Home Imidazoles 492-98-8
492-98-8,MFCD00047014
Catalog No.:AA00374K

492-98-8 | 2,2'-Biimidazole

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250mg
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1g
95%
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$8.00   $5.00
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5g
97%
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$13.00   $9.00
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25g
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA00374K
Chemical Name:
2,2'-Biimidazole
CAS Number:
492-98-8
Molecular Formula:
C6H6N4
Molecular Weight:
134.1386
MDL Number:
MFCD00047014
SMILES:
c1cnc([nH]1)c1ncc[nH]1
NSC Number:
522950
Properties
Properties
 
Form:
Solid  
MP:
>350°C  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
102  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
10  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
2  
Rotatable Bond Count:
1  
XLogP3:
-0.1  

Upstream Synthesis Route

[1]Patent:US2003/199700,2003,A1,.Locationinpatent:Page/Pagecolumn2

[2]Patent:US2003/199700,2003,A1,.Locationinpatent:Page/Pagecolumn2

[3]ArchivderPharmazie,1986,vol.319,#2,p.183-185

[4]Patent:US2003/199700,2003,A1,.Locationinpatent:Page/Pagecolumn2

[5]Patent:US2003/199700,2003,A1,.Locationinpatent:Page/Pagecolumn2

[6]Patent:US2003/199700,2003,A1,.Locationinpatent:Page/Pagecolumn2

[7]OrganicLetters,2004,vol.6,#21,p.3845-3847

[8]ZeitschriftfurAnorganischeundAllgemeineChemie,2012,vol.638,#9,p.1278-1286

[9]BulletinoftheChemicalSocietyofJapan,1995,vol.68,#7,p.1753-1774

[10]JournalofMaterialsChemistryC,2017,vol.5,#14,p.3519-3527

[11]CanadianJournalofChemistry,2009,vol.87,#6,p.729-737

[12]JournalofHeterocyclicChemistry,2002,vol.39,#4,p.733-735

[13]OrganicLetters,2018,vol.20,#12,p.3613-3617

[14]JournalofOrganicChemistry,1989,vol.54,#13,p.3057-3061

[15]AustralianJournalofChemistry,1994,vol.47,#4,p.723-738

[16]JournaloftheAmericanChemicalSociety,2003,vol.125,#16,p.4951-4957

[17]JournalofFluorineChemistry,2009,vol.130,#6,p.522-527

[18]Patent:WO2005/26178,2005,A2,.Locationinpatent:Page/Pagecolumn77;Sheet31

[19]BulletinoftheKoreanChemicalSociety,2012,vol.33,#11,p.3645-3650

[20]NewJournalofChemistry,2013,vol.37,#11,p.3706-3715

[21]RSCAdvances,2014,vol.4,#44,p.23116-23124

[22]AustralianJournalofChemistry,2015,vol.68,#10,p.1513-1517

[23]Chemistry-AEuropeanJournal,2016,vol.22,#6,p.2108-2113

[24]CatalysisLetters,2016,vol.146,#4,p.841-850

[25]EuropeanJournalofInorganicChemistry,2017,vol.2017,#12,p.1764-1771

[1]ChemistryofHeterocyclicCompounds(NewYork,NY,UnitedStates),1987,vol.23,#8,p.854-856

[2]KhimiyaGeterotsiklicheskikhSoedinenii,1987,#8,p.1069-1070

[1]Synthesis,1986,#4,p.336-337

[1]NewJournalofChemistry,2015,vol.39,#3,p.1827-1839

[2]JustusLiebigsAnnalenderChemie,1918,vol.416,p.231

[3]JustusLiebigsAnnalenderChemie,1927,vol.456,p.259,269,270,271

[4]ChemistryofHeterocyclicCompounds,2017,vol.53,#6-7,p.697-701

[5]Khim.Geterotsikl.Soedin.,2017,vol.53,#6-7,p.697-701,5

[1]JournalofMaterialsChemistryC,2016,vol.4,#17,p.3726-3737

Downstream Synthesis Route

[1]Patent:US2003/199700,2003,A1.Locationinpatent:Page/Pagecolumn2

[2]Patent:US2003/199700,2003,A1.Locationinpatent:Page/Pagecolumn2

[3]ArchivderPharmazie,1986,vol.319,p.183-185

[4]Patent:US2003/199700,2003,A1.Locationinpatent:Page/Pagecolumn2

[5]Patent:US2003/199700,2003,A1.Locationinpatent:Page/Pagecolumn2

[6]Patent:US2003/199700,2003,A1.Locationinpatent:Page/Pagecolumn2

[7]OrganicLetters,2004,vol.6,p.3845-3847

[8]ZeitschriftfurAnorganischeundAllgemeineChemie,2012,vol.638,p.1278-1286

[9]BulletinoftheChemicalSocietyofJapan,1995,vol.68,p.1753-1774

[10]JournalofMaterialsChemistryC,2017,vol.5,p.3519-3527

[11]CanadianJournalofChemistry,2009,vol.87,p.729-737

[12]JournalofHeterocyclicChemistry,2002,vol.39,p.733-735

[13]OrganicLetters,2018,vol.20,p.3613-3617

[14]JournalofOrganicChemistry,1989,vol.54,p.3057-3061

[15]GreenChemistry,2020,vol.22,p.913-920

[16]AustralianJournalofChemistry,1994,vol.47,p.723-738

[17]JournaloftheAmericanChemicalSociety,2003,vol.125,p.4951-4957

[18]JournalofFluorineChemistry,2009,vol.130,p.522-527

[19]Patent:WO2005/26178,2005,A2.Locationinpatent:Page/Pagecolumn77;Sheet31

[20]BulletinoftheKoreanChemicalSociety,2012,vol.33,p.3645-3650

[21]NewJournalofChemistry,2013,vol.37,p.3706-3715

[22]RSCAdvances,2014,vol.4,p.23116-23124

[23]AustralianJournalofChemistry,2015,vol.68,p.1513-1517

[24]Chemistry-AEuropeanJournal,2016,vol.22,p.2108-2113

[25]CatalysisLetters,2016,vol.146,p.841-850

[26]EuropeanJournalofInorganicChemistry,2017,vol.2017,p.1764-1771

[27]Molecules,2019,vol.24

[28]SpectrochimicaActaPartA:MolecularandBiomolecularSpectroscopy,2019,vol.223

[29]OrganicLetters,2019,vol.21,p.8201-8204

[1]Patent:WO2005/26178,2005,A2.Locationinpatent:Page/Pagecolumn77-78;Sheet31

[2]JournaloftheAmericanChemicalSociety,2003,vol.125,p.4951-4957

[1]JournaloftheAmericanChemicalSociety,2003,vol.125,p.4951-4957

492-98-8    542-69-8   
1,1'-di-n-butyl-1H,1'H-2,2'-biimidazole 

[1]OrganicLetters,2004,vol.6,p.3845-3847

[2]EuropeanJournalofInorganicChemistry,2017,vol.2017,p.1764-1771

108-86-1    492-98-8   
1-(1H-imidazol-2-yl)-1-phenyl-1H-imidazole 

[1]JournaloftheAmericanChemicalSociety,2007,vol.129,p.13879-13886

[2]JournalofOrganicChemistry,2007,vol.72,p.2737-2743

[3]JournalofOrganicChemistry,2007,vol.72,p.8535-8538

Literature

Title: Interaction between biimidazole complexes of ruthenium and acetate: hydrogen bonding and proton transfer.

Journal: Dalton transactions (Cambridge, England : 2003) 20120621

Title: Origins of the stability of imidazole-imidazole, benzene-imidazole, and benzene-indole dimers: CCSD(T)/CBS and SAPT calculations.

Journal: The journal of physical chemistry. A 20120223

Title: Tris(2,2'-bi-1H-imidazole-κN,N)-nickel(II) dinitrate N,N-dimethyl-formamide monosolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20111101

Title: Tris(2,2'-bi-1H-imidazole-κN,N)cobalt(II) hydrogen phosphate.

Journal: Acta crystallographica. Section E, Structure reports online 20111001

Title: Bis(μ-5-carboxybenzene-1,3-dicarboxylato-κ2O1:O3)bis[(2,2'-bi-1H-imidazole-κ2N3,N3')zinc].

Journal: Acta crystallographica. Section C, Crystal structure communications 20110901

Title: Photophysical, electrochemical and anion sensing properties of Ru(II) bipyridine complexes with 2,2'-biimidazole-like ligand.

Journal: Dalton transactions (Cambridge, England : 2003) 20110828

Title: Bis[2-(1H-imidazol-2-yl-κN)-1H-imidazol-3-ium]silver(I) trinitrate.

Journal: Acta crystallographica. Section E, Structure reports online 20110701

Title: Synthesis, characterization, antiproliferative and anti-metastatic properties of two ruthenium-DMSO complexes containing 2,2'-biimidazole.

Journal: European journal of medicinal chemistry 20110501

Title: Benzoic acid-2,2'-biimidazole (2/1).

Journal: Acta crystallographica. Section E, Structure reports online 20101201

Title: The effect of N-ligands on the geometry, bonding, and electronic absorption properties of ruthenium carbonyl chains.

Journal: Physical chemistry chemical physics : PCCP 20100907

Title: Bis(2,2'-bi-1H-imidazole-κN,N)bis-(dimethyl sulfoxide-κO)copper(II) bis-(tetra-fluoridoborate).

Journal: Acta crystallographica. Section E, Structure reports online 20100901

Title: Tetra-aqua-(1,10-phenanthroline-κN,N')cadmium(II) sulfate dihydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20100801

Title: Control of metal ion size-based selectivity through chelate ring geometry. metal ion complexing properties of 2,2'-biimidazole.

Journal: Inorganic chemistry 20100607

Title: 4-Nitro-benzoic acid-2,2'-biimidazole (2/1).

Journal: Acta crystallographica. Section E, Structure reports online 20100601

Title: Paramagnetic ruthenium-biimidazole derivatives [(acac)2Ru(III)(LHn)]m, n/m = 2/+, 1/0, 0/-. Synthesis, structures, solution properties and anion receptor features in solution state.

Journal: Dalton transactions (Cambridge, England : 2003) 20100507

Title: Tris[2-(1H-imidazol-2-yl)imidazol-1-ido]cobalt(III).

Journal: Acta crystallographica. Section E, Structure reports online 20100501

Title: Biimidazole containing cobalt(III) mixed ligand complexes: Crystal structure and photonuclease activity.

Journal: Dalton transactions (Cambridge, England : 2003) 20100227

Title: Bis(μ-2,2'-biimidazole-κN:N)bis-[aqua-copper(I)] sulfate.

Journal: Acta crystallographica. Section E, Structure reports online 20091201

Title: Bis(2,2'-bi-1H-imidazole-κN,N)(thio-cyanato-κN)copper(II) chloride.

Journal: Acta crystallographica. Section E, Structure reports online 20091101

Title: Synthesis and antibacterial activities of new metronidazole and imidazole derivatives.

Journal: Molecules (Basel, Switzerland) 20090708

Title: Di-tert-butyl 3,3'-(2,2'-bi-1H-imidazole-1,1'-di-yl)dipropanoate.

Journal: Acta crystallographica. Section E, Structure reports online 20090701

Title: The crucial role of C-H...O and C=O...pi interactions in the building of three-dimensional structures of dicarboxylic acid-biimidazole compounds.

Journal: Acta crystallographica. Section C, Crystal structure communications 20090401

Title: 2,2'-(2,2'-Biimidazole-1,1'-di-yl)diethanoic acid.

Journal: Acta crystallographica. Section E, Structure reports online 20090401

Title: Three-dimensional networks in the 1:2 organic salts 2,2'-biimidazolium bis(3-carboxy-4-hydroxybenzenesulfonate) and 2,2'-bibenzimidazolium bis(3-carboxy-4-hydroxybenzenesulfonate) trihydrate.

Journal: Acta crystallographica. Section C, Crystal structure communications 20090201

Title: 3,3'-(2,2'-Bi-1H-imidazole-1,1'-diyl)dipropanol.

Journal: Acta crystallographica. Section E, Structure reports online 20090201

Title: Proton-coupled electron transfer from a luminescent excited state.

Journal: Chemical communications (Cambridge, England) 20080928

Title: 2,2'-Biimidazolium hexa-aqua-manganese(II) bis-(sulfate).

Journal: Acta crystallographica. Section E, Structure reports online 20080801

Title: Diazido-bis(2,2'-biimidazole)manganese(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080701

Title: Diazido-bis(2,2'-biimidazole)iron(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080701

Title: Diaqua-bis(2,2'-biimidazole)cobalt(II) dichloride.

Journal: Acta crystallographica. Section E, Structure reports online 20080201

Title: Bis(2,2'-biimidazole-κN,N')bis-(2-bromo-fumarato-κO)copper(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080101

Title: Diazido-bis(2,2'-biimidazole)cobalt(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080101

Title: Anion-selective interaction and colorimeter by an optical metalloreceptor based on ruthenium(II) 2,2'-biimidazole: hydrogen bonding and proton transfer.

Journal: Inorganic chemistry 20070806

Title: Biimidazole and bis(amide)bipyridine molybdenum carbonyl complexes as anions receptors.

Journal: Inorganic chemistry 20070402

Title: Robust hydrogen-bonded self-assemblies from biimidazole complexes. Synthesis and structural characterization of [M(biimidazole)2(OH2)2]2+ (M = Co2+, Ni2+) complexes and carboxylate modules.

Journal: Dalton transactions (Cambridge, England : 2003) 20040221

Title: Some errors from the crystallographic literature, some amplifications and a questionable result.

Journal: Acta crystallographica. Section B, Structural science 20021001

Title: Anion binding by fluorescent biimidazole diamides.

Journal: The Journal of organic chemistry 20020823

Title: Self-assembled helices from 2,2'-biimidazoles.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20010202

Title: Preparations, characterizations, and structures of (biimidazole)dihalobis(triphenylphosphine)rhenium(III) salts: strong ion-pairing and acid-base properties.

Journal: Inorganic chemistry 20010101

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