Applications of palladium dibenzylideneacetone as catalyst in the synthesis of five-membered N-heterocycles

 

Navjeet Kaur
To cite this article: Navjeet Kaur (2019) Applications of palladium dibenzylideneacetone as
catalyst in the synthesis of five-membered N-heterocycles, Synthetic Communications, 49:10,
1205-1230, DOI: 10.1080/00397911.2018.1540048
To link to this article: https://doi.org/10.1080/00397911.2018.1540048

Introduction
Heterocycles are very important not only industrially and biologically but also for the functioning of any developed human society.[1,2] The largest classical divisions of organic chemistry are constituted by heterocycles. Many pharmaceutically active compounds and natural products contain heterocycle moieties.[3,4] Transition metal catalyzed reactions are most attractive protocols among a number of new synthetic methodologies because multiply substituted molecules were constructed directly under mild conditions from easily available starting substrates. The development of newer transformations for heterocycle syntheses using atom economical and efficient pathways is a popular research area nowadays.[5–7] One of the most powerful and useful tool in organic synthesis is metal coupling transformation now. Heteroannulation with metal is a convenient and useful method for the synthesis of sulfur containing heterocycles.[8,9]

 

There is a need for the development of rapid, efficient and versatile strategy for the synthesis of heterocyclic rings. Metal involving methods have gained prominence because traditional conditions have disadvantages such as long reaction times, harsh conditions and limited substrate scopes. In the past decade, metal complexes involving heterocyclic synthesis have become of common use because complicated molecules can be directly built by a metal-assisted reaction under mild conditions from commercial available starting materials.[10–14]

 

Palladium has a rich organometallic chemistry which has developed over the past 25 years. For products with a high added value, this approach can be cost effective, in that palladium is much cheaper than platinum or rhodium, and high recoveries of palladium can be achieved. The redox behavior of palladium plays an important role in its relevance to organic synthesis, there are at least three other characteristics which enrich the organic chemistry of palladium.

i. The facile rearrangement of trihapto into monohapto ally1 complexes, which creates co-ordinative unsaturation at the metal center and enhances reactivity.
ii. The ability of nucleophile to attack at either metal or ligand sites selectively.
iii. The kinetic lability of palladium-carbon monoxide species which enables carbon monoxide to insert into other palladium-carbon bonds. Among these palladium catalysts, palladium dibenzylideneacetone catalyst is preferred due to following reasons: I. The reaction proceeds in one step with high regioselective and stereoselective control. II. The reaction occurs under mild conditions and is not affected by water or air, however if organophosphines are present an inert atmosphere should be used. III. The reaction is tolerant of most functionalities.[15]

 

Synthesis of heterocyclic compounds in the presence of transition metal complexes has become common because a metal-catalyzed reaction can form complicated molecules directly from easily available starting materials under mild conditions.[16] In this review, I have focused on the synthesis of several five-membered heterocyclic compounds with nitrogen as the heteroatom in the presence of palladium dibenzylideneacetone catalysts.

 

Palladium bis(dibenzylideneacetone)-catalyzed synthesis of five-membered N-heterocycles
Kundig et al.[17,18] described the Pd-catalyzed intramolecular a-arylation reactions in the presence of chiral NHC ligands.[19,20] The most successful NHC ligand was examined from this
work in Wacker-type oxidative cyclization reactions which afforded the first highly-enantioselective reaction (>90% ee) using a chiral NHC-Pd catalyst (Scheme 1).

The a-arylation of carbonyl compounds was least investigated transformation, among the several palladium-catalyzed coupling reactions for the formation of C–C bonds, although it was a useful and simple process to synthesize interesting compounds. This simple cross-coupling reaction in the presence of a transition metal catalyst was independently reported by the groups of Hartwig[23] and Buchwald[24] in 1997 which involved a ketone enolate and an aryl halide. Muratake and Natsume[25] at the same time reported the intramolecular a-arylation to synthesize cyclic complex molecules by this short and convenient pathway. Many groups have used chiral N-heterocyclic carbenes in asymmetric intramolecular a-arylation. Hartwig et al.[26] in 2001 first attempted the enantioselective palladium-catalyzed intramolecular reaction of enolates and aromatic bromide in the presence of three different monodentate chiral imidazolium salts. Moderate to good yields of enantioenriched oxindoles were obtained (Scheme 2). With imidazolium salt, the highest selectivity (76% ee) was achieved, which possessed the (þ)-bornyl pattern, the stereogenic center was closer than the (–)-isopinocamphenyl structure. With chiral NHC-ligands the stereoselectivity remained modest and as compared to well-established chiral phosphines like Duphos, BINAP, and Josiphos best result was reported in this field. Glorius et al.[19] in 2002 constructed a C2-symmetric monodentate NHC possessing a two-chiral oxazoline pattern.

 

Nevertheless, only moderate yields were observed by enantioselective palladiumcatalyzed intramolecular a-arylation. Douthwaite et al.[27] have also performed this reaction with a trans-1,2-diaminocyclohexane spacer/linker containing C2-symmetric diimidazolium salt. However, low selectivity (11% ee) was observed with palladium complex PdCl2.

 

A variety of nitrogen containing aromatic heterocycles such as benzimidazoles, indoles, quinolines, and pyrrozoles were synthesized by intramolecular C–N bond formation. Watanabe[28] reported an early example for the synthesis of indoles by an intramolecular cyclization of hydrazones with o-chloroarenes (Scheme 3). The reaction occurred from the enamine tautomer through an intramolecular C–N bond formation.

 

This reaction occurred in good yields with bulky electron rich phosphine ligands like t-Bu3P. The enamines and simple imines along with hydrazones also underwent similar cyclizations to synthesize indoles.[29,30] The 1-aminoindoles without substituents in 2 and 3 position were synthesized by cyclization of N,N-dimethylhydrazones of arylacetaldehydes in the presence of phosphane and Pd(dba)2.[31] The chlorine was substituted directly in N,N-dimethylhydrazones of arylacetaldehydes in the presence of an azole, an amine or an arylboronic acid.

 

Tetracyclic oxazolocarbazoles (functionalized precursors of carbazoquinocins and antiostatins), hyellazole and carazostatin (polysubstituted carbazole alkaloids), 2-arylindole NK1 receptor antagonists, and vincadifformine and (-)-tabersonine (prominent members of aspirioderma alkaloids) contain indole moiety.[32–35] The isocyanade was transformed into indole by a one-pot synthetic protocol through in situ formed 2-iodoindole[36] (Scheme 4). An intramolecular Stille coupling was also reported for an indole synthesis.[37–44]

 

Tan and Hartwig[45] reported the amination of arenes with oxime acetates. Under Pd catalysis with Cs2CO3, numerous 2,3-disubstituted indoles were prepared at high temperature and long reaction times (Scheme 5). Moderate yields were obtained for all oxime substrates regardless of sterics and electronics (40–71%). Interestingly, m-OMe substituted oxime was cyclized on the more hindered C–H bond with complete selectivity in high yield (71%). A Pd(II) complex, resulting from N–O oxidative addition, was isolated, characterized and shown to proceed to the desired product upon heating with a base. With this result, the authors suggested that the oxidative addition was the first step, followed by C–H bond insertion and reductive elimination to afford the indole product. Although not mentioned by the authors, the intermediacy of a Pd-nitrene, similar to Buchwald’s proposal for his Cu transformation, should also be viable since the stoichiometric studies cannot rule out this possibility. Following oxidative addition, the Pd species can also form a Pd-nitrene upon elimination of acetic acid; subsequently Pd-nitrene amination afforded the product as well.

 

Soderberg et al.[46,47] reported the synthesis of indoles containing an electron-donating alkoxy group in the 3-position from o-nitrostyrenes through N-heterocyclization
(Scheme 6).

Palladium tris(dibenzylideneacetone)-catalyzed synthesis of five-membered N-heterocycles

The resin-bound 2-bromophenylacetylated amino acids were used for the solid-phase synthesis of indolines. The secondary amines were formed by reduction of solid-support bound amides with borane. The formed secondary amines by intramolecular cyclization in the presence of palladium catalyst and on cleavage afforded the corresponding disubstituted indulines (Scheme 7).[13d,48]

 

Di-palladium tris(dibenzylideneacetone)-catalyzed synthesis of five-membered N-heterocycles
Functionalized indoles at C-2 position were synthesized from o-(2,2-dibromovinyl)phenylacetanilide through domino palladium-catalyzed coupling cyclization reaction (Scheme 8).[49] The indole was synthesized through Suzuki coupling which needed the acetanilide derivative (with Boc derivative or free aniline unsatisfactory results were obtained) and Pd2(dba)3 instead of Pd(OAc)2. The o-(2,2-dibromovinyl)-aniline was transformed into a 2-substituted indole by some similarities in a mechanism to that of the last step of the Larock indole synthesis. Different reactivity of the two C–Br bonds in oxidative addition benefited this tandem process.[50,51] The bromovinyl aniline was formed in a first step through Suzuki coupling with substitution of the more reactive trans-bromine atom, then the formed bromovinyl aniline underwent Pd catalyzed intramolecular C–N bond formation. The phosphonylated 2-indolyl derivative was also prepared by this similar method. Moreover, the synthesis of benzofurans was also reported in the same publication using a phenol instead of aniline derivative.[44,52]

 

The N-fragments were introduced in a single-step cascade sequence onto an acyclic carbon framework for the synthesis of N-functionalized indoles through new palladiumcatalyzed pathway. The o-alkynylhaloarenes, (o-haloalkenyl)aryl halides, and gem-dihaloalkenylarenes were developed originally as indole precursors. Willis et al.[53,54] explored the alkenyl triflate substrates and reported that dihalides underwent tandem intermolecular N-alkenylation and intramolecular N-arylation to form indoles. The N-substituted products were afforded in excellent yields in the presence of palladiumbased catalytic system (Scheme 9). Both the E- and the Z-isomers of the starting alkenyl halides were utilized. High yields were also obtained with dichloro substrates. A chloro substituent was introduced at each position of the benzo ring to form the products which were suitable for further synthetic elaboration.[55] Willis et al.[56] used pyridinebased starting compounds for the synthesis of 7-azaindoles. Good yields of products were afforded under similar conditions that were used for the preparation of parent indole. The sterically demanding N-substituents bearing indoles like N-(reverse prenyl)indole were also prepared.[57] The synthesis of natural product demethylasterriquinone A by this approach demonstrated the synthetic utility of this process in which N-(reverse prenyl)indole was used as a key intermediate. The cascade coupling of the vinyl-triflate and aryl-halide bonds in styrene with primary amines formed the indoles.

 

This reaction occurred with a number of primary amines, carbamates and amides in the presence of a single palladium catalyst (Pd2dba3/Xantphos), despite the fact that two different types of C–X bonds must be activated. It has been found that even vinyl-chlorides participated in this coupling reaction.

 

Many reactions have been reported for the preparation of indol derivatives.[59] The anti-Markovnikov hydroamination of o-chloro-substituted 2-alkyl-1-arylalkynes pro￾duced arylethylimines by a one-pot synthetic route. The 1,2-disubstituted indoles were synthesized by direct Buchwald-Hartwig coupling of the imine through the formation of tautomeric enamine intermediate under basic conditions (Scheme 10).[60] The substi￾tuted benzo[b]furans were accessed through copper-catalyzed O-arylation of ketones formed through hydrolysis of the arylethylimines.[61,62]

 

Doye and coworkers[60] reported the one-pot synthesis of N-alkyl and N-arylindoles from 1-(o-chloroaryl)-2-alkyl alkynes which involved the formation of two new C–N bonds (Scheme 11). The alkynes underwent regioselective hydroamination with a pri￾mary amine to form imines in the presence of titanium catalyst. The imines were in equilibrium with enamines. Subsequently, the enamines were converted into indoles in good yield by a palladium-catalyzed intramolecular C–N bond forming reaction when the 1,3-bis(2,4,6-trimethylphenyl)imidazolium chloride (precursor of a carbene ligand),
Pd2(dba)3, and t-BuOK were added directly to the reaction mixture. The indole was afforded in modest yield (39%) only when the 2-vinyl alkyne was reacted with tertbutyl￾amine, this was due to the worse regioselectivity of the titanium-catalyzed hydroamina￾tion of 2-vinyl alkynes in comparison to 2-alkyl alkynes. The scope of this reaction was expanded for the synthesis of cyclic indole derivatives from 1-(o-chloroaryl)-2-(aminoal￾kyl)alkynes precursors. An intramolecular hydroamination occurred through titanium catalyzed protocol in this case.[44]

 

This protocol was extended for the formation of functionalized pyrrole on hetero￾aromatic scaffolds which offered a new access to pyrroloquinoxaline[63] and azaindole[64] derivatives. In the aminopalladation-reductive elimination alkyl halides such as benzyl bromides and ethyl iodoacetate were also employed for the synthesis of indoles to form Scheme 10. Synthesis of 2-(4-(benzyloxy)butyl)-1-tert-butyl-1H-indole. Scheme 11. Synthesis of 6,7,8,9-tetrahydropyrido[1,2-a]indole.

 

SYNTHETIC COMMUNICATIONSVR 1211
the 2-substituted 3-benzylindoles and indolylcarboxylate esters.[65,66] The reaction of heteroaryl, aryl and triflates, or vinyl halides successfully formed the 2,3-disubstituted indoles under the conditions,[67–70] under these same conditions the reaction was unsuccessful and afforded the N-alkyl derivative as main or sole product through a competitive nucleophilic substitution reaction. Noteworthy, the 2 acyl-3-alkylindoles were synthesized from N-alkyl intermediates.[71] The role of bases, ligands, and solvents was investigated to obtain the best results by using Pd2(dba)3, K2CO3, and electron-rich, strongly basic, sterically encumbered ligand tris(2,4,6-trimethoxyphenyl)phosphine (ttmpp)[72] at 80 C in THF. A number of o-alkynyltrifluoroacetanilides were transformed into the desired indole products in satisfactory yields and good selectivity was observed in favor of the palladium-catalyzed cyclization under these conditions (Scheme 12). Similar results were observed with benzyl bromides. The solvent played an important role in this reaction. For instance, when all the other parameters were kept same and dimethylsulfoxide (DMSO) solvent and o- (phenylethynyl)trifluoroacetanilide were used the indole carboxylate ester was formed in only 12% yield, whereas 64% yield of 2-ethoxycarbonyl-3-benzylindole was reported.[44,49b]

 

Proper conditions were developed for the indolization by the reaction of o-bromoaniline and a-bromostyrene (Scheme 13). The imine was afforded always without indole formation in the presence of BINAP (for the amination of vinyl bromides BINAP is a ligand of choice). When a more active ligand, like bulky electron-rich phosphine DavePhos, was used, the reaction was promoted and indolization occurred with good yield.[52,73]

 

Itoh and coworkers[74] described the palladium(0)-catalyzed intramolecular cyclotrimerization. Highly substituted dihydroisoindole derivatives were afforded when electron-deficient dialkynes were reacted with DMAD in the presence of Pd2(dba)3 and PPh3 (Scheme 14). Moderate yields of phthalin and isoindoline derivatives were reported by this method. This method was efficiently extended to intramolecular cyclization of triynes to form the tricyclic aromatic systems.[75]

 

To overcome the nonproductive b-hydride elimination, insertions of alkenes were combined with a fast second reductive elimination step in contrast to carbopalladation sequences of alkynes. Wolfe et al.[76] with the help of this concept have discovered a three component reaction with sequential N-arylation and carbopalladation as elementary steps. The N-arylation produced an alkene-coordinated aryl palladium complex.

 

The indoline was formed by inserting olefin fragment followed by a reductive elimination (Scheme 15). The nonvolatile, simple, achiral starting material 2-allylaniline was employed. This transformation afforded unsatisfactory results in the presence of dppe or dppb ligands again. However, N-phenyl-2-benzylindoline was formed in 92% yield using Dpe-phos as a ligand.[77] High yields of N-aryl-2-benzylindoline derivatives were also obtained by coupling a wide range of other aryl bromides with 2-allylaniline.[78,79]

 

Author’s prepared two identical aryl groups possessing indolines successfully and it prompted them to explore the synthesis of two different aryl groups containing related compounds. However, a mixture of mono- and diarylated products was furnished by reacting 2-allylaniline with 1 Eq. of 2-bromonaphthalene. In the presence of (t-Bu)2P(obiphenyl) ligand, high selectivity was observed for monoarylated product (Scheme 16).

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Gne-477 Catalog No.:AA008TDQ CAS No.:1032754-81-6 MDL No.:MFCD20527726 MF:C21H28N8O3S2 MW:504.6288	Apitolisib Catalog No.:AA0035WP CAS No.:1032754-93-0 MDL No.:MFCD20274520 MF:C23H30N8O3S MW:498.6011
(2R)-1-methanesulfonyl-2-methylpiperazine hydrochloride Catalog No.:AA01B693 CAS No.:1032757-87-1 MDL No.:MFCD30342795 MF:C6H15ClN2O2S MW:214.7135	1-(2-thienylsulfonyl)piperazine hydrochloride Catalog No.:AA00J0TW CAS No.:1032757-93-9 MDL No.:MFCD16990546 MF:C8H13ClN2O2S2 MW:268.7840
1-[(2-Fluorophenyl)sulfonyl]piperazine, HCl Catalog No.:AA00H9XV CAS No.:1032757-97-3 MDL No.:MFCD08445299 MF:C10H14ClFN2O2S MW:280.7468	1-[(3-Fluorophenyl)sulfonyl]piperazine, HCl Catalog No.:AA00H9XW CAS No.:1032758-01-2 MDL No.:MFCD10686910 MF:C10H14ClFN2O2S MW:280.7468
4-[(2-methyl-1H-imidazol-1-yl)methyl]piperidine dihydrochloride Catalog No.:AA00J18V CAS No.:1032758-55-6 MDL No.:MFCD11841263 MF:C10H19Cl2N3 MW:252.1840	2-Amino-3-nitropyridine-5-boronic acid, pinacol ester Catalog No.:AA003JPZ CAS No.:1032758-80-7 MDL No.:MFCD11867866 MF:C11H16BN3O4 MW:265.0734
6-(Boc-methylamino)-5-methylpyridine-3-boronic acid pinacol ester Catalog No.:AA003UIF CAS No.:1032758-82-9 MDL No.:MFCD09037485 MF:C18H29BN2O4 MW:348.2449	tert-Butyl 5-bromopyridin-2-yl(ethyl)carbamate Catalog No.:AA0085TY CAS No.:1032758-85-2 MDL No.:MFCD13190616 MF:C12H17BrN2O2 MW:301.1796
6-(Boc-methylamino)pyridine-3-boronic acid pinacol ester Catalog No.:AA003UI5 CAS No.:1032758-87-4 MDL No.:MFCD09037484 MF:C17H27BN2O4 MW:334.2183	2-(tert-Butoxycarbonylamino)pyrimidine-5-boronic acid, pinacol ester Catalog No.:AA0085TX CAS No.:1032758-88-5 MDL No.:MFCD09027069 MF:C15H24BN3O4 MW:321.1798
3-Chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-pyridinamine Catalog No.:AA003A20 CAS No.:1032758-99-8 MDL No.:MFCD12923405 MF:C11H16BClN2O2 MW:254.5209	2-Dimethylamino-pyrimidine-5-boronic acid pinacol ester Catalog No.:AA008R74 CAS No.:1032759-30-0 MDL No.:MFCD07368238 MF:C12H20BN3O2 MW:249.1171
Methyl 2,3-dichlorophenylacetate Catalog No.:AA003RIR CAS No.:10328-87-7 MDL No.:MFCD04112743 MF:C9H8Cl2O2 MW:219.0646	1-Methyl-1H-benzo[d][1,3]oxazine-2,4-dione Catalog No.:AA003EEA CAS No.:10328-92-4 MDL No.:MFCD00006815 MF:C9H7NO3 MW:177.1568
2-Bromo-5-(bromomethyl)benzonitrile Catalog No.:AA0039WG CAS No.:1032822-10-8 MDL No.:MFCD18073531 MF:C8H5Br2N MW:274.9400	1-(7-Hydroxy-6-methoxy-3,4-dihydroisoquinolin-2(1H)-yl)propan-1-one Catalog No.:AA01DZBM CAS No.:1032822-42-6 MDL No.:MFCD28133366 MF:C13H17NO3 MW:235.2790
GSK1292263 Catalog No.:AA008TDV CAS No.:1032823-75-8 MDL No.:MFCD18385004 MF:C23H28N4O4S MW:456.5578	1-Bromo-2-fluoro-4-(methylsulfonyl)benzene Catalog No.:AA0085TW CAS No.:1032825-02-7 MDL No.:MFCD11053812 MF:C7H6BrFO2S MW:253.0887
5-Hydroxy-2-(4-methylsulfonylphenyl)pyridine Catalog No.:AA0093ZF CAS No.:1032825-20-9 MDL No.:MFCD18323740 MF:C12H11NO3S MW:249.2856	[4-[[[2-(Methoxy)ethyl]amino]sulfonyl]phenyl]boronic acid Catalog No.:AA01EHUP CAS No.:1032825-28-7 MDL No.:MFCD25954564 MF:C9H14BNO5S MW:259.0872
5'-O-(4,4'-Dimethoxytrityl)-2'-o-methyluridine Catalog No.:AA008SI2 CAS No.:103285-22-9 MDL No.:MFCD00274123 MF:C31H32N2O8 MW:560.5944	5'-O-Dmt-2'-o-methylguanosine Catalog No.:AA00H9Y3 CAS No.:103285-24-1 MDL No.:MFCD15145231 MF:C32H33N5O7 MW:599.6337
1-(2-Bromo-4-methylphenyl)ethanone Catalog No.:AA0096J4 CAS No.:103286-27-7 MDL No.:MFCD08061386 MF:C9H9BrO MW:213.0712	3-Chloro-1h-pyrazol-4-amine Catalog No.:AA008UA8 CAS No.:103286-54-0 MDL No.:MFCD23701740 MF:C3H4ClN3 MW:117.5370
1H-PYRAZOL-4-YLAMINE DIHYDROCHLORIDE Catalog No.:AA0092AU CAS No.:103286-58-4 MDL No.:MFCD09878922 MF:C3H7Cl2N3 MW:156.0138	H-Leu-leu-leu-oh Catalog No.:AA00H9Y5 CAS No.:10329-75-6 MDL No.:MFCD00038309 MF:C18H35N3O4 MW:357.4882
1-Naphthyl 2-acetamido-2-deoxy-b-D-glucopyranoside Catalog No.:AA0085SH CAS No.:10329-98-3 MDL No.:MFCD00051151 MF:C18H21NO6 MW:347.3624	5-chloro-2-N-[5-methyl-4-(piperidin-4-yl)-2-(propan-2-yloxy)phenyl]-4-N-[2-(propane-2-sulfonyl)phenyl]pyrimidine-2,4-diamine Catalog No.:AA003A96 CAS No.:1032900-25-6 MDL No.:MFCD26142648 MF:C28H36ClN5O3S MW:558.1351
1-Chloro-5-isopropoxy-2-methyl-4-nitrobenzene Catalog No.:AA00H9Y6 CAS No.:1032903-50-6 MDL No.:MFCD11499001 MF:C10H12ClNO3 MW:229.6602	tert-Butyl 4-(4-amino-5-isopropoxy-2-methylphenyl)piperidine-1-carboxylate Catalog No.:AA00H9Y8 CAS No.:1032903-63-1 MDL No.:MFCD26407295 MF:C20H32N2O3 MW:348.4797
5-Bromo-2-fluoroanisole Catalog No.:AA003H78 CAS No.:103291-07-2 MDL No.:MFCD01861130 MF:C7H6BrFO MW:205.0243	4-Bromo-1-methyl-1H-pyrazolo[3,4-c]pyridine Catalog No.:AA0085SK CAS No.:1032943-41-1 MDL No.:MFCD16250453 MF:C7H6BrN3 MW:212.0466
4-Bromo-1h-pyrazolo[3,4-c]pyridine Catalog No.:AA0038A6 CAS No.:1032943-43-3 MDL No.:MFCD11109831 MF:C6H4BrN3 MW:198.0201	N-(Cyclohexylmethyl)prop-2-enamide Catalog No.:AA01AGX7 CAS No.:103297-86-5 MDL No.:MFCD12144949 MF:C10H17NO MW:167.2481
1-(4-Fluorophenoxy)-2,4-dinitrobenzene Catalog No.:AA007XRQ CAS No.:1033-02-9 MDL No.:MFCD01046749 MF:C12H7FN2O5 MW:278.1928	Taltirelin Catalog No.:AA007HJ2 CAS No.:103300-74-9 MDL No.:MFCD18074448 MF:C17H23N7O5 MW:405.4084
GDPG Catalog No.:AA008YWS CAS No.:103301-72-0 MDL No.:MFCD00070118 MF:C16H25N5NaO16P2 MW:628.3309	3-fluoro-1-N-(propan-2-yl)benzene-1,2-diamine Catalog No.:AA019VCC CAS No.:1033010-33-1 MDL No.:MFCD12149481 MF:C9H13FN2 MW:168.2113
1-[(2,4-Difluorophenyl)methyl]pyrrolidin-3-ol Catalog No.:AA01FM3A CAS No.:1033012-65-5 MDL No.:MFCD11048109 MF:C11H13F2NO MW:213.2238	D-ERYTHROSE 4-PHOSPHATE SODIUM SALT Catalog No.:AA008XAW CAS No.:103302-15-4 MDL No.:MFCD00057582 MF:C4H8NaO7P MW:222.0657
N2,N7-Diphenyl-n2,n7-di-m-tolyl-9,9'-spirobi[fluorene]-2,7-diamine Catalog No.:AA007GW4 CAS No.:1033035-83-4 MDL No.:MFCD11112143 MF:C51H38N2 MW:678.8608	TPO agonist 1 Catalog No.:AA008TMV CAS No.:1033040-23-1 MDL No.:MFCD30343847 MF:C25H22N8O2 MW:466.4946
benzyl (2S)-2-{[(benzyloxy)carbonyl]amino}-5-carbamimidamidopentanoate Catalog No.:AA00H9YE CAS No.:103305-87-9 MDL No.:MFCD01862300 MF:C21H26N4O4 MW:398.4555	2,2-difluoropropanehydrazide Catalog No.:AA01BU5D CAS No.:1033077-25-6 MDL No.:MFCD28401073 MF:C3H6F2N2O MW:124.0893
(R,S)-N2-Nitroso-Anabasine N'-β-D-Glucuronide Catalog No.:AA008VKZ CAS No.:1033078-12-4 MDL No.:MFCD28898584 MF:C16H22N3O7+ MW:368.3618	5,5'-Dichloro-3,3'-dinitro-[1,1'-biphenyl]-2,2'-diol Catalog No.:AA008R26 CAS No.:10331-57-4 MDL No.:MFCD00867407 MF:C12H6Cl2N2O6 MW:345.0918
2-azido-N-(propan-2-yl)propanamide Catalog No.:AA01A22I CAS No.:1033115-49-9 MDL No.:MFCD14652326 MF:C6H12N4O MW:156.1857	2-(((4-Chloro-3-methylpyridin-2-yl)methyl)thio)-1H-benzo[d]imidazole Catalog No.:AA003ELL CAS No.:103312-62-5 MDL No.:MFCD08282361 MF:C14H12ClN3S MW:289.7832
1-Propyl-3-(trifluoromethyl)pyrazole Catalog No.:AA00947I CAS No.:1033132-02-3 MDL No.:MFCD16619915 MF:C7H9F3N2 MW:178.1550	4-(pyridin-4-yl)-2,3-dihydro-1,3-thiazol-2-one Catalog No.:AA01A8AC CAS No.:103317-30-2 MDL No.:MFCD11220478 MF:C8H6N2OS MW:178.2110
2-(2-Bromophenyl)ethanethioamide Catalog No.:AA008S07 CAS No.:103317-32-4 MDL No.:MFCD09816252 MF:C8H8BrNS MW:230.1248	Benzoic acid, 2,4-dichloro-5-fluoro-, ethyl ester Catalog No.:AA009KBI CAS No.:103318-75-8 MDL No.:MFCD06205036 MF:C9H7Cl2FO2 MW:237.0551
2-(N-Isopropylphenylsulfonamido)acetic acid Catalog No.:AA009280 CAS No.:1033194-55-6 MDL No.:MFCD11040511 MF:C11H15NO4S MW:257.3061	tert-Butyl 1-(hydroxyimino)-3-phenylpropan-2-ylcarbamate Catalog No.:AA00H9YL CAS No.:1033194-57-8 MDL No.:MFCD11040514 MF:C14H20N2O3 MW:264.3202
2-(N-(2-Methoxyethyl)-3,5-dimethylisoxazole-4-sulfonamido)acetic acid Catalog No.:AA00H9YM CAS No.:1033194-58-9 MDL No.:MFCD11040515 MF:C10H16N2O6S MW:292.3088	2-(Methylthio)-4-(p-tolylamino)pyrimidine-5-carboxylic acid Catalog No.:AA00H9YO CAS No.:1033194-60-3 MDL No.:MFCD11040521 MF:C13H13N3O2S MW:275.3262
7-Methyl-1-benzofuran-3-carboxylic acid Catalog No.:AA01C41W CAS No.:1033196-18-7 MDL No.:MFCD17010639 MF:C10H8O3 MW:176.1687	Methyl (2s)-2-amino-4-(methylsulfanyl)butanoate Catalog No.:AA007XR2 CAS No.:10332-17-9 MDL No.:MFCD08282663 MF:C2H5O6S2- MW:189.1875
N-(2-(4-Nitrophenoxy)ethyl)cyclopropanamine Catalog No.:AA003S4U CAS No.:1033201-53-4 MDL No.:MFCD10699603 MF:C11H14N2O3 MW:222.2405	1-(5-Bromo-2-nitrophenyl)pyrrolidine Catalog No.:AA003CYL CAS No.:1033201-57-8 MDL No.:MFCD10699604 MF:C10H11BrN2O2 MW:271.1105
6-Amino-3-bromopicolinic acid Catalog No.:AA007XRJ CAS No.:1033201-61-4 MDL No.:MFCD10699642 MF:C6H5BrN2O2 MW:217.0201	Ethyl 7-bromobenzofuran-2-carboxylate Catalog No.:AA007XRI CAS No.:1033201-65-8 MDL No.:MFCD10699643 MF:C11H9BrO3 MW:269.0914
t-Butyl 3-Bromo-4-fluorobenzamide Catalog No.:AA003UF0 CAS No.:1033201-68-1 MDL No.:MFCD10699644 MF:C11H13BrFNO MW:274.1294	3-Ethoxy-2-fluorobenzoic acid Catalog No.:AA007XRH CAS No.:1033201-71-6 MDL No.:MFCD10699646 MF:C9H9FO3 MW:184.1644
1-(3-Bromo-4-fluorobenzoyl)piperidine Catalog No.:AA003CTF CAS No.:1033201-74-9 MDL No.:MFCD10699648 MF:C12H13BrFNO MW:286.1401	5-Bromo-4-octylpyrimidine Catalog No.:AA003MGS CAS No.:1033201-80-7 MDL No.:MFCD10699650 MF:C12H19BrN2 MW:271.1967
5-Benzyl-3-(2-bromophenyl)-1,2,4-oxadiazole Catalog No.:AA003MC8 CAS No.:1033201-86-3 MDL No.:MFCD10699653 MF:C15H11BrN2O MW:315.1646	1-(3-Chloro-4-fluorophenyl)piperidine Catalog No.:AA003CTW CAS No.:1033201-89-6 MDL No.:MFCD10699654 MF:C11H13ClFN MW:213.6790
5-Butyl-3-p-tolyl-1,2,4-oxadiazole Catalog No.:AA003MIL CAS No.:1033201-93-2 MDL No.:MFCD10699656 MF:C13H16N2O MW:216.2789	t-Butyl 3-Bromo-5-methylbenzenesulfonamide Catalog No.:AA003UF1 CAS No.:1033201-97-6 MDL No.:MFCD10699659 MF:C11H16BrNO2S MW:306.2192
5-(Prop-1-en-2-yl)-3-p-tolyl-1,2,4-oxadiazole Catalog No.:AA003M54 CAS No.:1033201-98-7 MDL No.:MFCD10699661 MF:C12H12N2O MW:200.2365	3-(4-Nitrophenyl)-5-(prop-1-en-2-yl)-1,2,4-oxadiazole Catalog No.:AA003I2I CAS No.:1033202-00-4 MDL No.:MFCD10699663 MF:C11H9N3O3 MW:231.2075
8-Hydroxyimidazo[1,2-a]pyridine-3-carbaldehyde Catalog No.:AA007XRG CAS No.:1033202-04-8 MDL No.:MFCD10699667 MF:C8H6N2O2 MW:162.1454	3-formylimidazo[1,2-a]pyridine-7-carboxylic acid Catalog No.:AA01CJH5 CAS No.:1033202-06-0 MDL No.:MFCD10699668 MF:C9H6N2O3 MW:190.1555
8-Bromo-6-methylimidazo[1,2-a]pyridine-3-carbaldehyde Catalog No.:AA008SR7 CAS No.:1033202-08-2 MDL No.:MFCD10699669 MF:C9H7BrN2O MW:239.0687	6-Chloro-8-fluoroimidazo[1,2-a]pyridine Catalog No.:AA007GW0 CAS No.:1033202-10-6 MDL No.:MFCD10699670 MF:C7H4ClFN2 MW:170.5715
3-(3-Bromophenyl)-1,2,4-oxadiazole Catalog No.:AA0085SA CAS No.:1033202-12-8 MDL No.:MFCD10699671 MF:C8H5BrN2O MW:225.0421	3-Fluoro-5-nitropyridin-2-ol Catalog No.:AA008W5V CAS No.:1033202-14-0 MDL No.:MFCD10699675 MF:C5H3FN2O3 MW:158.0873
6-Bromo-7-chloro-8-methylquinoline Catalog No.:AA008SRJ CAS No.:1033202-16-2 MDL No.:MFCD10699677 MF:C10H7BrClN MW:256.5263	3-Ethoxy-2-fluorobenzonitrile Catalog No.:AA008SR3 CAS No.:1033202-20-8 MDL No.:MFCD10699689 MF:C9H8FNO MW:165.1643
1-Bromo-4-pentylcyclohex-1-ene Catalog No.:AA003E2C CAS No.:1033202-26-4 MDL No.:MFCD10699694 MF:C11H19Br MW:231.1726	2-Cyclopentylamino-5-methyl-3-nitropyridine Catalog No.:AA003H22 CAS No.:1033202-29-7 MDL No.:MFCD10699704 MF:C11H15N3O2 MW:221.2557
4,5,6,7-tetrahydro-1H-indol-4-amine Catalog No.:AA019Y8L CAS No.:1033202-31-1 MDL No.:MFCD11040650 MF:C8H12N2 MW:136.1943	2-(5-Bromo-3-nitropyridin-2-ylamino)ethanol Catalog No.:AA007XRF CAS No.:1033202-32-2 MDL No.:MFCD10699705 MF:C7H8BrN3O3 MW:262.0607
5-Bromo-N-(4-methoxybenzyl)-3-nitropyridin-2-amine Catalog No.:AA003MHH CAS No.:1033202-35-5 MDL No.:MFCD10699706 MF:C13H12BrN3O3 MW:338.1567	3-Bromo-2-chloro-5-methoxypyridine Catalog No.:AA0085S9 CAS No.:1033202-44-6 MDL No.:MFCD10699708 MF:C6H5BrClNO MW:222.4670
Dimethyl 3,3'-bipyridine-6,6'-dicarboxylate Catalog No.:AA007XR4 CAS No.:1033202-47-9 MDL No.:MFCD10699711 MF:C14H12N2O4 MW:272.2561	5-Fluoro-3-nitropicolinonitrile Catalog No.:AA008XHO CAS No.:1033202-51-5 MDL No.:MFCD11040666 MF:C6H2FN3O2 MW:167.0974
5-Bromo-2-cyclopentylamino-3-nitropyridine Catalog No.:AA003MHT CAS No.:1033202-53-7 MDL No.:MFCD08692161 MF:C10H12BrN3O2 MW:286.1252	3-Chloro-2-(4-methoxybenzyloxy)pyridine Catalog No.:AA003J3G CAS No.:1033202-56-0 MDL No.:MFCD10699712 MF:C13H12ClNO2 MW:249.6929
6-Bromo-3-ethyl-3H-imidazo[4,5-b]pyridine Catalog No.:AA008SRB CAS No.:1033202-59-3 MDL No.:MFCD08692128 MF:C8H8BrN3 MW:226.0732	2-(4-Methoxybenzyloxy)-5-(trifluoromethyl)pyridine Catalog No.:AA003ETT CAS No.:1033202-62-8 MDL No.:MFCD10699714 MF:C14H12F3NO2 MW:283.2458
2-Cyclopropylamino-5-methyl-3-nitropyridine Catalog No.:AA0090CJ CAS No.:1033202-65-1 MDL No.:MFCD10699715 MF:C9H11N3O2 MW:193.2025	2-t-Butylamino-5-methyl-3-nitropyridine Catalog No.:AA003HUQ CAS No.:1033202-70-8 MDL No.:MFCD10699717 MF:C10H15N3O2 MW:209.2450
4-Chloro-5-methylpyridin-2-amine Catalog No.:AA008Z0Y CAS No.:1033203-31-4 MDL No.:MFCD11100639 MF:C6H7ClN2 MW:142.5862	4-Bromo-5-methylpyridin-2-amine Catalog No.:AA007GVZ CAS No.:1033203-32-5 MDL No.:MFCD11100640 MF:C6H7BrN2 MW:187.0372
2-Bromo-4-chloro-5-methylpyridine Catalog No.:AA007GVY CAS No.:1033203-40-5 MDL No.:MFCD11100651 MF:C6H5BrClN MW:206.4676	6-Bromopyridine-3,4-diamine Catalog No.:AA0039RC CAS No.:1033203-41-6 MDL No.:MFCD11100655 MF:C5H6BrN3 MW:188.0252
2-bromo-4,5-dichloropyridine Catalog No.:AA0094OX CAS No.:1033203-42-7 MDL No.:MFCD11100656 MF:C5H2BrCl2N MW:226.8861	2-Bromo-4-chloro-5-fluoropyridine Catalog No.:AA008Z0E CAS No.:1033203-44-9 MDL No.:MFCD11100658 MF:C5H2BrClFN MW:210.4315
2,5-Dibromo-4-chloropyridine Catalog No.:AA007GVX CAS No.:1033203-47-2 MDL No.:MFCD11100661 MF:C5H2Br2ClN MW:271.3371	Fmoc-Gly-Cl Catalog No.:AA0085S7 CAS No.:103321-49-9 MDL No.:MFCD00235814 MF:C17H14ClNO3 MW:315.7510
Fmoc-l-alanyl chloride Catalog No.:AA0085S6 CAS No.:103321-50-2 MDL No.:MFCD00235802 MF:C18H16ClNO3 MW:329.7775	Boc-beta-Cyclohexyl-L-alaninol Catalog No.:AA003CBX CAS No.:103322-56-1 MDL No.:MFCD00076899 MF:C14H27NO3 MW:257.3691
1-N-(2,6-difluorophenyl)benzene-1,2-diamine Catalog No.:AA008STP CAS No.:1033225-44-3 MDL No.:MFCD11202197 MF:C12H10F2N2 MW:220.2180	1-N-(2,4-difluorophenyl)benzene-1,2-diamine Catalog No.:AA01A50L CAS No.:1033227-40-5 MDL No.:MFCD11201984 MF:C12H10F2N2 MW:220.2180
4’-Ethyl-2-hydroxyacetophenone Catalog No.:AA01DEQP CAS No.:103323-24-6 MDL No.:MFCD08443457 MF:C10H12O2 MW:164.2011	3',5'-Dimethyl-2'-hydroxyacetophenone Catalog No.:AA00H9YT CAS No.:103323-25-7 MDL No.:MFCD01631133 MF:C10H12O2 MW:164.2011
3-Ethyl-4-methoxybenzaldehyde Catalog No.:AA01FOCV CAS No.:103323-26-8 MDL No.:MFCD06247460 MF:C10H12O2 MW:164.2011	1-Bromo-4-(sec-butoxy)benzene Catalog No.:AA019XSM CAS No.:103323-60-0 MDL No.:MFCD11168492 MF:C10H13BrO MW:229.1136
2-Methyl-3-phenoxypropanoic acid Catalog No.:AA007XQY CAS No.:103323-93-9 MDL No.:MFCD06657037 MF:C10H12O3 MW:180.2005	methyl 2-(2-hydroxy-3-methoxyphenyl)acetate Catalog No.:AA01ALG5 CAS No.:103324-26-1 MDL No.:MFCD18399374 MF:C10H12O4 MW:196.1999
1-(Bromomethyl)-2-isopropylbenzene Catalog No.:AA007GVS CAS No.:103324-37-4 MDL No.:MFCD09999705 MF:C10H13Br MW:213.1142	1-(3-Bromopropyl)-3-methylbenzene Catalog No.:AA01A51R CAS No.:103324-39-6 MDL No.:MFCD09744407 MF:C10H13Br MW:213.1142
tert-butyl (2S,4S)-4-fluoro-2-[(methanesulfonyloxy)methyl]pyrrolidine-1-carboxylate Catalog No.:AA01E88T CAS No.:1033245-10-1 MDL No.:MFCD30734033 MF:C11H20FNO5S MW:297.3436	tert-Butyl (2S,4S)-2-(aminomethyl)-4-fluoro-1-pyrrolidinecarboxylate Catalog No.:AA0097EM CAS No.:1033245-12-3 MDL No.:MFCD18917064 MF:C10H19FN2O2 MW:218.2685
tert-Butyl 5-bromo-1h-indole-3-carboxylate Catalog No.:AA007GVR CAS No.:1033265-51-8 MDL No.:MFCD19441179 MF:C13H14BrNO2 MW:296.1598	(1-Methylpiperidin-4-yl)acetaldehyde Catalog No.:AA0085RW CAS No.:10333-64-9 MDL No.:MFCD08458721 MF:C8H15NO MW:141.2108
2-(Pyrrol-1-yl)benzoic acid Catalog No.:AA007GVN CAS No.:10333-68-3 MDL No.:MFCD00051645 MF:C11H9NO2 MW:187.1947	Guanine sulfate Catalog No.:AA003G9E CAS No.:10333-92-3 MDL No.:MFCD00213671 MF:C5H7N5O5S MW:249.2046
7-Bromoisoquinoline-1,3(2h,4h)-dione Catalog No.:AA0094PJ CAS No.:1033330-27-6 MDL No.:MFCD12756049 MF:C9H6BrNO2 MW:240.0534	(4aR,4bS,6aS,7S,9aS,9bS,11aR)-Methyl 4a,6a-dimethyl-2-oxo-2,4a,4b,5,6,6a,7,8,9,9a,9b,10,11,11a-tetradecahydro-1H-indeno[5,4-f]quinoline-7-carboxylate Catalog No.:AA008UGW CAS No.:103335-41-7 MDL No.:MFCD00876749 MF:C20H29NO3 MW:331.4492
3-Oxo-4-aza-5-alpha-androstane-17-beta-carboxylic acid Catalog No.:AA008QY8 CAS No.:103335-55-3 MDL No.:MFCD06411020 MF:C19H29NO3 MW:319.4385	N-Boc-alpha-methyl-L-proline Catalog No.:AA00H9YW CAS No.:103336-06-7 MDL No.:MFCD08706361 MF:C11H19NO4 MW:229.2729
Thieno[2,3-d]pyrimidin-2(1H)-one, 4-amino-5,6-dimethyl-, hydrochloride (1:1) Catalog No.:AA003ACE CAS No.:1033366-59-4 MDL No.:MFCD31560051 MF:C8H10ClN3OS MW:231.7025	Methyldiclazuril Catalog No.:AA01DZBN CAS No.:103337-71-9 MDL No.:MFCD31735098 MF:C18H11Cl3N4O2 MW:421.6645
Letrazuril Catalog No.:AA008ZAV CAS No.:103337-74-2 MDL No.:MFCD00867212 MF:C17H9Cl2FN4O2 MW:391.1834	(1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione Catalog No.:AA003BET CAS No.:10334-26-6 MDL No.:MFCD00082863 MF:C10H14O2 MW:166.2170
2-(Cbz-Amino)-5-methylpyrazine Catalog No.:AA007XQR CAS No.:1033418-57-3 MDL No.:MFCD11053848 MF:C13H13N3O2 MW:243.2612	L-364,373 Catalog No.:AA007XQQ CAS No.:103342-82-1 MDL No.:MFCD10687096 MF:C25H20FN3O MW:397.4442
3-Amino-5-phenyl-1H-benzo[e][1,4]diazepin-2(3H)-one Catalog No.:AA008RRT CAS No.:103343-47-1 MDL No.:MFCD01318260 MF:C15H11N3O MW:249.2673	1',5'-Dimethyl-1'H,2H-[3,4'-bipyrazole]-5-carboxylic acid Catalog No.:AA007GVM CAS No.:1033431-24-1 MDL No.:MFCD22192464 MF:C9H10N4O2 MW:206.2013
(4-Fluoro-3-nitrophenyl)hydrazine hydrochloride Catalog No.:AA01ACTO CAS No.:1033439-46-1 MDL No.:MFCD26936156 MF:C6H7ClFN3O2 MW:207.5901	3-Cyclopentyl-1-methyl-1H-pyrazole-5-carboxylic acid Catalog No.:AA01DQAZ CAS No.:1033444-00-6 MDL No.:MFCD20646094 MF:C10H14N2O2 MW:194.2304
3-bromo-1-methyl-1H-pyrazolo[4,3-d]pyrimidine-5,7-diol Catalog No.:AA01ELEQ CAS No.:1033444-07-3 MDL No.:MFCD31617113 MF:C6H5BrN4O2 MW:245.0335	1-Butyl-3-Vinylimidazolium Bromide Catalog No.:AA003E3Q CAS No.:1033461-45-8 MDL No.:MFCD18251314 MF:C9H15BrN2 MW:231.1328
1,3-diethyl 2-({[(benzyloxy)carbonyl]amino}(3-chlorophenyl)methyl)propanedioate Catalog No.:AA00ITIW CAS No.:1033463-15-8 MDL No.:MFCD10758053 MF:C22H24ClNO6 MW:433.8821	6-methyl-5-[(pyrrolidin-1-yl)methyl]-1,2,3,4-tetrahydropyrimidine-2,4-dione Catalog No.:AA00IW3O CAS No.:1033463-16-9 MDL No.:MFCD10758054 MF:C10H15N3O2 MW:209.2450
2-((Dimethylamino)methyl)-4-(2-methylbutyl)phenol Catalog No.:AA00IZ6W CAS No.:1033463-17-0 MDL No.:MFCD11100202 MF:C14H23NO MW:221.3385	1-[4-(4-chlorophenyl)-1,3-thiazol-2-yl]-N-(2-hydroxyethyl)piperidine-4-carboxamide Catalog No.:AA00ITQZ CAS No.:1033463-18-1 MDL No.:MFCD10758056 MF:C17H20ClN3O2S MW:365.8776
N-(2,4-Dichloro-5-((4-nitrobenzyl)oxy)phenyl)acetamide Catalog No.:AA00IW6U CAS No.:1033463-19-2 MDL No.:MFCD10758057 MF:C15H12Cl2N2O4 MW:355.1728	5-Chloro-1-(2-chloro-6-fluorobenzyl)-6-oxo-1,6-dihydropyridine-3-carbaldehyde Catalog No.:AA00ITR0 CAS No.:1033463-20-5 MDL No.:MFCD10758058 MF:C13H8Cl2FNO2 MW:300.1125
5-Chloro-1-(4-chlorobenzyl)-6-oxo-1,6-dihydropyridine-3-carbaldehyde Catalog No.:AA00ITR1 CAS No.:1033463-21-6 MDL No.:MFCD03415386 MF:C13H9Cl2NO2 MW:282.1221	5-Chloro-1-(4-fluorobenzyl)-6-oxo-1,6-dihydro-3-pyridinecarbaldehyde Catalog No.:AA00IZ73 CAS No.:1033463-22-7 MDL No.:MFCD18907001 MF:C13H9ClFNO2 MW:265.6675
Methyl 6-[4-(trifluoromethyl)piperidino]nicotinate Catalog No.:AA00ITR3 CAS No.:1033463-23-8 MDL No.:MFCD10758065 MF:C13H15F3N2O2 MW:288.2656	Methyl 4-acetamido-2-((4-nitrobenzyl)oxy)benzoate Catalog No.:AA00IZ8I CAS No.:1033463-24-9 MDL No.:MFCD10758072 MF:C17H16N2O6 MW:344.3187
5-Amino-1-(benzo[d]oxazol-2-yl)-2,3-dihydro-1H-pyrazole-4-carbonitrile Catalog No.:AA00ITWC CAS No.:1033463-25-0 MDL No.:MFCD31618159 MF:C11H9N5O MW:227.2221	3-(1-(4-Methylbenzo[d]thiazol-2-yl)hydrazinyl)propanenitrile Catalog No.:AA00ITWD CAS No.:1033463-26-1 MDL No.:MFCD10758075 MF:C11H12N4S MW:232.3048
6,8-dichloro-3-iodoimidazo[1,2-a]pyridine Catalog No.:AA00ITWE CAS No.:1033463-27-2 MDL No.:MFCD10758076 MF:C7H3Cl2IN2 MW:312.9226	6-Chloro-8-iodoimidazo[1,2-a]pyridine Catalog No.:AA00H9YY CAS No.:1033463-28-3 MDL No.:MFCD10758078 MF:C7H4ClIN2 MW:278.4775
2-(1-Benzyl-4-(hydroxymethyl)pyrrolidin-3-yl)phenol Catalog No.:AA00ITZT CAS No.:1033463-29-4 MDL No.:MFCD10758080 MF:C18H21NO2 MW:283.3648	3-Chloro-5-(trifluoromethyl)picolinohydrazide Catalog No.:AA00IS3X CAS No.:1033463-30-7 MDL No.:MFCD10758083 MF:C7H5ClF3N3O MW:239.5823
(3-Chloro-5-(trifluoromethyl)pyridin-2-yl)methanol Catalog No.:AA00329U CAS No.:1033463-31-8 MDL No.:MFCD11100207 MF:C7H5ClF3NO MW:211.5689	2-(4-(Trifluoromethyl)phenethyl)piperazine Catalog No.:AA00ITZV CAS No.:1033463-32-9 MDL No.:MFCD11100209 MF:C13H17F3N2 MW:258.2827
5-Chloro-3-nitro-1H-pyrrolo[2,3-b]pyridine Catalog No.:AA0098YV CAS No.:1033463-33-0 MDL No.:MFCD10758085 MF:C7H4ClN3O2 MW:197.5786	Ethyl 6-chloro-8-iodoimidazo[1,2-a]pyridine-2-carboxylate Catalog No.:AA0093L8 CAS No.:1033463-34-1 MDL No.:MFCD10758086 MF:C10H8ClIN2O2 MW:350.5402
3-Iodoimidazo[1,2-a]pyridine-2-carboxylic acid Catalog No.:AA00ITZW CAS No.:1033463-35-2 MDL No.:MFCD10758089 MF:C8H5IN2O2 MW:288.0420	6-(4-(Trifluoromethyl)piperidin-1-yl)nicotinic acid Catalog No.:AA00IS3Y CAS No.:1033463-36-3 MDL No.:MFCD10758091 MF:C12H13F3N2O2 MW:274.2390
5-Nitro-2-(4-(trifluoromethyl)piperidin-1-yl)benzaldehyde Catalog No.:AA00ITZX CAS No.:1033463-37-4 MDL No.:MFCD10758093 MF:C13H13F3N2O3 MW:302.2491	2-(4-(Hydroxymethyl)piperidin-1-yl)-5-nitrobenzaldehyde Catalog No.:AA00IZC5 CAS No.:1033463-38-5 MDL No.:MFCD10758094 MF:C13H16N2O4 MW:264.2771
5-Amino-1-(pyridin-2-ylmethyl)-1H-1,2,3-triazole-4-carboxamide Catalog No.:AA00IWO6 CAS No.:1033463-39-6 MDL No.:MFCD10758095 MF:C9H10N6O MW:218.2153	5-Methyl-1-(4-methylbenzyl)-1H-1,2,3-triazole-4-carboxylic acid Catalog No.:AA00IWO7 CAS No.:1033463-40-9 MDL No.:MFCD10758097 MF:C12H13N3O2 MW:231.2505
1-(4-Chlorobenzyl)-5-methyl-1H-1,2,3-triazole-4-carboxylic acid Catalog No.:AA00IWO9 CAS No.:1033463-41-0 MDL No.:MFCD10758098 MF:C11H10ClN3O2 MW:251.6690	1-(1-(4-Chlorobenzyl)-5-methyl-1H-1,2,3-triazol-4-yl)ethanone Catalog No.:AA00IZJF CAS No.:1033463-42-1 MDL No.:MFCD10758100 MF:C12H12ClN3O MW:249.6962
methyl 3-(N-methyl4-bromobenzamido)thiophene-2-carboxylate Catalog No.:AA00IUST CAS No.:1033463-43-2 MDL No.:MFCD10758101 MF:C14H12BrNO3S MW:354.2190	3-(4-Bromophenyl)-5,6-dihydroimidazo[2,1-b]thiazole-2-carbaldehyde Catalog No.:AA00IUUW CAS No.:1033463-44-3 MDL No.:MFCD10758103 MF:C12H9BrN2OS MW:309.1817
2-Methyl-2H-benzo[d][1,2,3]triazole-4-sulfonyl chloride Catalog No.:AA00J2OC CAS No.:1033464-75-3 MDL No.:MFCD19200537 MF:C7H6ClN3O2S MW:231.6594	1-Methyl-1h-1,2,3-benzotriazole-4-sulfonyl chloride Catalog No.:AA00J2NK CAS No.:1033464-77-5 MDL No.:MFCD19200536 MF:C7H6ClN3O2S MW:231.6594
4-(Bromomethyl)-1-chloro-2-methoxybenzene Catalog No.:AA0038A4 CAS No.:103347-14-4 MDL No.:MFCD09907927 MF:C8H8BrClO MW:235.5055	(2S,3R,4E)-2-AZIDO-4-OCTADECENE-1,3-DIOL Catalog No.:AA008W6E CAS No.:103348-49-8 MDL No.:MFCD00274378 MF:C18H36N3O2 MW:326.4973
methyl (2E)-2-{[(2E)-3-methoxy-3-oxo-2-(phenylmethylidene)propoxy]methyl}-3-phenylprop-2-enoate Catalog No.:AA00IXEX CAS No.:1033494-82-4 MDL No.:MFCD30833933 MF:C22H22O5 MW:366.4071	MMP-2 Inhibitor I Catalog No.:AA007GVG CAS No.:10335-69-0 MDL No.:MFCD02683956 MF:C18H35NO2 MW:297.4760
N-hydroxy-2-(naphthalen-1-yl)acetamide Catalog No.:AA019WO7 CAS No.:10335-80-5 MDL No.:MFCD00448736 MF:C12H11NO2 MW:201.2212	2-(1H-1,2,4-Triazol-1-yl)ethan-1-amine hydrochloride Catalog No.:AA00H9YZ CAS No.:1033521-69-5 MDL No.:MFCD06656249 MF:C4H9ClN4 MW:148.5941
"1-(1,3-benzothiazol-2-yl)-2,2,2-trifluoroethane-1,1-diol" Catalog No.:AA01FM3R CAS No.:1033591-96-6 MDL No.:MFCD10630861 MF:C9H6F3NO2S MW:249.2096	Potassium (3,4-difluorophenyl)trifluoroborate Catalog No.:AA008SS8 CAS No.:1033592-49-2 MDL No.:MFCD09993188 MF:C6H3BF5K MW:219.9893
1-[2-(Dimethylamino)phenyl]ethan-1-one Catalog No.:AA0096Y0 CAS No.:10336-55-7 MDL No.:MFCD11136834 MF:C10H13NO MW:163.2163	(4-Fluorophenyl)methanesulfonyl chloride Catalog No.:AA003BT2 CAS No.:103360-04-9 MDL No.:MFCD01631930 MF:C7H6ClFO2S MW:208.6377
2-(1-(3,5-Dimethoxybenzyl)-3-oxopiperazin-2-yl)acetic acid Catalog No.:AA0090UJ CAS No.:1033600-03-1 MDL No.:MFCD29068029 MF:C15H20N2O5 MW:308.3297	[1-(4-fluorobenzyl)-3-oxo-2-piperazinyl]acetic acid Catalog No.:AA00J3TU CAS No.:1033600-10-0 MDL No.:MFCD05666726 MF:C13H15FN2O3 MW:266.2682
2-[1-(2-METHOXYBENZYL)-3-OXO-2-PIPERAZINYL]-ACETIC ACID Catalog No.:AA0099UK CAS No.:1033600-22-4 MDL No.:MFCD05666757 MF:C14H18N2O4 MW:278.3037	2-(3-Oxo-1-(3-(trifluoromethyl)benzyl)piperazin-2-yl)acetic acid Catalog No.:AA0090UX CAS No.:1033600-26-8 MDL No.:MFCD05666786 MF:C14H15F3N2O3 MW:316.2757
2-(3-Oxo-1-(3-phenylpropyl)piperazin-2-yl)acetic acid Catalog No.:AA007XLY CAS No.:1033600-32-6 MDL No.:MFCD05666743 MF:C15H20N2O3 MW:276.3309	5-Bromo-2-(methoxymethoxy)benzonitrile Catalog No.:AA0096WI CAS No.:1033602-66-2 MDL No.:MFCD12913647 MF:C9H8BrNO2 MW:242.0693
(1R,2R)-2-(Benzylamino)cyclopentanol Catalog No.:AA0085RK CAS No.:1033605-25-2 MDL No.:MFCD09999250 MF:C12H17NO MW:191.2695	1H-Isoindole-1,3(2H)-dione,2-[7-fluoro-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetrahydro- Catalog No.:AA01CB71 CAS No.:103361-09-7 MDL No.:MFCD01754256 MF:C19H15FN2O4 MW:354.3318
2H-1,4-Benzoxazin-3(4H)-one, 6-amino-7-fluoro-4-(2-propynyl)- Catalog No.:AA007GVA CAS No.:103361-42-8 MDL No.:MFCD03069255 MF:C11H9FN2O2 MW:220.1998	6-Amino-4-methyl-2h-1,4-benzoxazin-3(4h)-one Catalog No.:AA007XLX CAS No.:103361-43-9 MDL No.:MFCD01834021 MF:C9H10N2O2 MW:178.1879
6-Amino-4-ethyl-2H-benzo[b][1,4]oxazin-3(4H)-one Catalog No.:AA007GV9 CAS No.:103361-44-0 MDL No.:MFCD09907440 MF:C10H12N2O2 MW:192.2145	4-Methyl-6-nitro-2H-1,4-benzoxazin-3-one Catalog No.:AA0093YO CAS No.:103361-68-8 MDL No.:MFCD03012694 MF:C9H8N2O4 MW:208.1708
7-Fluoro-2H-1,4-benzoxazin-3(4H)-one Catalog No.:AA007XLW CAS No.:103361-99-5 MDL No.:MFCD07774200 MF:C8H6FNO2 MW:167.1371	4-Bromo-3,5-dimethoxypyridine Catalog No.:AA0085RJ CAS No.:1033610-45-5 MDL No.:MFCD14705143 MF:C7H8BrNO2 MW:218.0479
Fmoc-n-(propargyl)-glycine Catalog No.:AA00H9Z1 CAS No.:1033622-38-6 MDL No.:MFCD17976767 MF:C20H17NO4 MW:335.3533	2-(2-bromophenyl)ethane-1-sulfonyl chloride Catalog No.:AA01AKYP CAS No.:1033629-59-2 MDL No.:MFCD20926131 MF:C8H8BrClO2S MW:283.5699
(S)-N-Boc-3-amino-3-phenylpropanoic acid Catalog No.:AA0038XB CAS No.:103365-47-5 MDL No.:MFCD01860892 MF:C14H19NO4 MW:265.3050	1-Methyl-L-4,5-dihydroorotic acid Catalog No.:AA007GV5 CAS No.:103365-69-1 MDL No.:MFCD08460215 MF:C6H8N2O4 MW:172.1387
ethyl 2-(4-methyl-2-oxo-1,2-dihydroquinolin-1-yl)acetate Catalog No.:AA00IRTQ CAS No.:103368-18-9 MDL No.:MFCD01444199 MF:C14H15NO3 MW:245.2738	N-(3-Amino-1-methylpropyl)-n-ethyl-n-methylamine Catalog No.:AA0090R2 CAS No.:1033693-03-6 MDL No.:MFCD10686556 MF:C7H18N2 MW:130.2312
1-(3-Aminophenyl)-5-methylpyrrolidin-2-one Catalog No.:AA00H9Z2 CAS No.:1033693-04-7 MDL No.:MFCD10686558 MF:C11H14N2O MW:190.2417	1-(1-Methyl-1h-imidazol-2-yl)-1-butanamine Catalog No.:AA00H9Z3 CAS No.:1033693-05-8 MDL No.:MFCD10686561 MF:C8H15N3 MW:153.2248
1,5-Dimethyl-1H-indazole-3-carboxylic acid Catalog No.:AA00J1QF CAS No.:1033693-06-9 MDL No.:MFCD10686580 MF:C10H10N2O2 MW:190.1986	2-Bromo-n-cyclopropylpropanamide Catalog No.:AA00J1RB CAS No.:1033693-07-0 MDL No.:MFCD10686587 MF:C6H10BrNO MW:192.0537
(2-Pyrazin-2-yl-1,3-thiazol-4-yl)methylamine Catalog No.:AA00H9Z4 CAS No.:1033693-08-1 MDL No.:MFCD10686595 MF:C8H8N4S MW:192.2409	4-Chloro-1-methyl-1h-indazole-3-carbaldehyde Catalog No.:AA00H9Z5 CAS No.:1033693-09-2 MDL No.:MFCD10686602 MF:C9H7ClN2O MW:194.6177
1-(4-chloro-1-methyl-1H-indazol-3-yl)methanamine Catalog No.:AA00J1SY CAS No.:1033693-10-5 MDL No.:MFCD10686606 MF:C9H10ClN3 MW:195.6488	(7-Chloro-2-ethyl-3-methyl-1-benzofuran-5-yl)amine Catalog No.:AA00J1TD CAS No.:1033693-11-6 MDL No.:MFCD10686608 MF:C11H12ClNO MW:209.6721
([3-(3-Fluorophenyl)isoxazol-5-yl]methyl)amine Catalog No.:AA0090G7 CAS No.:1033693-12-7 MDL No.:MFCD10686612 MF:C10H9FN2O MW:192.1897	3-chloro-5-(1-pyrrolidinyl)pyridazine Catalog No.:AA00J1TR CAS No.:1033693-13-8 MDL No.:MFCD10686614 MF:C8H10ClN3 MW:183.6381
2-Propylpyrimidine-5-carbonitrile Catalog No.:AA00J1UC CAS No.:1033693-14-9 MDL No.:MFCD10686619 MF:C8H9N3 MW:147.1772	2-Ethyl-3-methyl-1-benzofuran-5-amine Catalog No.:AA009NZW CAS No.:1033693-15-0 MDL No.:MFCD10686621 MF:C11H13NO MW:175.2270
2-(Ethylamino)pyrimidine-5-carbonitrile Catalog No.:AA00J1V9 CAS No.:1033693-16-1 MDL No.:MFCD10686623 MF:C7H8N4 MW:148.1652	(4-Isopropyl-1,2,3-thiadiazol-5-yl)methanol Catalog No.:AA00J1X5 CAS No.:1033693-18-3 MDL No.:MFCD10686634 MF:C6H10N2OS MW:158.2214
3-Methyl-2-(methylthio)phenol Catalog No.:AA00H9Z6 CAS No.:1033693-19-4 MDL No.:MFCD10686635 MF:C8H10OS MW:154.2294	N8,N8-Dimethyl-5,8-quinolinediamine Catalog No.:AA008VKP CAS No.:1033693-20-7 MDL No.:MFCD10686637 MF:C11H13N3 MW:187.2410
Maraviroc-d6 Catalog No.:AA01CC4R CAS No.:1033699-22-7 MDL No.:MFCD21363705 MF:C29H35D6F2N5O MW:519.7025	tert-butyl 4-[(dimethylcarbamoyl)methyl]piperidine-1-carboxylate Catalog No.:AA01A5MC CAS No.:1033705-58-6 MDL No.:MFCD24842998 MF:C14H26N2O3 MW:270.3678
(5-ethynylpyridin-2-yl)methanol Catalog No.:AA01AFQA CAS No.:1033705-77-9 MDL No.:MFCD11520016 MF:C8H7NO MW:133.1473	tert-butyl 3-iodo-7,8-dihydro-1,6-naphthyridine-6(5H)-carboxylate Catalog No.:AA01DT7M CAS No.:1033706-36-3 MDL No.:MFCD31653916 MF:C13H17IN2O2 MW:360.1907
ethyl 2-chloro-5-methyl-3-oxohexanoate Catalog No.:AA019YQD CAS No.:1033707-35-5 MDL No.:MFCD22369809 MF:C9H15ClO3 MW:206.6666	(S)-1-(tert-Butoxycarbonyl)-5-oxopiperazine-2-carboxylic acid Catalog No.:AA0090ZB CAS No.:1033713-11-9 MDL No.:MFCD10698231 MF:C10H16N2O5 MW:244.2444
2-(Oxan-4-yl)-1h-imidazole Catalog No.:AA01B4SB CAS No.:1033717-12-2 MDL No.:MFCD20687037 MF:C8H12N2O MW:152.1937	(R)-1,3-Dimethyl-piperazine Catalog No.:AA009287 CAS No.:1033717-21-3 MDL No.:MFCD11114439 MF:C6H14N2 MW:114.1888
tert-Butyl n-(cis-3-hydroxycyclobutyl)-n-methylcarbamate Catalog No.:AA00H9Z9 CAS No.:1033718-10-3 MDL No.:MFCD21362303 MF:C10H19NO3 MW:201.2628	tert-Butyl n-(trans-3-hydroxycyclobutyl)-n-methylcarbamate Catalog No.:AA009910 CAS No.:1033718-20-5 MDL No.:MFCD21362306 MF:C10H19NO3 MW:201.2628
tert-Butyl n-methyl-n-[(1r,3r)-3-(methanesulfonyloxy)cyclobutyl]carbamate Catalog No.:AA00IKXO CAS No.:1033718-21-6 MDL No.:MFCD03094194 MF:C11H21NO5S MW:279.3531	Carbamic acid, N-[(3S,4R)-4-fluoro-3-pyrrolidinyl]-, 1,1-dimethylethyl ester Catalog No.:AA003AE2 CAS No.:1033718-89-6 MDL No.:MFCD24368651 MF:C9H17FN2O2 MW:204.2419
tert-Butyl ((3R,4S)-4-fluoropyrrolidin-3-yl)carbamate Catalog No.:AA0092M5 CAS No.:1033718-91-0 MDL No.:MFCD24368650 MF:C9H17FN2O2 MW:204.2419	2-[3-(MethylaMino)-1-(2-thienyl)propyl]-1-naphthalenol Hydrochloride Catalog No.:AA008WW9 CAS No.:1033719-36-6 MDL No.:MFCD29038212 MF:C18H20ClNOS MW:333.8755
4-(Isopropoxycarbonylamino)phenylboronic acid Catalog No.:AA0085OI CAS No.:1033726-21-4 MDL No.:MFCD17214243 MF:C10H14BNO4 MW:223.0335	GNE-493 Catalog No.:AA008TDR CAS No.:1033735-94-2 MDL No.:MFCD18251526 MF:C17H20N6O2S MW:372.4447
2-(2-chloro-4-morpholinothieno[3,2-d]pyrimidin-6-yl)propan-2-ol Catalog No.:AA019EQ4 CAS No.:1033743-25-7 MDL No.:MFCD28966046 MF:C13H16ClN3O2S MW:313.8030	3-(4-Methylpiperazin-1-ylsulfonyl)phenylboronic acid pinacol ester Catalog No.:AA008UOU CAS No.:1033743-79-1 MDL No.:MFCD19288884 MF:C17H27BN2O4S MW:366.2833
3-(4-Boc-piperazin-1-ylsulfonyl)phenylboronic acid pinacol ester Catalog No.:AA008UPN CAS No.:1033743-83-7 MDL No.:MFCD19288883 MF:C21H33BN2O6S MW:452.3725	(5-Acetylpyridin-3-yl)boronic acid Catalog No.:AA00944E CAS No.:1033745-21-9 MDL No.:MFCD10696658 MF:C7H8BNO3 MW:164.9543
2-(Methylamino)pyrimidin-5-ylboronic acid Catalog No.:AA007XLB CAS No.:1033745-26-4 MDL No.:MFCD16618931 MF:C5H8BN3O2 MW:152.9469	Trans-4-(boc-amino)-3-methoxypiperidine Catalog No.:AA00H9ZC CAS No.:1033748-33-2 MDL No.:MFCD22566136 MF:C11H22N2O3 MW:230.3040
6-(propan-2-yl)pyridine-3-carbonitrile Catalog No.:AA01ACJV CAS No.:1033750-40-1 MDL No.:MFCD18256041 MF:C9H10N2 MW:146.1891	4-Isobutylphenylboronic acid, pinacol ester Catalog No.:AA007XLA CAS No.:1033753-01-3 MDL No.:MFCD05663842 MF:C16H25BO2 MW:260.1795
CIS-2-AMINO-CYCLOHEPTANECARBOXYLIC ACID HYDROCHLORIDE Catalog No.:AA008SJA CAS No.:1033756-97-6 MDL No.:MFCD08277034 MF:C8H16ClNO2 MW:193.6711	rac-methyl (1R,2S)-2-aminocyclooctane-1-carboxylate hydrochloride, cis Catalog No.:AA01EJIN CAS No.:1033756-98-7 MDL No.:MFCD31559508 MF:C10H20ClNO2 MW:221.7243
Gnf 5837 Catalog No.:AA008TDS CAS No.:1033769-28-6 MDL No.:MFCD24386809 MF:C28H21F4N5O2 MW:535.4923	1H-Pyrazolo[4,3-b]pyridine-5-carbonitrile Catalog No.:AA007XL9 CAS No.:1033772-22-3 MDL No.:MFCD18384475 MF:C7H4N4 MW:144.1335
Methyl 1h-pyrazolo[3,4-c]pyridine-5-carboxylate Catalog No.:AA00975Q CAS No.:1033772-26-7 MDL No.:MFCD19690201 MF:C8H7N3O2 MW:177.1601	N-(Benzyloxy)-4-nitrobenzenesulfonamide Catalog No.:AA01BDOU CAS No.:1033774-90-1 MDL No.:MFCD27991999 MF:C13H12N2O5S MW:308.3098
1-(Pyridin-3-ylmethyl)-1h-pyrazol-3-amine Catalog No.:AA01A8BH CAS No.:1033780-34-5 MDL No.:MFCD12149379 MF:C9H10N4 MW:174.2025	Potassium trifluoro(2-hydroxy-3-methylphenyl)boranuide Catalog No.:AA00H9ZE CAS No.:1033783-02-6 MDL No.:MFCD09993089 MF:C7H7BF3KO MW:214.0344
Salidroside Catalog No.:AA0039JD CAS No.:10338-51-9 MDL No.:MFCD00210553 MF:C14H20O7 MW:300.3044	4-Piperidinobenzaldehyde Catalog No.:AA0037Z0 CAS No.:10338-57-5 MDL No.:MFCD00778395 MF:C12H15NO MW:189.2536
Methyl 4-piperidinobenzenecarboxylate Catalog No.:AA008ZCM CAS No.:10338-58-6 MDL No.:MFCD08444024 MF:C13H17NO2 MW:219.2796	4-(Piperidin-1-yl)benzenesulfonamide Catalog No.:AA007GOU CAS No.:10338-60-0 MDL No.:MFCD05744864 MF:C11H16N2O2S MW:240.3219
1,2,3,6-Tetrahydro-4-phenyl-pyridine Catalog No.:AA0085OA CAS No.:10338-69-9 MDL No.:MFCD00023118 MF:C11H13N MW:159.2276	Lx1606 Catalog No.:AA008TEQ CAS No.:1033805-22-9 MDL No.:MFCD18251583 MF:C27H26ClF3N6O3 MW:574.9819
(R)-1-(4-Chloro-2-(3-methyl-1h-pyrazol-1-yl)phenyl)-2,2,2-trifluoroethanol Catalog No.:AA008TKW CAS No.:1033805-26-3 MDL No.:MFCD23099027 MF:C12H10ClF3N2O MW:290.6688	(2S)-2-amino-3-(4-{2-amino-6-[(1R)-1-[4-chloro-2-(3-methyl-1H-pyrazol-1-yl)phenyl]-2,2,2-trifluoroethoxy]pyrimidin-4-yl}phenyl)propanoic acid Catalog No.:AA008TH4 CAS No.:1033805-28-5 MDL No.:MFCD20528907 MF:C25H22ClF3N6O3 MW:546.9288
7-Hydroxyisoindolin-1-one Catalog No.:AA009913 CAS No.:1033809-85-6 MDL No.:MFCD18416894 MF:C8H7NO2 MW:149.1467	tert-butyl 4-formyl-4-propylpiperidine-1-carboxylate Catalog No.:AA01BB0V CAS No.:1033819-08-7 MDL No.:MFCD24470695 MF:C14H25NO3 MW:255.3532
(S)-2-(Aminomethyl)pyrrolidine dihydrochloride Catalog No.:AA007GOZ CAS No.:103382-84-9 MDL No.:MFCD11974898 MF:C5H14Cl2N2 MW:173.0841	6-Bromo-2,3-dichloropyridine Catalog No.:AA008YZI CAS No.:1033820-08-4 MDL No.:MFCD11857711 MF:C5H2BrCl2N MW:226.8861
Methyl 8-boc-8-azabicyclo[3.2.1]octane-2-carboxylate Catalog No.:AA00H9ZJ CAS No.:1033820-28-8 MDL No.:MFCD23106266 MF:C14H23NO4 MW:269.3367	6-(3-Fluorophenyl)-n-(1-(2,2,2-trifluoroethyl)piperidin-4-yl)nicotinamide Catalog No.:AA008TE2 CAS No.:1033836-12-2 MDL No.:MFCD18206776 MF:C19H19F4N3O MW:381.3673
1-[4-(2H-1,3-benzodioxol-5-yloxy)but-2-yn-1-yl]-4-methylpiperazine dihydrochloride Catalog No.:AA00IYEG CAS No.:1033847-02-7 MDL No.:MFCD06795608 MF:C16H22Cl2N2O3 MW:361.2635	4-[2-nitro-4-(1H-pyrazol-5-yl)phenyl]morpholine Catalog No.:AA00IYSF CAS No.:1033847-04-9 MDL No.:MFCD08281890 MF:C13H14N4O3 MW:274.2753
2-amino-N-(2-phenylethyl)benzene-1-sulfonamide hydrochloride Catalog No.:AA00IT32 CAS No.:1033847-14-1 MDL No.:MFCD05669253 MF:C14H16ClN2O2S MW:311.8070	3-(Methoxymethyl)benzene-1-sulfonyl chloride Catalog No.:AA01A9PO CAS No.:1033865-73-4 MDL No.:MFCD11650727 MF:C8H9ClO3S MW:220.6733
nitraminoacetic acid Catalog No.:AA009RA4 CAS No.:10339-31-8 MDL No.:MFCD01724669 MF:C2H4N2O4 MW:120.0642	N'-(prop-2-enoyl)benzohydrazide Catalog No.:AA01BBO2 CAS No.:10339-47-6 MDL No.:MFCD25954591 MF:C10H10N2O2 MW:190.1986
3,3,3-Trifluoropropane-1-sulfonamide Catalog No.:AA008SD0 CAS No.:1033906-44-3 MDL No.:MFCD08704575 MF:C3H6F3NO2S MW:177.1454	2,2-Difluoroethane-1-sulfonamide Catalog No.:AA0096IS CAS No.:1033906-56-7 MDL No.:MFCD16990720 MF:C2H5F2NO2S MW:145.1284
2,2-Difluoroethanesulfonyl Chloride Catalog No.:AA008UQ6 CAS No.:1033906-60-3 MDL No.:MFCD16990719 MF:C2H3ClF2O2S MW:164.5588	3-fluoropropane-1-sulfonamide Catalog No.:AA01AKKT CAS No.:1033906-62-5 MDL No.:MFCD11847579 MF:C3H8FNO2S MW:141.1645
methyl 3-[(6-methylpyridin-2-yl)amino]propanoate Catalog No.:AA01AJCV CAS No.:103392-82-1 MDL No.:MFCD12806956 MF:C10H14N2O2 MW:194.2304	2-tert-Butyl-5-nitroaniline Catalog No.:AA007XKZ CAS No.:103392-84-3 MDL No.:MFCD01463870 MF:C10H14N2O2 MW:194.2304
2-(2-methyl-1H-1,3-benzodiazol-1-yl)ethan-1-amine dihydrochloride Catalog No.:AA019VZW CAS No.:103394-45-2 MDL No.:MFCD12912829 MF:C10H15Cl2N3 MW:248.1522	6,8-Dimethyl-1,2,3,4-tetrahydro-1,5-naphthyridine Catalog No.:AA01ARXA CAS No.:103394-65-6 MDL No.:MFCD14704083 MF:C10H14N2 MW:162.2316
Octyl gallate Catalog No.:AA003TE9 CAS No.:1034-01-1 MDL No.:MFCD00002197 MF:C15H22O5 MW:282.3322	Dl-thyronine Catalog No.:AA003PRV CAS No.:1034-10-2 MDL No.:MFCD00045864 MF:C15H15NO4 MW:273.2839
Triphenylphosphine dibromide Catalog No.:AA0035P1 CAS No.:1034-39-5 MDL No.:MFCD00000054 MF:C18H15Br2P MW:422.0935	(Bromomethyl)triphenylphosphonium bromide Catalog No.:AA003AVO CAS No.:1034-49-7 MDL No.:MFCD00011864 MF:C19H17Br2P MW:436.1200
Cis-1,3-bis(aminomethyl)cyclohexane Catalog No.:AA008X26 CAS No.:10340-00-8 MDL No.:MFCD19204670 MF:C8H18N2 MW:142.2419	Benzyl isocyanide Catalog No.:AA003O1G CAS No.:10340-91-7 MDL No.:MFCD26620325 MF:C8H7N MW:117.1479
Carbamic acid, N-(6,8-difluoro-2H-1-benzopyran-3-yl)-, methyl ester Catalog No.:AA007XKP CAS No.:1034001-13-2 MDL No.:MFCD20528372 MF:C11H9F2NO3 MW:241.1909	[RuCl(p-cymene)((R)-tolbinap)]Cl Catalog No.:AA00942V CAS No.:1034001-51-8 MDL No.:MFCD09753014 MF:C58H54Cl2P2Ru+ MW:984.9729
3-Deoxy-D-manno-2-octulosonic Acid Ammonium Salt Catalog No.:AA003JAA CAS No.:103404-70-2 MDL No.:MFCD00269965 MF:C8H17NO8 MW:255.2225	D-Luciferin sodium salt Catalog No.:AA0037YZ CAS No.:103404-75-7 MDL No.:MFCD11865368 MF:C11H7N2NaO3S2 MW:302.3047
(2R)-2-Hydroxypentanedioic acid Catalog No.:AA007XKK CAS No.:103404-90-6 MDL No.:MFCD00069573 MF:C5H6Na2O5 MW:192.0777	CHEMHERE CHEM143848 Catalog No.:AA01DX4Q CAS No.:1034047-33-0 MDL No.:MFCD28665253 MF:C5H2ClF3O2S2 MW:250.6464
rac-(1R,2S,4S)-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid Catalog No.:AA00J2T0 CAS No.:1034079-37-2 MDL No.:MFCD28390508 MF:C7H10O3 MW:142.1525	pyrimido(1,2-a)purin-10(1H)-one Catalog No.:AA008X4E CAS No.:103408-45-3 MDL No.: MF:C8H5N5O MW:187.1582
ethyl 3,5-dimethyl-1-(4-methylphenyl)-1H-pyrazole-4-carboxylate Catalog No.:AA00IP6F CAS No.:103409-93-4 MDL No.:MFCD05974910 MF:C15H18N2O2 MW:258.3156	1,4-Oxazepan-5-one Catalog No.:AA0032KC CAS No.:10341-26-1 MDL No.:MFCD02683091 MF:C5H9NO2 MW:115.1305
N-(3-methylbutan-2-ylidene)hydroxylamine Catalog No.:AA019MSJ CAS No.:10341-62-5 MDL No.:MFCD00126852 MF:C5H11NO MW:101.1469	2-(((ethylamino)carbonyl)amino)benzoic acid Catalog No.:AA01858Y CAS No.:10341-84-1 MDL No.:MFCD00020245 MF:C10H12N2O3 MW:208.2139
3-Allylquinazoline-2,4(1H,3H)-dione Catalog No.:AA00H9ZP CAS No.:10341-86-3 MDL No.:MFCD14703302 MF:C11H10N2O2 MW:202.2093	3-Phenylthiophene-2-carboxylic acid Catalog No.:AA007GMK CAS No.:10341-88-5 MDL No.:MFCD06358640 MF:C11H8O2S MW:204.2450
Methyl 5-((tert-butoxycarbonyl)(methyl)amino)-2-chloroisonicotinate Catalog No.:AA00H9ZQ CAS No.:1034131-89-9 MDL No.:MFCD24470723 MF:C13H17ClN2O4 MW:300.7381	5-AMINO-1-(3-FLUOROPHENYL)-1H-PYRAZOLE-4-CARBOXYLIC ACID Catalog No.:AA01ELGQ CAS No.:1034142-09-0 MDL No.:MFCD16311555 MF:C10H8FN3O2 MW:221.1878
1-(methoxycarbonyl)-2-phenylcyclopropane-1-carboxylic acid Catalog No.:AA01E81K CAS No.:1034147-27-7 MDL No.:MFCD30750664 MF:C12H12O4 MW:220.2213	1,3,4-Oxadiazol-2(3H)-one,5-(2-furanyl)- Catalog No.:AA0085NQ CAS No.:103418-56-0 MDL No.:MFCD07838478 MF:C6H4N2O3 MW:152.1076
B-L-FUCOPYRANOSYLAMINE Catalog No.:AA008SLH CAS No.:103419-79-0 MDL No.:MFCD00057553 MF:C6H13NO4 MW:163.1717	Ethyl1,5-Dimethyl-1H-1,2,4-triazole-3-carboxylate Catalog No.:AA01BD0B CAS No.:1034197-35-7 MDL No.:MFCD18344465 MF:C7H11N3O2 MW:169.1811
3-(Chloromethyl)-4,5-dimethyl-4h-1,2,4-triazole hydrochloride Catalog No.:AA00J25W CAS No.:1034197-53-9 MDL No.:MFCD08669960 MF:C5H8ClN3 MW:145.5901	3-ethyl-4-methyl-4H-1,2,4-triazole Catalog No.:AA01A90M CAS No.:1034197-72-2 MDL No.:MFCD16622035 MF:C5H9N3 MW:111.1451
Boc-ser(bzl)-oh dcha Catalog No.:AA008XKW CAS No.:10342-01-5 MDL No.:MFCD00067670 MF:C27H44N2O5 MW:476.6487	1-(2-Methylpropyl)-4-nitro-benzene Catalog No.:AA007GMG CAS No.:10342-60-6 MDL No.:MFCD00130032 MF:C10H13NO2 MW:179.2157
4'-Bromopropiophenone Catalog No.:AA007GMB CAS No.:10342-83-3 MDL No.:MFCD00000106 MF:C9H9BrO MW:213.0712	1-(4-(Piperidin-1-yl)phenyl)ethanone Catalog No.:AA0085NF CAS No.:10342-85-5 MDL No.:MFCD00006481 MF:C13H17NO MW:203.2802
1-(4-(4-Hydroxypiperidin-1-yl)phenyl)ethanone Catalog No.:AA007GMA CAS No.:10342-87-7 MDL No.:MFCD00023665 MF:C13H17NO2 MW:219.2796	Devazepide Catalog No.:AA007XKB CAS No.:103420-77-5 MDL No.:MFCD00864500 MF:C25H20N4O2 MW:408.4519
3-Chloro-5-methylbenzaldehyde Catalog No.:AA0085NL CAS No.:103426-20-6 MDL No.:MFCD11553565 MF:C8H7ClO MW:154.5936	1-(4-broMo-2-fluorophenyl)ethanaMine Catalog No.:AA00963R CAS No.:1034266-14-2 MDL No.:MFCD18701996 MF:C8H9BrFN MW:218.0662
4-Ethynylbenzeneboronic acid pinacol ester Catalog No.:AA009047 CAS No.:1034287-04-1 MDL No.:MFCD16294504 MF:C14H17BO2 MW:228.0946	CTOP Catalog No.:AA008RR3 CAS No.:103429-31-8 MDL No.:MFCD00076708 MF:C50H67N11O11S2 MW:1062.2641
CTAP Catalog No.:AA008ROT CAS No.:103429-32-9 MDL No.:MFCD00671434 MF:C51H69N13O11S2 MW:1104.3041	CRT5 Catalog No.:AA00977A CAS No.:1034297-58-9 MDL No.:MFCD29081160 MF:C28H32Cl2N4O2 MW:527.4853
6-Methoxypyridine-2-boronic acid pinacol ester Catalog No.:AA003HGQ CAS No.:1034297-69-2 MDL No.:MFCD06798266 MF:C12H18BNO3 MW:235.0872	2,3,4,6-Tetra-O-acetyl-D-glucopyranose Catalog No.:AA00H9ZU CAS No.:10343-06-3 MDL No.:MFCD00061634 MF:C14H20O10 MW:348.3026
Benzyl 2,3,4,6-tetra-o-acetyl-beta-d-glucopyranoside Catalog No.:AA0085NC CAS No.:10343-13-2 MDL No.:MFCD00184641 MF:C21H26O10 MW:438.4251	Allyl 2,3,4,6-tetra-o-acetyl-beta-d-glucopyranoside Catalog No.:AA008UAH CAS No.:10343-15-4 MDL No.:MFCD03427087 MF:C17H24O10 MW:388.3665
Rac-(4aR,8aR)-decahydroquinoline Catalog No.:AA008YDL CAS No.:10343-99-4 MDL No.:MFCD00137756 MF:C9H17N MW:139.2380	1,3,5-Triazin-2(1H)-one,4-amino-1-[3,5-bis-O-(4-chlorobenzoyl)-2-deoxy-b-D-erythro-pentofuranosyl]- Catalog No.:AA01CBIS CAS No.:1034301-08-0 MDL No.:MFCD22124452 MF:C22H18Cl2N4O6 MW:505.3075
2-(5-Bromo-2-fluorobenzyl)benzo[b]thiophene Catalog No.:AA00H9ZV CAS No.:1034305-17-3 MDL No.:MFCD28144826 MF:C15H10BrFS MW:321.2073	JPMTWOPHARM JPM2-00-8466 Catalog No.:AA01EL8F CAS No.:1034309-54-0 MDL No.:MFCD28402994 MF:C10H7BrN2 MW:235.0800
4-(2-Chloroethyl)-1h-pyrazole hydrochloride Catalog No.:AA008T5S CAS No.:103433-17-6 MDL No.:MFCD07778415 MF:C5H8Cl2N2 MW:167.0364	Graphene filM, Monolayer, on copper foil (1cM x 1cM) Catalog No.:AA008WQU CAS No.:1034343-98-0 MDL No.:MFCD00144065 MF:CH4 MW:16.0425
2-Bromo-3-(2-ethylhexyl)-5-iodothiophene Catalog No.:AA009432 CAS No.:1034352-30-1 MDL No.:MFCD28384136 MF:C12H18BrIS MW:401.1448	2-Fluoro-5-hydroxybenzaldehyde Catalog No.:AA0038A3 CAS No.:103438-84-2 MDL No.:MFCD01321273 MF:C7H5FO2 MW:140.1118
4-Fluoro-3-hydroxybenzaldehyde Catalog No.:AA007GM5 CAS No.:103438-85-3 MDL No.:MFCD11110190 MF:C7H5FO2 MW:140.1118	2-Fluoro-3-hydroxybenzaldehyde Catalog No.:AA008SL8 CAS No.:103438-86-4 MDL No.:MFCD27929482 MF:C7H5FO2 MW:140.1118
2-Fluoro-3-methoxybenzaldehyde Catalog No.:AA003H61 CAS No.:103438-88-6 MDL No.:MFCD03411962 MF:C8H7FO2 MW:154.1384	(+/-)-1-AMINO-TRANS-3-PHOSPHONO-CYCLOPEN TANE CARBO Catalog No.:AA008Y1R CAS No.:103439-17-4 MDL No.:MFCD12828753 MF:C12H24N2O10P2 MW:418.2739
4-Bromo-3,6-dichloropyridazine Catalog No.:AA0037YU CAS No.:10344-42-0 MDL No.:MFCD13193322 MF:C4HBrCl2N2 MW:227.8741	Diethyl malonimidate dihydrochloride Catalog No.:AA003PE4 CAS No.:10344-69-1 MDL No.:MFCD00054633 MF:C7H16Cl2N2O2 MW:231.1201
4-Nitrophenyl-beta-d-glucuronide Catalog No.:AA003LTI CAS No.:10344-94-2 MDL No.:MFCD06412595 MF:C12H13NO9 MW:315.2329	4-(chloromethyl)-3-nitrobenzoic acid Catalog No.:AA01B1ZS CAS No.:103440-03-5 MDL No.:MFCD26801843 MF:C8H6ClNO4 MW:215.5905
Methyl 2-Iodo-5-methylbenzoate Catalog No.:AA007GM2 CAS No.:103440-52-4 MDL No.:MFCD12198129 MF:C9H9IO2 MW:276.0710	Methyl 4-iodo-2-methylbenzoate Catalog No.:AA007GM1 CAS No.:103440-53-5 MDL No.:MFCD18399464 MF:C9H9IO2 MW:276.0710
Methyl 5-iodo-2-methylbenzoate Catalog No.:AA008TXG CAS No.:103440-54-6 MDL No.:MFCD11112847 MF:C9H9IO2 MW:276.0710	Methyl 2-iodo-6-methylbenzoate Catalog No.:AA008Z53 CAS No.:103440-55-7 MDL No.:MFCD08061917 MF:C9H9IO2 MW:276.0710
Methyl 2-iodo-4-methylbenzoate Catalog No.:AA007GM0 CAS No.:103440-56-8 MDL No.:MFCD18399463 MF:C9H9IO2 MW:276.0710	3-(2-Iodophenoxy)propanoic acid Catalog No.:AA01BFG8 CAS No.:103440-61-5 MDL No.:MFCD12181701 MF:C9H9IO3 MW:292.0704
(2-Methylbenzo[d]thiazol-6-yl)methanol Catalog No.:AA009197 CAS No.:103440-65-9 MDL No.:MFCD02940901 MF:C9H9NOS MW:179.2389	7-Amino-2,3-dihydro-4h-1-benzopyran-4-one Catalog No.:AA0095SF CAS No.:103440-75-1 MDL No.:MFCD11111759 MF:C9H9NO2 MW:163.1733
4-Ethyl-3-nitrobenzoic acid Catalog No.:AA0085LQ CAS No.:103440-95-5 MDL No.:MFCD08460111 MF:C9H9NO4 MW:195.1721	4-Ethoxy-2-nitrobenzoic acid Catalog No.:AA0094JR CAS No.:103440-98-8 MDL No.:MFCD09909646 MF:C9H9NO5 MW:211.1715
Methyl 2-iodo-3-methylbenzoate Catalog No.:AA0093KV CAS No.:103441-60-7 MDL No.:MFCD12923249 MF:C9H9IO2 MW:276.0710	7,8-Dihydroisoquinolin-5(6h)-one hydrochloride Catalog No.:AA007GFZ CAS No.:103441-65-2 MDL No.:MFCD18384593 MF:C9H10ClNO MW:183.6348
6-Aminochroman-4-one Catalog No.:AA0095AH CAS No.:103441-69-6 MDL No.:MFCD14526813 MF:C9H9NO2 MW:163.1733	Deoxy Donepezil Hydrochloride Catalog No.:AA007XFV CAS No.:1034439-57-0 MDL No.:MFCD16294190 MF:C24H32ClNO2 MW:401.9694
1,3-Dicyclohexylbenzimidazolium chloride Catalog No.:AA008V90 CAS No.:1034449-15-4 MDL No.:MFCD08705248 MF:C19H27ClN2 MW:318.8841	1-(2,3-Dihydro-1h-inden-2-yl)-2-methylpropan-2-amine hydrochloride Catalog No.:AA0093VE CAS No.:1034457-07-2 MDL No.:MFCD22383947 MF:C13H20ClN MW:225.7576
2-Fluoro-4-iodo-5-(methoxymethoxy)pyridine Catalog No.:AA0096EI CAS No.:1034467-27-0 MDL No.:MFCD22123918 MF:C7H7FINO2 MW:283.0389	4-Chloro-3-((trimethylsilyl)ethynyl)pyridine Catalog No.:AA00H9ZZ CAS No.:1034467-33-8 MDL No.:MFCD15530294 MF:C10H12ClNSi MW:209.7475
1-(6-Fluoropyridin-3-yl)ethanol Catalog No.:AA0095U0 CAS No.:1034467-37-2 MDL No.:MFCD18384473 MF:C7H8FNO MW:141.1429	5-Cyclopropyl-2-fluoropyridine Catalog No.:AA008TLE CAS No.:1034467-80-5 MDL No.:MFCD18384289 MF:C8H8FN MW:137.1542
4-Fluorobicyclo[4.2.0]octa-1,3,5-triene-7-carbonitrile Catalog No.:AA009L49 CAS No.:103447-28-5 MDL No.:MFCD18827079 MF:C9H6FN MW:147.1490	Ethyl 3-amino-4-cyanobenzoate Catalog No.:AA019ERX CAS No.:1034470-00-2 MDL No.:MFCD20702986 MF:C10H10N2O2 MW:190.1986
2-Bromo-4-methyl-5-nitrophenol Catalog No.:AA003GLQ CAS No.:103448-24-4 MDL No.:MFCD27935372 MF:C7H6BrNO3 MW:232.0314	4-Ethyl-3-fluoroaniline Catalog No.:AA01A26N CAS No.:1034497-92-1 MDL No.:MFCD19205834 MF:C8H10FN MW:139.1701