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52670-38-9,MFCD00168862
Catalog No.:AA00DFK0

52670-38-9 | 2-Ethynylaniline

Pack Size
Purity
Availability
Price(USD)
Quantity
  
1g
97%
in stock  
$16.00   $11.00
- +
5g
97%
in stock  
$50.00   $35.00
- +
10g
97%
in stock  
$96.00   $68.00
- +
25g
97%
in stock  
$237.00   $166.00
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100g
95%
in stock  
$925.00   $648.00
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  • Technical Information
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  • Literature
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA00DFK0
Chemical Name:
2-Ethynylaniline
CAS Number:
52670-38-9
Molecular Formula:
C8H7N
Molecular Weight:
117.1479
MDL Number:
MFCD00168862
SMILES:
C#Cc1ccccc1N
Properties
Properties
 
BP:
229.5°C at 760 mmHg  
Form:
Liquid  
Refractive Index:
n20/D 1.6200(lit.)  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
131  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
9  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
1  
Rotatable Bond Count:
1  
XLogP3:
1.5  

Literature

Title: Copper-catalyzed [5+1] annulation of 2-ethynylanilines with an N,O-acetal leading to construction of quinoline derivatives.

Journal: Organic letters 20120203

Title: Remodelling of the natural product fumagillol employing a reaction discovery approach.

Journal: Nature chemistry 20111201

Title: New tetradentate N,N,N,N-chelating α-diimine ligands and their corresponding zinc and nickel complexes: synthesis, characterisation and testing as olefin polymerisation catalysts.

Journal: Dalton transactions (Cambridge, England : 2003) 20110407

Title: A facile route to polysubstituted indoles via three-component reaction of 2-ethynylaniline, sulfonyl azide, and nitroolefin.

Journal: Organic letters 20110304

Title: The mechanism of N-vinylindole formation via tandem imine formation and cycloisomerisation of o-ethynylanilines.

Journal: Dalton transactions (Cambridge, England : 2003) 20091214

Title: Efficient synthesis of 5,6-dihydroxyindole dimers, key eumelanin building blocks, by a unified o-ethynylaniline-based strategy for the construction of 2-linked biindolyl scaffolds.

Journal: The Journal of organic chemistry 20090918

Title: Construction of nitrogen heterocycles bearing an aminomethyl group by copper-catalyzed domino three-component coupling-cyclization.

Journal: The Journal of organic chemistry 20090918

Title: InBr3-promoted divergent approach to polysubstituted indoles and quinolines from 2-ethynylanilines: switch from an intramolecular cyclization to an intermolecular dimerization by a type of terminal substituent group.

Journal: The Journal of organic chemistry 20080606

Title: Fast CE for combinatorial catalysis.

Journal: Electrophoresis 20080101

Title: Design and synthesis of beta-methoxyacrylate analogues via click chemistry and biological evaluations.

Journal: Bioorganic & medicinal chemistry letters 20070401

Title: Direct synthesis of polysubstituted quinoline derivatives by InBr3-promoted dimerization of 2-ethynylaniline derivatives.

Journal: The Journal of organic chemistry 20060428

Title: Synthesis of 4H-3,1-benzoxazines, quinazolin-2-ones, and quinoline-4-ones by palladium-catalyzed oxidative carbonylation of 2-ethynylaniline derivatives.

Journal: The Journal of organic chemistry 20040402

Title: Development of an efficient procedure for indole ring synthesis from 2-ethynylaniline derivatives catalyzed by CuII salts and its application to natural product synthesis.

Journal: The Journal of organic chemistry 20040220

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