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498-66-8,MFCD00082304
Catalog No.:AA003T7N

498-66-8 | Bicyclo[2.2.1]hept-2-ene

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5g
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$18.00   $13.00
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25g
99%
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$22.00   $15.00
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100g
99%
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$32.00   $22.00
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400g
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  • Technical Information
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  • Technical Information
  • Properties
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Technical Information
Catalog Number:
AA003T7N
Chemical Name:
Bicyclo[2.2.1]hept-2-ene
CAS Number:
498-66-8
Molecular Formula:
C7H10
Molecular Weight:
94.1543
MDL Number:
MFCD00082304
SMILES:
C1CC2CC1C=C2
Properties
Properties
 
BP:
96°C at 760 mmHg  
Form:
Solid  
MP:
44-46 °C(lit.)  
Refractive Index:
1.4770 (estimate)  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
90.6  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
7  
Undefined Atom Stereocenter Count:
2  
XLogP3:
2.4  

Literature

Title: The stereochemical outcome of allyl magnesium and indium additions to 5-substituted norbornen-7-ones and its application to cis fused carbocycle formation via ring rearrangement metathesis.

Journal: Organic & biomolecular chemistry 20121121

Title: A dicationic ruthenium alkylidene complex for continuous biphasic metathesis using monolith-supported ionic liquids.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20121029

Title: Pd(II)-catalyzed regioselective 2-alkylation of indoles via a norbornene-mediated C-H activation: mechanism and applications.

Journal: Journal of the American Chemical Society 20120905

Title: Synthesis of isocyanate-based brush block copolymers and their rapid self-assembly to infrared-reflecting photonic crystals.

Journal: Journal of the American Chemical Society 20120829

Title: Functional monolithic materials for boronate-affinity chromatography via Schrock catalyst-triggered ring-opening metathesis polymerization.

Journal: Macromolecular rapid communications 20120828

Title: Ring-opening metathesis polymerization-derived large-volume monolithic supports for reversed-phase and anion-exchange chromatography of biomolecules.

Journal: The Analyst 20120721

Title: Bicyclo-[2.2.1]hept-2-en-7-yl 4-bromo-benzoate.

Journal: Acta crystallographica. Section E, Structure reports online 20120701

Title: Room temperature asymmetric Pd-catalyzed methoxycarbonylation of norbornene: highly selective catalysis and HP-NMR studies.

Journal: Dalton transactions (Cambridge, England : 2003) 20120621

Title: A genetically encoded norbornene amino acid for the mild and selective modification of proteins in a copper-free click reaction.

Journal: Angewandte Chemie (International ed. in English) 20120427

Title: Group 4 dimethylsilylenebisamido complexes bearing the 6-[2-(diethylboryl)phenyl]pyrid-2-yl motif: synthesis and use in tandem ring-opening metathesis/vinyl-insertion copolymerization of cyclic olefins with ethylene.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20111202

Title: Study of the activity of Grubbs catalyst-functionalized multiwalled carbon nanotubes in the ring opening metathesis polymerization.

Journal: Journal of nanoscience and nanotechnology 20111101

Title: Synthesis, structure, and reactivity of hydridoiridium complexes bearing a pincer-type PSiP ligand.

Journal: Chemistry, an Asian journal 20110905

Title: Self-activation in de novo designed mimics of cell-penetrating peptides.

Journal: Angewandte Chemie (International ed. in English) 20110627

Title: Cationic versus neutral Ru(II)--N-heterocyclic carbene complexes as latent precatalysts for the UV-induced ring-opening metathesis polymerization.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20101115

Title: Bis-exo-2-norbornylboron triflate for stereospecific enolization of 3,3,3-trifluoropropionates.

Journal: Organic letters 20101015

Title: Ring-Opening Metathesis Polymerization-Based Synthesis of CaCO(3) Nanoparticle-Reinforced Polymeric Monoliths for Tissue Engineering.

Journal: Macromolecular rapid communications 20100901

Title: Iridium-catalyzed (Z)-trialkylsilylation of terminal olefins.

Journal: The Journal of organic chemistry 20100305

Title: Distinct structural features of cyclothiazide are responsible for effects on peak current amplitude and desensitization kinetics at iGluR2.

Journal: Journal of molecular biology 20090904

Title: Ring-opening metathesis polymerization for the preparation of norbornene-based weak cation-exchange monolithic capillary columns.

Journal: Journal of chromatography. A 20090327

Title: High-load, oligomeric dichlorotriazine: a versatile ROMP-derived reagent and scavenger.

Journal: The Journal of organic chemistry 20081121

Title: Comparative study on the separation behavior of monolithic columns prepared via ring-opening metathesis polymerization and via electron beam irradiation triggered free radical polymerization for proteins.

Journal: Journal of chromatography. A 20080516

Title: Ring-opening metathesis polymerization-derived monolithic capillary columns for high-performance liquid chromatography. Downscaling and application in medical research.

Journal: Journal of chromatography. A 20080516

Title: Foiled carbenes revisited: When sigma-stabilization surpasses pi-stabilization.

Journal: The Journal of organic chemistry 20070105

Title: Enantioseparation of glycyl-dipeptides by CEC using particle-loaded monoliths prepared by ring-opening metathesis polymerization (ROMP).

Journal: Journal of biochemical and biophysical methods 20061130

Title: Anticancer thiopyrano[2,3-d][1,3]thiazol-2-ones with norbornane moiety. Synthesis, cytotoxicity, physico-chemical properties, and computational studies.

Journal: Bioorganic & medicinal chemistry 20060801

Title: Facile one-pot synthesis of brush polymers through tandem catalysis using Grubbs' catalyst for both ring-opening metathesis and atom transfer radical polymerizations.

Journal: Nano letters 20060801

Title: Oligomers of cis-beta-norbornene amino acid: formation of beta-strand mimetics.

Journal: Chemical communications (Cambridge, England) 20060414

Title: Metathesis polymerization-derived monolithic membranes for solid-phase extraction coupled with diffuse reflectance spectroscopy.

Journal: Journal of chromatography. A 20060317

Title: Evaluation of ring-opening metathesis polymerization (ROMP)-derived monolithic capillary high performance liquid chromatography columns.

Journal: Journal of chromatography. A 20051007

Title: Unusual cyclopropanation of 9-bromocamphor derivatives: a novel formal C(1)-C(7) bond cleavage of camphor.

Journal: Organic letters 20050707

Title: Effect of structure of the redox molecular sieve TS-1 on the oxidation of phenol, crotyl alcohol and norbornylene.

Journal: Physical chemistry chemical physics : PCCP 20050707

Title: Acute, subchronic, and mutagenicity studies with norbornene fluoroalcohol.

Journal: Drug and chemical toxicology 20050101

Title: Living copolymerization of ethylene with norbornene catalyzed by bis(pyrrolide-imine) titanium complexes with MAO.

Journal: Journal of the American Chemical Society 20040929

Title: Nortricyclyl-norbornenyl cation system accessed by carbene fragmentation.

Journal: The Journal of organic chemistry 20040528

Title: Synthesis and reactivity of homogeneous and heterogeneous ruthenium-based metathesis catalysts containing electron-withdrawing ligands.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20040206

Title: Terpyridine-based silica supports prepared by ring-opening metathesis polymerization for the selective extraction of noble metals.

Journal: Journal of chromatography. A 20031010

Title: A novel access to 3-aryl-2-norbornyl cation.

Journal: Chemical communications (Cambridge, England) 20030321

Title: Kinetically controlled optical resolution of racemic norbornene aldehyde derivatives.

Journal: Chirality 20030101

Title: Hydrophobic, pellicular, monolithic capillary columns based on cross-linked polynorbornene for biopolymer separations.

Journal: Analytical chemistry 20021201

Title: Separation of planar chiral ferrocene derivatives on beta-cyclodextrin-based polymer supports prepared via ring-opening metathesis graft-polymerization.

Journal: Journal of chromatography. A 20021011

Title: New developments in chemical library synthesis. Norbornenyl tags for use in phase-switching, sequestration, capture-release and soluble support applications.

Journal: Current opinion in drug discovery & development 20020701

Title: Micropreparative fractionation of DNA fragments on metathesis-based monoliths: influence of stoichiometry on separation.

Journal: Journal of chromatography. A 20020614

Title: Scavenge-ROMP-filter: a facile strategy for soluble scavenging via norbornenyl tagging of electrophilic Reagents.

Journal: Organic letters 20020530

Title: Metathesis-based monoliths: influence of polymerization conditions on the separation of biomolecules.

Journal: Analytical chemistry 20010901

Title: Influences of surface chemistry on the separation behavior of stationary phases for reversed-phase and ion-exchange chromatography: a comparison of coated and grafted supports prepared by ring-opening metathesis polymerization.

Journal: Journal of chromatography. A 20010112

Title: Evaluation of norbornene- beta-cyclodextrin-based monomers and oligomers as chiral selectors by means of nonaqueous capillary electrophoresis.

Journal: Electrophoresis 20010101

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Tags:498-66-8 Molecular Formula|498-66-8 MDL|498-66-8 SMILES|498-66-8 Bicyclo[2.2.1]hept-2-ene |Organic_Building_Blocks