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803-14-5,MFCD22551639
Catalog No.:AA005BGY

803-14-5 | Ethyl 2-bromo-2-(triphenylphosphoranylidene)acetate

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Purity
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250mg
≥95%
2 weeks  
$289.00   $202.00
- +
1g
≥95%
2 weeks  
$304.00   $213.00
- +
5g
≥95%
2 weeks  
$781.00   $547.00
- +
10g
≥95%
2 weeks  
$1,334.00   $934.00
- +
  • Technical Information
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  • Technical Information
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  • Downstream Synthesis Route
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Technical Information
Catalog Number:
AA005BGY
Chemical Name:
Ethyl 2-bromo-2-(triphenylphosphoranylidene)acetate
CAS Number:
803-14-5
Molecular Formula:
C22H20BrO2P
Molecular Weight:
427.2708
MDL Number:
MFCD22551639
SMILES:
CCOC(=O)C(=P(c1ccccc1)(c1ccccc1)c1ccccc1)Br
Properties
Properties
 
Form:
Solid  
MP:
155-156℃  


Downstream Synthesis Route

[1]CurrentPatentAssignee:JOHNSON&JOHNSONINC-WO2018/31818,2018,A2Locationinpatent:Paragraph0413

[2]Hong,Bor-Cherng;Lin,Cheng-Wei;Liao,Wei-Kai;Lee,Gene-Hsiang[OrganicLetters,2013,vol.15,#24,p.6258-6261]

[3]Sarkar,Somnath;Ghosh,Swarbhanu;Mondal,Jahangir;Islam,Sk.Manirul[ChemicalCommunications,2020,vol.56,#81,p.12202-12205]

[4]Gong,Xiaoyu;Yang,Haijun;Liu,Hongxia;Jiang,Yuyang;Zhao,Yufen;Fu,Hua[OrganicLetters,2010,vol.12,#14,p.3128-3131]

[5]Sharma,Siddharth;Singh,AjayK.;Singh,Devendra;Kim,Dong-Pyo[GreenChemistry,2015,vol.17,#3,p.1404-1407]

[6]Zhang,Minghao;Deng,Wenbo;Sun,Mingjie;Zhou,Liwei;Deng,Guobo;Liang,Yun;Yang,Yuan[OrganicLetters,2021,vol.23,#15,p.5744-5749]

[7]Chakraborty;Mandal;Roy[JournalofChemicalSciences,2016,vol.128,#7,p.1067-1079]

[8]Sun,Huan-Li;Chen,Fei;Xie,Ming-Sheng;Guo,Hai-Ming;Qu,Gui-Rong;He,Yan-Mei;Fan,Qing-Hua[OrganicLetters,2016,vol.18,#9,p.2260-2263]

[9]Magdesieva,N.N.;Kyandzhetsian,R.A.[JournalofOrganicChemistryUSSR(EnglishTranslation),1979,vol.15,p.2169-2173][ZhurnalOrganicheskoiKhimii,1979,vol.15,p.2396-2402]

[10]Huang,Zhizhen;Yu,Xiaochun;Huang,Xian[JournalofOrganicChemistry,2002,vol.67,#23,p.8261-8264]

[11]Chen,Jian;Liu,Qiang;Zhang,Weicheng;Spinella,Stephen;Lei,Aiwen;Zhang,Xumu[OrganicLetters,2008,vol.10,#14,p.3033-3036]

[12]Suzuki,Mitsuharu;Comito,Angelo;Khan,SaeedI.;Rubin,Yves[OrganicLetters,2010,vol.12,#10,p.2346-2349]

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4.5.6.7.8-Penta-O-acetyl-D-gluco-trans-2-brom-2.3-didehydro-2.3-didesoxy-aldonsaeure-aethylester 

[1]BulletinoftheAcademyofSciencesoftheUSSRDivisionofChemicalScience,1967,p.2564-2568    IzvestiyaAkademiiNaukSSSR,SeriyaKhimicheskaya,1967,p.2691-2697

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tert-butyl6-(2-ethoxy-2-oxoethylidene)-2-azaspiro3.3heptane-2-carboxylate 

[1]Patent:US2018/99940,2018,A1.Locationinpatent:Paragraph0407-0408

1195-08-0    803-14-5   
ethyl2-bromo-3-(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)acrylate 

[1]Patent:WO2020/84389,2020,A1.Locationinpatent:Page/Pagecolumn4;7-8

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