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77-99-6,MFCD00004694
Catalog No.:AA003H3Z

77-99-6 | Trimethylolpropane

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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003H3Z
Chemical Name:
Trimethylolpropane
CAS Number:
77-99-6
Molecular Formula:
C6H14O3
Molecular Weight:
134.1736
MDL Number:
MFCD00004694
SMILES:
CCC(CO)(CO)CO
NSC Number:
3576
Properties
Properties
 
BP:
295.7°C at 760 mmHg  
Form:
Solid  
MP:
56-58°C  
Refractive Index:
1.4850 (estimate)  
Solubility:
H2O: 0.1 g/mL, clear  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
60.4  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
9  
Hydrogen Bond Acceptor Count:
3  
Hydrogen Bond Donor Count:
3  
Rotatable Bond Count:
4  
XLogP3:
-0.8  

Upstream Synthesis Route

[1]Polymer,2011,vol.52,#25,p.5716-5722

[2]Patent:JP2016/29040,2016,A,.Locationinpatent:Paragraph0036;0037

[3]Patent:US5057504,1991,A,

[4]OrganicProcessResearchandDevelopment,2001,vol.5,#6,p.568-571

[1]Patent:DE950850,1954,,

[2]JournaloftheAmericanChemicalSociety,1957,vol.79,p.3455

[3]Patent:US5463084,1995,A,

[4]Patent:DE950850,1954,,

[1]OrganicProcessResearchandDevelopment,2001,vol.5,#6,p.568-571

[1]Patent:US6593479,2003,B2,

[1]Macromolecules,2003,vol.36,#11,p.3861-3873

Downstream Synthesis Route

[1]Patent:CN109485544,2019,A.Locationinpatent:Paragraph0018-0027

[2]Patent:US2468718,1947,

[3]Patent:EP1167330,2002,A2.Locationinpatent:Page8

[4]Patent:WO2004/13074,2004,A1.Locationinpatent:Page/Pagecolumn11-13

[5]Patent:WO2007/102637,2007,A1.Locationinpatent:Page/Pagecolumn8;10;11

[6]Patent:US2012/178973,2012,A1.Locationinpatent:Page/Pagecolumn3-4

[7]Patent:US2019/241492,2019,A1.Locationinpatent:Paragraph0049;0050

[1]JournaloftheAmericanChemicalSociety,1957,vol.79,p.3455

[2]Patent:US5463084,1995,A

[3]Patent:DE950850,1954,

[1]Patent:CN109593103,2019,A.Locationinpatent:Paragraph0028-0047

[2]JournaloftheAmericanChemicalSociety,1962,vol.84,p.610-617

[1]InternationalJournalofPharmaceutics,2018,vol.548,p.649-658

[2]MonatsheftefurChemie,1964,vol.95,p.373-378

[3]AngewandteChemie-InternationalEdition,2008,vol.47,p.928-931

[4]SoftMatter,2011,vol.7,p.7948-7951

[5]Patent:CN106580920,2017,A.Locationinpatent:Paragraph0032;0063

[1]TetrahedronLetters,1987,vol.28,p.6601-6604

Literature

Title: 2-hydroxylethyl methacrylate (HEMA), a tooth restoration component, exerts its genotoxic effects in human gingival fibroblasts trough methacrylic acid, an immediate product of its degradation.

Journal: Molecular biology reports 20120201

Title: Isocyanate-functional adhesives for biomedical applications. Biocompatibility and feasibility study for vascular closure applications.

Journal: Journal of biomedical materials research. Part B, Applied biomaterials 20111001

Title: Synthesis of a difunctional orthogonal coupler for the preparation of carbohydrate-functionalized sP(EO-stat-PO) hydrogels.

Journal: Macromolecular bioscience 20110909

Title: Synthesis of trimethylolpropane esters of oleic acid by Lipoprime 50T.

Journal: Journal of industrial microbiology & biotechnology 20110901

Title: Synthesis of X(Y)-(EO)(n)-OCH₃ type heterobifunctional and X(Y)-(EO)(n)-Z type heterotrifunctional poly(ethylene glycol)s.

Journal: Bioconjugate chemistry 20110316

Title: Preparation of biocompatible, UV-cured fumarated poly(ether-ester)-based tissue-engineering hydrogels.

Journal: Journal of biomaterials science. Polymer edition 20110101

Title: Layered double hydroxide as nanofiller in the development of polyurethane nanocomposites.

Journal: Journal of nanoscience and nanotechnology 20100901

Title: Modeling of reaction kinetics for transesterification of palm-based methyl esters with trimethylolpropane.

Journal: Bioresource technology 20100801

Title: Engineering of cyclodextrin glucanotransferases and the impact for biotechnological applications.

Journal: Applied microbiology and biotechnology 20100101

Title: Investigation of thiol-ene and thiol-ene-methacrylate based resins as dental restorative materials.

Journal: Dental materials : official publication of the Academy of Dental Materials 20100101

Title: Studies on in vitro biostability and blood compatibility of polyurethane potting compound based on aromatic polymeric MDI for extracorporeal devices.

Journal: Journal of materials science. Materials in medicine 20091201

Title: Dissociation constants for GABA(A) receptor antagonists determined with neuronal networks on microelectrode arrays.

Journal: Journal of neuroscience methods 20080830

Title: Dispersion behavior of zirconia nanocrystals and their surface functionalization with vinyl group-containing ligands.

Journal: Langmuir : the ACS journal of surfaces and colloids 20070828

Title: High-spin Mn wheels.

Journal: Inorganic chemistry 20070820

Title: Nanofabricated particles for engineered drug therapies: a preliminary biodistribution study of PRINT nanoparticles.

Journal: Journal of controlled release : official journal of the Controlled Release Society 20070816

Title: Hyperbranched polyesters: synthesis, characterization, and molecular simulations.

Journal: The journal of physical chemistry. B 20070802

Title: Synthesis and characterization of branched polymers from lipase-catalyzed trimethylolpropane copolymerizations.

Journal: Biomacromolecules 20070601

Title: Co- and terpolyesters based on isosorbide and succinic acid for coating applications: synthesis and characterization.

Journal: Biomacromolecules 20061201

Title: A family of [Mn6] complexes featuring tripodal ligands.

Journal: Inorganic chemistry 20060821

Title: In situ lubricant degradation in Antarctic marine sediments. 1. Short-term changes.

Journal: Environmental toxicology and chemistry 20060201

Title: Interactions of bupivacaine with a molecularly imprinted polymer in a monolithic format studied by NMR.

Journal: Analytical chemistry 20060115

Title: 1,1,1-Tris(hydroxymethyl)propane in manganese carboxylate chemistry: synthesis, structure and magnetic properties of a mixed-valence [MnIII4MnII4] cluster featuring the novel [MnIII4MnII4(mu3-OR)6(mu2-OR)8]6+ core.

Journal: Dalton transactions (Cambridge, England : 2003) 20060114

Title: Control of cardiomyocyte orientation on a microscaffold fabricated by photopolymerization with laser beam interference.

Journal: Journal of biomedical optics 20060101

Title: Thiol-ene oligomers as dental restorative materials.

Journal: Dental materials : official publication of the Academy of Dental Materials 20051201

Title: Toxicology studies of trimethylolpropane triacrylate (technical grade) (CAS No. 15625-89-5) in F344/N rats, B6C3F1 mice, and genetically modified (FVB Tg.AC hemizygous) mice (dermal studies).

Journal: National Toxicology Program genetically modified model report 20051001

Title: Photo-polymerized microarchitectural constructs prepared by microstereolithography (muSL) using liquid acrylate-end-capped trimethylene carbonate-based prepolymers.

Journal: Biomaterials 20050501

Title: Tailoring lactide/caprolactone co-oligomers as tissue adhesives.

Journal: Biomaterials 20041201

Title: Synthesis, structure, and magnetic properties of a [Mn22] wheel-like single-molecule magnet.

Journal: Inorganic chemistry 20040712

Title: Preparation and evaluation of non-bonded hyperbranched polymer-coated columns for capillary electrophoresis.

Journal: Talanta 20040708

Title: [The preparation of chemical-bonded hyperbranched polymer coated column for capillary electrophoresis and their application to separation of basic proteins].

Journal: Se pu = Chinese journal of chromatography 20040501

Title: Synthetic polymers adsorbing bisphenol A and its analogues prepared by covalent molecular imprinting using bisphenol A dimethacrylate as a template molecule.

Journal: Analytical and bioanalytical chemistry 20040401

Title: Photocurable biodegradable liquid copolymers: synthesis of acrylate-end-capped trimethylene carbonate-based prepolymers, photocuring, and hydrolysis.

Journal: Biomacromolecules 20040101

Title: Telechelic and star-shaped poly(L-lactide)s by means of bismuth(III) acetate as initiator.

Journal: Biomacromolecules 20040101

Title: Sensitivity evaluation of the Daphtoxkit and Thamnotoxkit microbiotests on blind samples.

Journal: Journal of applied toxicology : JAT 20040101

Title: Preparation of polyol esters based on vegetable and animal fats.

Journal: Bioresource technology 20030301

Title: Introducing lactide-based biodegradable tissue adhesives.

Journal: Journal of materials science. Materials in medicine 20030201

Title: Spectra from 2.5-15 microm of tissue phantom materials, optical clearing agents and ex vivo human skin: implications for depth profiling of human skin.

Journal: Physics in medicine and biology 20030121

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