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6399-81-1,MFCD00035107
Catalog No.:AA003V35

6399-81-1 | Triphenylphosphine hydrobromide

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  • Technical Information
  • Properties
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Technical Information
Catalog Number:
AA003V35
Chemical Name:
Triphenylphosphine hydrobromide
CAS Number:
6399-81-1
Molecular Formula:
C18H16BrP
Molecular Weight:
343.1974
MDL Number:
MFCD00035107
SMILES:
c1ccc(cc1)P(c1ccccc1)c1ccccc1.Br
Properties
Properties
 
Form:
Solid  
MP:
196 °C (dec.)(lit.)  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
202  
Covalently-Bonded Unit Count:
2  
Heavy Atom Count:
20  
Hydrogen Bond Donor Count:
1  
Rotatable Bond Count:
3  

Literature

Title: Synthesis of kifunensine thioanalogs and their inhibitory activities against HIV-RT and α-mannosidase.

Journal: Carbohydrate research 20130110

Title: Copper-catalyzed ortho-acylation of phenols with aryl aldehydes and its application in one-step preparation of xanthones.

Journal: Chemical communications (Cambridge, England) 20121125

Title: Mixed ligand palladium(II) complexes of 6-methoxy-2-oxo-1,2-dihydroquinoline-3-carbaldehyde 4N-substituted thiosemicarbazones with triphenylphosphine co-ligand: synthesis, crystal structure and biological properties.

Journal: Dalton transactions (Cambridge, England : 2003) 20121121

Title: Nitrous-acid-mediated synthesis of iron-nitrosyl-porphyrin: pH-dependent release of nitric oxide.

Journal: Chemistry, an Asian journal 20121101

Title: Reaction between enaminones and acetylenic esters in the presence of triphenylphosphine: a convenient synthesis of alkyl 2(1-benzyl-2,4-dioxo-2,3,4,5,6,7-hexahydro-1H-indol-3-yl)acetates.

Journal: Molecular diversity 20120801

Title: Silver(I)-catalyzed carboxylation of arylboronic esters with CO2.

Journal: Chemical communications (Cambridge, England) 20120625

Title: Mixed ligand-silver(I) complexes with anti-inflammatory agents which can bind to lipoxygenase and calf-thymus DNA, modulating their function and inducing apoptosis.

Journal: Metallomics : integrated biometal science 20120601

Title: Synthesis and characterization of triphenylphosphine adducts of ferrocene-based palladacycles and their performance in the Suzuki and Sonogashira reactions with bromo- and chloroarenes.

Journal: Molecules (Basel, Switzerland) 20120509

Title: Microwave-assisted synthesis of cyclopentanones using the relevant phosphorus ylides.

Journal: Combinatorial chemistry & high throughput screening 20120501

Title: The use of a cis-dioxomolybdenum(VI) dinuclear complex with quadradentate 1,4-benzenediylbis(benzyldithiocarbamate)(2-) as model compound for the active site of oxo transfer molybdoenzymes: reactivity, kinetics, and catalysis.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120301

Title: Ruthenium(II)/(III) complexes of 4-hydroxy-pyridine-2,6-dicarboxylic acid with PPh3/AsPh3 as co-ligand: impact of oxidation state and co-ligands on anticancer activity in vitro.

Journal: Dalton transactions (Cambridge, England : 2003) 20120221

Title: Identification of protein nitrosothiols using phosphine-mediated selective reduction.

Journal: Nitric oxide : biology and chemistry 20120101

Title: Solubilization of triphenylamine, triphenylphosphine, triphenylphosphineoxide and triphenylmethanol in single and binary surfactant systems.

Journal: Journal of colloid and interface science 20111201

Title: A DFT comparison of the neutral and cationic Heck pathways.

Journal: Dalton transactions (Cambridge, England : 2003) 20111114

Title: Azide-reactive liposome for chemoselective and biocompatible liposomal surface functionalization and glyco-liposomal microarray fabrication.

Journal: Langmuir : the ACS journal of surfaces and colloids 20111101

Title: Unusual catalytic effect of the two-dimensional molecular space with regular triphenylphosphine groups.

Journal: Langmuir : the ACS journal of surfaces and colloids 20111004

Title: Inhibition of lipoxygenase (LOX) and anticancer activity caused by gold(I) mixed ligands complexes of triphenylphosphine and thioamides.

Journal: Journal of enzyme inhibition and medicinal chemistry 20110801

Title: Phosphine-catalyzed [3 + 2] cycloaddition of allenoates with trifluoromethylketones: synthesis of dihydrofurans and tetrahydrofurans.

Journal: Organic & biomolecular chemistry 20110721

Title: Solution and mechanochemical syntheses, and spectroscopic and structural studies in the silver(I) (bi-)carbonate: triphenylphosphine system.

Journal: Dalton transactions (Cambridge, England : 2003) 20110721

Title: o-Semiquinonato and o-iminosemiquinonato rhodium complexes. EPR study of the reactions in coordination sphere of rhodium.

Journal: Journal of magnetic resonance (San Diego, Calif. : 1997) 20110401

Title: Flow synthesis of organic azides and the multistep synthesis of imines and amines using a new monolithic triphenylphosphine reagent.

Journal: Organic & biomolecular chemistry 20110321

Title: Preparation, spectroscopy, EXAFS, electrochemistry and pharmacology of new ruthenium(II) carbonyl complexes containing ferrocenylthiosemicarbazone and triphenylphosphine/arsine.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20110201

Title: Re(V) and Re(III) complexes with sal2phen and triphenylphosphine: rearrangement, oxidation and reduction.

Journal: Dalton transactions (Cambridge, England : 2003) 20110107

Title: Synthesis, structure and biological evaluation of bis salicylaldehyde-4(N)-ethylthiosemicarbazone ruthenium(iii) triphenylphosphine.

Journal: Metallomics : integrated biometal science 20110101

Title: Chemically selective liposome surface glyco-functionalization.

Journal: Methods in molecular biology (Clifton, N.J.) 20110101

Title: Surface-bound cytomimetic assembly based on chemoselective and biocompatible immobilization and further modification of intact liposome.

Journal: Bioconjugate chemistry 20101117

Title: Synthesis of highly substituted pyrroles via nucleophilic catalysis.

Journal: The Journal of organic chemistry 20100917

Title: Ex vivo oxidation in tissue and plasma assays of hydroxyoctadecadienoates: Z,E/E,E stereoisomer ratios.

Journal: Chemical research in toxicology 20100517

Title: Photophysical properties of ruthenium(II) polypyridyl-gold(I) ethynyl dyads and triads containing mono- or diethynylphenanthroline incorporated into gold(I) triphenylphosphine organometallics.

Journal: Inorganic chemistry 20100503

Title: Gold(I) triphenylphosphine complexes incorporating pentaarylfulleride ligands.

Journal: Inorganic chemistry 20100503

Title: Catalytic properties of [Pd(COOMe)(n)X(2-n)(PPh(3))(2)] (n = 0, 1, 2; X = Cl, NO(2), ONO(2), OAc and OTs) in the oxidative carbonylation of MeOH.

Journal: Inorganic chemistry 20100419

Title: Synthesis and reactivity of oxo-peroxo-vanadium(V) bipyridine compounds.

Journal: Inorganic chemistry 20100301

Title: Cycloaurated triphenylphosphine-sulfide and -selenide.

Journal: Dalton transactions (Cambridge, England : 2003) 20100221

Title: Anti-trypanosomatid benzofuroxans and deoxygenated analogues: synthesis using polymer-supported triphenylphosphine, biological evaluation and mechanism of action studies.

Journal: European journal of medicinal chemistry 20091201

Title: Hard/soft selectivity in ligand substitution reactions of beta-diketonate platinum(II) complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20091007

Title: Synthesis, spectral characterization, catalytic and antibacterial studies of new Ru(III) Schiff base complexes containing chloride/bromide and triphenylphosphine/arsine as co-ligands.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20091001

Title: Triphenylphosphine reduction of saturated endoperoxides.

Journal: Organic letters 20090903

Title: Noncovalent interactions in a transition-metal triphenylphosphine complex: a density functional case study.

Journal: Inorganic chemistry 20090601

Title: Ultraviolet A-induced peroxidation of phosphatidylcholine in unilamellar liposomes.

Journal: Bioscience, biotechnology, and biochemistry 20090501

Title: Cross coupling reactions of chiral secondary organoboronic esters with retention of configuration.

Journal: Journal of the American Chemical Society 20090415

Title: Radical intermediates in chloroform reactions over triphenylphosphine-protected Au nanoparticles.

Journal: Organic & biomolecular chemistry 20090407

Title: Cyclopentadienone iron alcohol complexes: synthesis, reactivity, and implications for the mechanism of iron-catalyzed hydrogenation of aldehydes.

Journal: Journal of the American Chemical Society 20090225

Title: A cascade approach to pyridines from 2-azido-2,4-dienoates and alpha-diazocarbonyl compounds.

Journal: The Journal of organic chemistry 20090116

Title: Protein detection using oligonucleotide probes.

Journal: Nucleic acids symposium series (2004) 20090101

Title: A new five-coordinated CuIP2NO2 system: XRD structure of 6-acetyl-1,3,7-trimethyl-pteridine-2,4(1H,3H)-dione and its Cu(I) (N5,O61,O4)-tridentate complex with triphenylphosphine. An AIM study of the nature of metal-ligand bonds.

Journal: Dalton transactions (Cambridge, England : 2003) 20081207

Title: Synthesis of neoglycoconjugates by the desulfurative rearrangement of allylic disulfides.

Journal: The Journal of organic chemistry 20080919

Title: Rhodium-catalyzed substitution reaction of aryl fluorides with disulfides: p-orientation in the polyarylthiolation of polyfluorobenzenes.

Journal: Journal of the American Chemical Society 20080917

Title: Transition-metal-catalyzed chemoselective methylenation of dicarbonyl substrates.

Journal: The Journal of organic chemistry 20080905

Title: Absolute rate constants for some intermolecular reactions of alpha-aminoalkylperoxyl radicals. Comparison with alkylperoxyls.

Journal: The Journal of organic chemistry 20080905

Title: Substituent effect on the efficiency of desulfurizative rearrangement of allylic disulfides.

Journal: The Journal of organic chemistry 20080815

Title: The structure of polymer-supported triphenylphosphine ditriflate: a potentially useful reagent in organic synthesis.

Journal: The Journal of organic chemistry 20080620

Title: Effects of targeting moiety, linker, bifunctional chelator, and molecular charge on biological properties of 64Cu-labeled triphenylphosphonium cations.

Journal: Journal of medicinal chemistry 20080522

Title: Highly active catalysts for the telomerization of crude glycerol with 1,3-butadiene.

Journal: ChemSusChem 20080101

Title: Palladium-based telomerization of 1,3-butadiene with glycerol using methoxy-functionalized triphenylphosphine ligands.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

Title: Novel HPMA copolymer-bound constructs for combined tumor and mitochondrial targeting.

Journal: Molecular pharmaceutics 20080101

Title: Determination of peroxide value of edible oils by FTIR spectroscopy with the use of the spectral reconstitution technique.

Journal: Talanta 20071130

Title: Anti-Markovnikov addition of both primary and secondary amines to terminal alkynes catalyzed by the TpRh(C2H4)2/PPh3 system.

Journal: Journal of the American Chemical Society 20071114

Title: Adducts of uridine and glycals as potential substrates for glycosyltransferases.

Journal: Bioorganic chemistry 20071001

Title: Variable coordination behaviour of pyrazole-containing N,P and N,P(O) ligands towards palladium(II).

Journal: Dalton transactions (Cambridge, England : 2003) 20070714

Title: Synthesis of oxime phosphoranes from reaction between triphenylphosphine and acetylenic esters in the presence of oxime derivatives.

Journal: Molecular diversity 20070501

Title: Site-selective post-translational modification of proteins using an unnatural amino acid, 3-azidotyrosine.

Journal: Journal of biochemistry 20070301

Title: Evaluation of methods for the determination of water in substances with unknown chemical and thermal behaviour.

Journal: Journal of pharmaceutical and biomedical analysis 20070117

Title: RuCl3/PPh3: an efficient combination for the preparation of chiral 1,3-anti-diols through catalytic hydrogenation.

Journal: Organic letters 20070104

Title: 4-O-Acetyl-3-O-tert-butyldimethylsilyl-L-rhamnal: a building block in the stereoselective synthesis of 2-deoxy-alpha-L-rhamnopyranosides.

Journal: Carbohydrate research 20061127

Title: DNA-programmed chemistry in rapid homogeneous assays for DNA and protein targets.

Journal: Clinical chemistry 20061101

Title: Determination of triphenylphosphine oxide in active pharmaceutical ingredients by hollow-fiber liquid-phase microextraction followed by reversed-phase liquid chromatography.

Journal: Journal of chromatography. A 20060915

Title: Isolation and synthesis of acmellonate, a new unsaturated long chain 2-ketol ester from Spilanthes acmella.

Journal: Natural product research 20060720

Title: Kinetics, mechanism, and computational studies of rhenium-catalyzed desulfurization reactions of thiiranes (thioepoxides).

Journal: Inorganic chemistry 20060710

Title: Spectral, redox and catalytic studies of triphenylphosphine/triphenylarsine complexes of Ru(III) with N, O donor ligands derived from 2-hydroxy-1-naphthaldehyde and primary amines.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20060701

Title: A one-pot entry to a novel 3-H-benzo[d]pyrazolo[1,5-b]isothiazole ring system.

Journal: Molecular diversity 20060501

Title: Cu(I) dinuclear complexes with tripodal ligands vs monodentate donors: triphenylphosphine, thiourea, and pyridine. A 1H NMR titration study.

Journal: Inorganic chemistry 20060417

Title: Triphenylphosphine as a ligand for room-temperature Ni(0)-catalyzed cross-coupling reactions of aryl chlorides with arylboronic acids.

Journal: The Journal of organic chemistry 20060303

Title: Phosphine-ligated induced formation of thallium(I) full Pt3TlPt3 sandwich versus 'open-face' TlPt3 sandwich with triangular Pt3(mu2-CO)3(PR3)3 units: synthesis and structural/spectroscopic analysis of triphenylphosphine [(mu3-Tl)Pt3(mu2-CO)3(PPh3)3]+ and its (mu3-AuPPh3)Pt3 analogue.

Journal: Dalton transactions (Cambridge, England : 2003) 20060227

Title: Three-component reaction between triphenylphosphine, dialkyl acetylenedicarboxylates and urea or N-methylurea.

Journal: Molecular diversity 20060201

Title: Studies on the structure behavior of triphenyldichlorophosphorane in different solvents.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20060101

Title: Synthesis and structure of cycloruthenated carbonyl complexes and their emission, redox and biological properties.

Journal: Journal of inorganic biochemistry 20060101

Title: [Functionalized nanocomposite coating of a glass surface for oligonucleotide immobilization].

Journal: Bioorganicheskaia khimiia 20060101

Title: Controllable pt nanoparticle deposition on carbon nanotubes as an anode catalyst for direct methanol fuel cells.

Journal: The journal of physical chemistry. B 20051201

Title: Synthesis of 3-amino-1,2,4-benzothiadi- azine 1,1-dioxides via a tandem aza-Wittig/heterocumulene annulation.

Journal: The Journal of organic chemistry 20051125

Title: Efficient solid-phase synthesis of highly functionalized 1,4-benzodiazepin-5-one derivatives and related compounds by intramolecular aza-Wittig reactions.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20050422

Title: Regioselective nucleophilic addition of triphenylphosphine to the nitrosylruthenium alkynyl complexes having a hydrotris(pyrazol-1-yl)borate: formation of phosphonio-alkenyl, alkynyl, and allenyl species.

Journal: Dalton transactions (Cambridge, England : 2003) 20050307

Title: Mitochondriotropic liposomes.

Journal: Journal of liposome research 20050101

Title: Fluorous reagents and scavengers versus solid-supported reagents and scavengers, a reaction rate and kinetic comparison.

Journal: Molecular diversity 20050101

Title: Preparation of nucleoside H-phosphonoselenoate monoesters via the phosphinate approach.

Journal: Nucleosides, nucleotides & nucleic acids 20050101

Title: Nucleic acid-triggered fluorescent probe activation by the Staudinger reaction.

Journal: Journal of the American Chemical Society 20041222

Title: Extraction and transport of chromium(VI) through a bulk liquid membrane containing triphenylphosphine.

Journal: Annali di chimica 20041201

Title: Separation-friendly Mitsunobu reactions: a microcosm of recent developments in separation strategies.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20040705

Title: Direct synthesis of sulfonamides and activated sulfonate esters from sulfonic acids.

Journal: Journal of the American Chemical Society 20040204

Title: Synthesis, spectroscopic characterization, redox properties and catalytic activity of some ruthenium(II) complexes containing aromatic aldehyde and triphenylphosphine or triphenylarsine.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20040101

Title: Role of carboxylate bridges in modulating nonheme diiron(II)/O(2) reactivity.

Journal: Inorganic chemistry 20031117

Title: Measurement of plasma hydroperoxide concentration by FOX-1 assay in conjunction with triphenylphosphine.

Journal: Clinica chimica acta; international journal of clinical chemistry 20031101

Title: Thermodynamic hydride donor abilities of [HW(CO)4L]- complexes (L = PPh3, P(OMe)3, CO) and their reactions with [C5Me5Re(PMe3)(NO)(CO)]+.

Journal: Journal of the American Chemical Society 20031008

Title: Thermally induced stoichiometric and catalytic O-atom transfer by a non-heme iron(III)-nitro complex: first example of reversible [Fe-NO]7<-->FeIII-NO2 transformation in the presence of dioxygen.

Journal: Angewandte Chemie (International ed. in English) 20030929

Title: An easy access to halide ion-catalytic alpha-glycosylation using carbon tetrabromide and triphenylphosphine as multifunctional reagents.

Journal: Organic & biomolecular chemistry 20030721

Title: An improved procedure for the preparation of 8-substituted guanines.

Journal: Chemical communications (Cambridge, England) 20030621

Title: Synthesis of p, p'-divinylazobenzene.

Journal: Di 1 jun yi da xue xue bao = Academic journal of the first medical college of PLA 20030301

Title: Specificity of the ferrous oxidation of xylenol orange assay: analysis of autoxidation products of cholesteryl arachidonate.

Journal: Analytical biochemistry 20030215

Title: Distributions of hydroperoxide positional isomers generated by oxidation of 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine in liposomes and in methanol solution.

Journal: Lipids 20030101

Title: A novel one-pot, four component synthesis of some densely functionalized pyrroles.

Journal: Molecular diversity 20030101

Title: One-step synthesis of non-anomeric sugar isothiocyanates from sugar azides.

Journal: Carbohydrate research 20021119

Title: Tandem intermolecular Suzuki coupling/intramolecular vinyl triflate-arene coupling.

Journal: Chemical communications (Cambridge, England) 20020421

Title: New examples of mixed seleno-sulfides; reactions with triphenylphosphine.

Journal: Chemical communications (Cambridge, England) 20020307

Title: Thermodynamic insight into the origin of the inclusion of monosulfonated isomers of triphenylphosphine into the beta-cyclodextrin cavity.

Journal: Carbohydrate research 20020211

Title: Investigation of the influence of charge derivatization on the fragmentation of multiply protonated peptides.

Journal: Journal of the American Society for Mass Spectrometry 20020101

Title: Catalysis of NO production by a molybdoenzyme model.

Journal: Organic letters 20011115

Title: Synthesis and structural characterization of a novel covalently-bound corrole dimer.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20011001

Title: Carbohydrate-derived alkylcobalt carbonyl:([(1,2:5,6-di-O,O-isopropylidene-alpha-D-glucofuranos-3-yl)oxycarbonyl]methyl)cobalt tricarbonyl triphenylphosphene.

Journal: Chirality 20010801

Title: Efficient scavenging of Ph3P and Ph3P=O with high-loading merrifield resin.

Journal: Organic letters 20010614

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Tags:6399-81-1 Molecular Formula|6399-81-1 MDL|6399-81-1 SMILES|6399-81-1 Triphenylphosphine hydrobromide