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935-14-8,MFCD00078375
Catalog No.:AA0032K8

935-14-8 | 1,4-Diethynylbenzene

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  • Technical Information
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0032K8
Chemical Name:
1,4-Diethynylbenzene
CAS Number:
935-14-8
Molecular Formula:
C10H6
Molecular Weight:
126.1546
MDL Number:
MFCD00078375
SMILES:
C#Cc1ccc(cc1)C#C
Properties
Properties
 
BP:
182.8°C at 760 mmHg  
Form:
Solid  
MP:
94-98 °C(lit.)  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
163  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
10  
Rotatable Bond Count:
2  
XLogP3:
2.4  

Literature

Title: Base-mediated selective synthesis of diversely substituted N-heterocyclic enamines and enaminones by the hydroamination of alkynes.

Journal: The Journal of organic chemistry 20120706

Title: Thermodynamic and kinetic stabilities of complementary double helices utilizing amidinium-carboxylate salt bridges.

Journal: Journal of the American Chemical Society 20120606

Title: Topological and electronic influences on magnetic exchange coupling in Fe(III) ethynylbenzene dendritic building blocks.

Journal: Journal of the American Chemical Society 20111228

Title: Simultaneous bridge-localized and mixed-valence character in diruthenium radical cations featuring diethynylaromatic bridging ligands.

Journal: Journal of the American Chemical Society 20111116

Title: Reactivity of the 16e (p-cymene)Ru half-sandwich complex containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligand towards diynes.

Journal: Dalton transactions (Cambridge, England : 2003) 20110714

Title: Highly CO2-selective organic molecular cages: what determines the CO2 selectivity.

Journal: Journal of the American Chemical Society 20110504

Title: Synthesis and SAR studies of 1,4-benzoxazine MenB inhibitors: novel antibacterial agents against Mycobacterium tuberculosis.

Journal: Bioorganic & medicinal chemistry letters 20101101

Title: Synthesis and solid state characterization of molecular rotors with steroidal stators: ethisterone and norethisterone.

Journal: Organic & biomolecular chemistry 20100628

Title: Topological dependence of the magnetic exchange coupling in arylethynyl-bridged organometallic diradicals containing [(eta(2)-dppe)(eta(5)-C(5)Me(5))Fe(III)](+) fragments.

Journal: Inorganic chemistry 20091116

Title: Length dependence for intramolecular energy transfer in three- and four-color donor-spacer-acceptor arrays.

Journal: Journal of the American Chemical Society 20090923

Title: Synthesis and EPR studies of 2'-deoxyuridines with alkynyl, rodlike linkages.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20090803

Title: Synthesis and electrochemical characterization of halide, isocyanide, and alkynyl synthons containing the encumbered triangular cluster unit Pt3(mu-P(t)Bu2)3.

Journal: Inorganic chemistry 20090216

Title: Synthesis of rare-metal absorbing polymer by three-component polyaddition through combination of chemo-selective nucleophilic and radical additions.

Journal: Journal of the American Chemical Society 20090211

Title: Electronic energy transfer to the S2 level of the acceptor in functionalised boron dipyrromethene dyes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20090101

Title: 9,10-Dihydro-9,10-diboraanthracene: supramolecular structure and use as a building block for luminescent conjugated polymers.

Journal: Angewandte Chemie (International ed. in English) 20090101

Title: Fine structures of 8-G-1-(p-YC6H4C identical with CSe)C10H6 (G = H, Cl, and Br) in crystals and solutions: ethynyl influence and Y- and G-dependences.

Journal: Bioinorganic chemistry and applications 20090101

Title: Highly luminescent BODIPY-based organoboron polymer exhibiting supramolecular self-assemble structure.

Journal: Journal of the American Chemical Society 20081119

Title: Macrocyclic cyclophanes with two and three alpha,omega-dichalcogena-1,4-diethynylaryl units: syntheses and structural properties.

Journal: The Journal of organic chemistry 20081017

Title: One-step synthesis of low molecular weight poly(p-phenyleneethynylenevinylene)s via polyaddition of aromatic diynes by catalysis of the [Ru(p-cymene)Cl2]2/AcOH system.

Journal: The Journal of organic chemistry 20080516

Title: Synthesis and characterization of cruciform-conjugated molecules based on tetrathiafulvalene.

Journal: The Journal of organic chemistry 20080418

Title: Directed 1D assembly of a ring-shaped inorganic nanocluster templated by an organic rigid-rod molecule: an inorganic/organic polypseudorotaxane.

Journal: Angewandte Chemie (International ed. in English) 20080101

Title: Energy flow in a purpose-built cascade molecule bearing three distinct chromophores attached to the terminal acceptor.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

Title: In situ Raman monitoring triazole formation from self-assembled monolayers of 1,4-diethynylbenzene on Ag and Au surfaces via 'click' cyclization.

Journal: Journal of colloid and interface science 20070715

Title: Synthesis and photophysical properties of carbazole-based blue light-emitting dendrimers.

Journal: The Journal of organic chemistry 20070622

Title: Ethynylbenzene monolayers on gold: a metal-molecule binding motif derived from a hydrocarbon.

Journal: Journal of the American Chemical Society 20070328

Title: A two stage click-based library of protein tyrosine phosphatase inhibitors.

Journal: Bioorganic & medicinal chemistry 20070101

Title: Design, synthesis, and BK channel-opening activity of hexahydrodibenzazepinone derivatives.

Journal: Bioorganic & medicinal chemistry 20061201

Title: Improved physical properties and rotational dynamics in a molecular gyroscope with an asymmetric stator structure.

Journal: Organic letters 20060803

Title: Molecular structure and benzene ring deformation of three ethynylbenzenes from gas-phase electron diffraction and quantum chemical calculations.

Journal: The journal of physical chemistry. A 20060209

Title: Two-photon photochromism of diarylethene dimer derivatives.

Journal: Chemphyschem : a European journal of chemical physics and physical chemistry 20051111

Title: Photoinduced electron transfer in platinum(II) terpyridinyl acetylide complexes connected to a porphyrin unit.

Journal: Inorganic chemistry 20050627

Title: Di([5]trovacenyl)ethyne, di([5]trovacenyl)butadiyne, and di-1,4-([5]trovacenylethynyl)benzene: electrocommunication and magnetocommunication mediated by --C triple bond C--, --C triple bond C--C triple bond C-- and --C triple bond C--C6H4--C triple bond C-- spacers.

Journal: Inorganic chemistry 20050221

Title: Synthesis, characterisation and optical spectroscopy of platinum(II) di-ynes and poly-ynes incorporating condensed aromatic spacers in the backbone.

Journal: Dalton transactions (Cambridge, England : 2003) 20040807

Title: Synthesis of linear and tripoidal oligo(phenylene ethynylene)-based building blocks for application in modular DNA-programmed assembly.

Journal: The Journal of organic chemistry 20040402

Title: Trinuclear and hexanuclear platinum clusters as building blocks for organometallic one-dimensional structures.

Journal: Chemical communications (Cambridge, England) 20030921

Title: Influence of delocalization on the stability of dianions: study of a systematic series of dianions with growing electronic localization.

Journal: Journal of the American Chemical Society 20030806

Title: Oxidative polymerization of 1,4-diethynylbenzene into highly conjugated poly(phenylene butadiynylene) within the channels of surface-functionalized mesoporous silica and alumina materials.

Journal: Journal of the American Chemical Society 20020807

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