|1660-93-1 3,4,7,8-Tetramethyl-1,10-phenanthroline |Organic_Building_Blocks